Nonplanar Electrode Architectures for Ultrahigh Areal Capacity Batteries

Zheng, Jingxu; Zhao, Qing; Liu, Xiaotun; Tang, Tian; Bock, David C.; Bruck, Andrea M.; Tallman, Killian R.; Housel, Lisa M.; Kiss, Andrew M.; Marschilok, Amy C.; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Archer, Lynden A.

doi:10.1021/acsenergylett.8b02131

Nonplanar Electrode Architectures for Ultrahigh Areal Capacity Batteries

Journal Article · Wed Dec 12 23:00:00 EST 2018 · ACS Energy Letters

DOI:https://doi.org/10.1021/acsenergylett.8b02131· OSTI ID:1495007

Zheng, Jingxu ^[1]; Zhao, Qing ^[1]; Liu, Xiaotun ^[1]; Tang, Tian ^[1]; Bock, David C. ^[2]; Bruck, Andrea M. ^[3]; Tallman, Killian R. ^[3]; Housel, Lisa M. ^[3]; Kiss, Andrew M. ^[2]; ^[4]; ^[4]; ^[3]; ^[1]

Cornell Univ., Ithaca, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
State Univ. of New York at Stony Brook, Stony Brook, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York at Stony Brook, Stony Brook, NY (United States)

Here, we report on the design of a battery electrode architecture in which ion and electronic transport pathways are continuous, and span the entire volume of a thick, non-planar electrode. It is shown that for a range of active materials conductivities, the length scale for electronic transport in such an architecture can be tuned by simple manipulations of the electrode design to enable good access to the active material. The benefits of such electrodes for basic science research and practical lithium metal batteries are demonstrated in low-N:P ratio cells in which a conventional (300- 800 μm) Li foil is successfully cycled with LiCoO₂ cathodes with high areal capacities (10- 28 mAh/cm²).

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012704

OSTI ID:: 1495007

Report Number(s):: BNL--211271-2019-JAAM

Journal Information:: ACS Energy Letters, Journal Name: ACS Energy Letters Journal Issue: 1 Vol. 4; ISSN 2380-8195

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Free-standing transition metal oxide electrode architectures for electrochemical energy storage Spencer, Michael A.; Augustyn, Veronica Journal of Materials Science, Vol. 54, Issue 20 https://doi.org/10.1007/s10853-019-03823-y	journal	July 2019
Reversible epitaxial electrodeposition of metals in battery anodes Zheng, Jingxu; Zhao, Qing; Tang, Tian Science, Vol. 366, Issue 6465 https://doi.org/10.1126/science.aax6873	journal	October 2019

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