Li-Substituted Layered Spinel Cathode Material for Sodium Ion Batteries

Deng, Changjian; Skinner, Paige; Liu, Yuzi; Sun, Meiling; Tong, Wei; Ma, Chunrong; Lau, Miu Lun; Hunt, Riley; Barnes, Pete; Xu, Jing; Xiong, Hui

doi:10.1021/acs.chemmater.8b02614

Title: Li-Substituted Layered Spinel Cathode Material for Sodium Ion Batteries

Journal Article · Wed Oct 24 00:00:00 EDT 2018 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.8b02614· OSTI ID:1542342

Deng, Changjian ^[1]; Skinner, Paige ^[1]; Liu, Yuzi ^[2]; Sun, Meiling ^[3];

^[3]; Ma, Chunrong ^[4]; Lau, Miu Lun ^[1]; Hunt, Riley ^[1]; Barnes, Pete ^[1]; Xu, Jing ^[5];

^[6]

Boise State Univ., ID (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Boise State Univ., ID (United States); Shanghai Jiao Tong Univ., Shanghai (China)
Iowa State Univ., Ames, IA (United States)
Boise State Univ., ID (United States); Center for Advanced Energy Studies, Boulevard, Idaho Falls, ID (United States)

The O3-type layered Na(NixFeyMnz)O2 (0 < x, y, z < 1) cathode materials have attracted great interest in sodium-ion batteries due to the abundance and cost of raw materials and their high specific capacities. However, the cycling stability and rate ca-pability at high voltages (> 4.0V) of these materials remains an issue. In this work, we successfully synthesized a Li-substituted layered-tunneled (O3-spinel) intergrowth cathode (LS-NFM) to address these issues. The remarkable structural compatibility and connectivity of the two phases were confirmed by X-ray diffraction (XRD), selected area electron diffrac-tion (SAED) and high resolution transmission electron microscopy (HRTEM). LS-NFM electrode reached a discharge capaci-ty of 96 mAh g-1 with a capacity retention of 86% after 100 cycles at a current rate of 100 mA g-1 in a voltage window of 2.0 - 4.2 V. Moreover, the LS-NFM cathode exhibited an enhanced rate capability in comparison to the un-doped layered cath-ode (NFM). The enhanced rate capability of LS-NFM can be explained by the significantly increased effective Na+ diffusivity measured by galvanostatic intermittent titration technique (GITT) compared to the un-doped control NFM cathode, which can be ascribed to the improved charge transport kinetics through shortened diffusion path by direct connection between the 3D channels in the spinel phase and 2D channels in the layered phase. The results from ex situ hard/soft X-ray adsorption spectroscopy (XAS) suggest that the capacity of LS-NFM cathode is mainly associated with the Ni2+/Ni4+ redox couple, and slightly from the Fe3+/Fe4+ redox couple. The voltage profile of the LS-NFM cathode exhibited a reversible plateau above 4.0 V, indicating great stability at high voltages and structural stabilization by the spinel phase. In addition to the substitution of various transition metals, or the modification of the stoichiometry of each transition metal, this study provides a new strategy to improve electrochemical performance of layered cathode materials for sodium ion batteries.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Boise State Univ., ID (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC02-05CH11231; SC0019121; AC02-06CH11357

OSTI ID:: 1542342

Alternate ID(s):: OSTI ID: 1494597; OSTI ID: 1711437

Journal Information:: Chemistry of Materials, Vol. 30, Issue 22; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 25 works

Citation information provided by
Web of Science

References (66)

