Polymorphism in M(H2PO2)3 (M = V, Al, Ga) compounds with the perovskite-related ReO3 structure

Evans, Hayden A.; Deng, Zeyu; Collings, Ines E.; Wu, Yue; Andrews, Jessica L.; Pilar, Kartik; Tuffnell, Joshua M.; Wu, Guang; Wang, John; Dutton, Siân E.; Bristowe, Paul D.; Seshadri, Ram; Cheetham, Anthony K.

doi:10.1039/C9CC00118B

Polymorphism in M(H₂PO₂)₃ (M = V, Al, Ga) compounds with the perovskite-related ReO₃ structure

Journal Article · Fri Feb 15 00:00:00 EST 2019 · ChemComm

DOI:https://doi.org/10.1039/C9CC00118B· OSTI ID:1599724

^[1]; ^[2]; ^[3]; ^[4]; Andrews, Jessica L. ^[5]; ^[5]; Tuffnell, Joshua M. ^[6]; Wu, Guang ^[5]; Wang, John ^[4]; ^[6]; ^[6]; ^[5]; ^[7]

Univ. of California, Santa Barbara, CA (United States); UC Santa Barbara
National Univ. of Singapore (Singapore); Univ. of Cambridge (United Kingdom)
European Synchrotron Radiation Facility (ESRF), Grenoble (France)
National Univ. of Singapore (Singapore)
Univ. of California, Santa Barbara, CA (United States)
Univ. of Cambridge (United Kingdom)
Univ. of California, Santa Barbara, CA (United States); National Univ. of Singapore (Singapore)

Trivalent metal hypophosphites with the general formula M(H₂PO₂)₃ (M = V, Al, Ga) adopt the ReO₃ structure, with each compound displaying two structural polymorphs. High-pressure synchrotron X-ray studies reflect a pressure-driven phase transition in Ga(H₂PO₂)₃ that can be considered on the basis of ab initio thermodynamics.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Contributing Organization:: European Synchrotron Radiation Facility; National University of Singapore; University of Cambridge

Grant/Contract Number:: SC0012541

OSTI ID:: 1599724

Alternate ID(s):: OSTI ID: 1495059

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 20 Vol. 55; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Perovskite-related ReO3-type structures Evans, Hayden A.; Wu, Yue; Seshadri, Ram Nature Reviews Materials, Vol. 5, Issue 3 https://doi.org/10.1038/s41578-019-0160-x	journal	January 2020
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