Research Development on Sodium-Ion Batteries Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500192f	journal	October 2014
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan Energy & Environmental Science, Vol. 6, Issue 8 https://doi.org/10.1039/c3ee40847g	journal	January 2013
The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage Kundu, Dipan; Talaie, Elahe; Duffort, Victor Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201410376	journal	February 2015
Sodium-Ion Batteries Slater, Michael D.; Kim, Donghan; Lee, Eungje Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958 https://doi.org/10.1002/adfm.201200691	journal	May 2012
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721 https://doi.org/10.1002/aenm.201200026	journal	May 2012
Sodium and sodium-ion energy storage batteries Ellis, Brian L.; Nazar, Linda F. Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177 https://doi.org/10.1016/j.cossms.2012.04.002	journal	August 2012
Recent Advances in Sodium Intercalation Positive Electrode Materials for Sodium ion Batteries Xu, Jing; Lee, Dae Hoe; Meng, Ying Shirley Functional Materials Letters, Vol. 06, Issue 01 https://doi.org/10.1142/S1793604713300016	journal	February 2013
Assessment of world lithium resources and consequences of their geographic distribution on the expected development of the electric vehicle industry Grosjean, Camille; Miranda, Pamela Herrera; Perrin, Marion Renewable and Sustainable Energy Reviews, Vol. 16, Issue 3 https://doi.org/10.1016/j.rser.2011.11.023	journal	April 2012
Electrochemical performance of a smooth and highly ordered TiO2 nanotube electrode for Li-ion batteries Ryu, Won-Hee; Nam, Do-Hwan; Ko, Yoo-Sung Electrochimica Acta, Vol. 61 https://doi.org/10.1016/j.electacta.2011.11.042	journal	February 2012
Lithium market research – global supply, future demand and price development Martin, Gunther; Rentsch, Lars; Höck, Michael Energy Storage Materials, Vol. 6 https://doi.org/10.1016/j.ensm.2016.11.004	journal	January 2017
The future of lithium availability for electric vehicle batteries Speirs, Jamie; Contestabile, Marcello; Houari, Yassine Renewable and Sustainable Energy Reviews, Vol. 35 https://doi.org/10.1016/j.rser.2014.04.018	journal	July 2014
Lithium availability and future production outlooks Vikström, Hanna; Davidsson, Simon; Höök, Mikael Applied Energy, Vol. 110 https://doi.org/10.1016/j.apenergy.2013.04.005	journal	October 2013
Na-ion batteries, recent advances and present challenges to become low cost energy storage systems Palomares, Verónica; Serras, Paula; Villaluenga, Irune Energy & Environmental Science, Vol. 5, Issue 3 https://doi.org/10.1039/c2ee02781j	journal	January 2012
Layered oxides as positive electrode materials for Na-ion batteries Kubota, Kei; Yabuuchi, Naoaki; Yoshida, Hiroaki MRS Bulletin, Vol. 39, Issue 5 https://doi.org/10.1557/mrs.2014.85	journal	May 2014
Electrochemical and Thermal Properties of α-NaFeO ₂ Cathode for Na-Ion Batteries Zhao, Jie; Zhao, Liwei; Dimov, Nikolay Journal of The Electrochemical Society, Vol. 160, Issue 5 https://doi.org/10.1149/2.007305jes	journal	January 2013
Synthesis and Electrode Performance of O3-Type NaFeO ₂ -NaNi _1/2 Mn _1/2 O ₂ Solid Solution for Rechargeable Sodium Batteries Yabuuchi, Naoaki; Yano, Masaya; Yoshida, Hiroaki Journal of The Electrochemical Society, Vol. 160, Issue 5 https://doi.org/10.1149/2.018305jes	journal	January 2013
Improved Electrochemical Performance of Fe-Substituted NaNi _0.5 Mn _0.5 O ₂ Cathode Materials for Sodium-Ion Batteries Yuan, Ding D.; Wang, Yan X.; Cao, Yu L. ACS Applied Materials & Interfaces, Vol. 7, Issue 16 https://doi.org/10.1021/acsami.5b00594	journal	April 2015
Large-Scale Synthesis of NaNi _1/3 Fe _1/3 Mn _1/3 O ₂ as High Performance Cathode Materials for Sodium Ion Batteries Wang, Hong; Liao, Xiao-Zhen; Yang, Yang Journal of The Electrochemical Society, Vol. 163, Issue 3 https://doi.org/10.1149/2.0011605jes	journal	January 2016
O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries Li, Xin; Wu, Di; Zhou, Yong-Ning Electrochemistry Communications, Vol. 49 https://doi.org/10.1016/j.elecom.2014.10.003	journal	December 2014
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3309	journal	April 2012
O3-type NaNi0·33Li0·11Ti0·56O2-based electrode for symmetric sodium ion cell Zhang, Shuming; Liu, Yu; Zhang, Na Journal of Power Sources, Vol. 329 https://doi.org/10.1016/j.jpowsour.2016.08.066	journal	October 2016
High Capacity O3-Type Na[Li _0.05 (Ni _0.25 Fe _0.25 Mn _0.5 ) _0.95 ]O ₂ Cathode for Sodium Ion Batteries Oh, Seung-Min; Myung, Seung-Taek; Hwang, Jang-Yeon Chemistry of Materials, Vol. 26, Issue 21 https://doi.org/10.1021/cm502481b	journal	October 2014
Exploring the working mechanism of Li ⁺ in O3-type NaLi _0.1 Ni _0.35 Mn _0.55 O ₂ cathode materials for rechargeable Na-ion batteries Zheng, Shiyao; Zhong, Guiming; McDonald, Matthew J. Journal of Materials Chemistry A, Vol. 4, Issue 23 https://doi.org/10.1039/C6TA02230H	journal	January 2016
Exploring Li substituted O3-structured layered oxides NaLixNi1/3−xMn1/3+xCo1/3−xO2 (x = 0.07, 0.13, and 0.2) as promising cathode materials for rechargeable Na batteries Xu, Jing; Liu, Haodong; Meng, Ying Shirley Electrochemistry Communications, Vol. 60 https://doi.org/10.1016/j.elecom.2015.07.023	journal	November 2015
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Layered P2/O3 Intergrowth Cathode: Toward High Power Na-Ion Batteries Lee, Eungje; Lu, Jun; Ren, Yang Advanced Energy Materials, Vol. 4, Issue 17 https://doi.org/10.1002/aenm.201400458	journal	July 2014
Stable layered P3/P2 Na _0.66 Co _0.5 Mn _0.5 O ₂ cathode materials for sodium-ion batteries Chen, Xiaoqing; Zhou, Xianlong; Hu, Meng Journal of Materials Chemistry A, Vol. 3, Issue 41 https://doi.org/10.1039/C5TA05205J	journal	January 2015
Layered P2–O3 sodium-ion cathodes derived from earth abundant elements Bianchini, Marco; Gonzalo, Elena; Drewett, Nicholas E. Journal of Materials Chemistry A, Vol. 6, Issue 8 https://doi.org/10.1039/C7TA11180K	journal	January 2018
High stable post-spinel NaMn ₂ O ₄ cathode of sodium ion battery Liu, Xizheng; Wang, Xi; Iyo, Akira J. Mater. Chem. A, Vol. 2, Issue 36 https://doi.org/10.1039/C4TA03349C	journal	January 2014
Phase Stability of Post-spinel Compound AMn ₂ O ₄ (A = Li, Na, or Mg) and Its Application as a Rechargeable Battery Cathode Ling, Chen; Mizuno, Fuminori Chemistry of Materials, Vol. 25, Issue 15 https://doi.org/10.1021/cm401250c	journal	July 2013
Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P. Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0201514jes	journal	January 2015
Role of Ligand-to-Metal Charge Transfer in O3-Type NaFeO ₂ –NaNiO ₂ Solid Solution for Enhanced Electrochemical Properties Wang, Xianfen; Liu, Guandong; Iwao, Tatsumi The Journal of Physical Chemistry C, Vol. 118, Issue 6 https://doi.org/10.1021/jp411382r	journal	January 2014
Studies of a layered-spinel Li[Ni1/3Mn2/3]O2 cathode material for Li-ion batteries synthesized by a hydrothermal precipitation Nayak, Prasant Kumar; Grinblat, Judith; Levi, Mikhael Materials Science and Engineering: B, Vol. 213 https://doi.org/10.1016/j.mseb.2016.04.012	journal	November 2016
Jahn–Teller Assisted Na Diffusion for High Performance Na Ion Batteries Li, Xin; Wang, Yan; Wu, Di Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b02440	journal	September 2016
In Operando XRD and TXM Study on the Metastable Structure Change of NaNi _1/3 Fe _1/3 Mn _1/3 O ₂ under Electrochemical Sodium-Ion Intercalation Xie, Yingying; Wang, Hong; Xu, Guiliang Advanced Energy Materials, Vol. 6, Issue 24 https://doi.org/10.1002/aenm.201601306	journal	September 2016
Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi _{¹ / ₃} Mn _{¹ / ₃} Co _{¹ / ₃} O ₂ Sathiya, M.; Hemalatha, K.; Ramesha, K. Chemistry of Materials, Vol. 24, Issue 10 https://doi.org/10.1021/cm300466b	journal	April 2012
Synthesis and Stoichiometry of Different Layered Sodium Cobalt Oxides Lei, Yuechuan; Li, Xin; Liu, Lei Chemistry of Materials, Vol. 26, Issue 18 https://doi.org/10.1021/cm5021788	journal	September 2014
Investigation of solid electrolyte interface (SEI) film on LiCoO2 cathode in fluoroethylene carbonate (FEC)-containing electrolyte by 2D correlation X-ray photoelectron spectroscopy (XPS) Park, Yeonju; Shin, Su Hyun; Hwang, Hoon Journal of Molecular Structure, Vol. 1069 https://doi.org/10.1016/j.molstruc.2014.01.041	journal	July 2014
Formation of SEI on Cycled Lithium-Ion Battery Cathodes: Soft X-Ray Absorption Study Balasubramanian, M.; Lee, H. S.; Sun, X. Electrochemical and Solid-State Letters, Vol. 5, Issue 1 https://doi.org/10.1149/1.1423802	journal	January 2002
Electrolyte Reactions with the Surface of High Voltage LiNi[sub 0.5]Mn[sub 1.5]O[sub 4] Cathodes for Lithium-Ion Batteries Yang, Li; Ravdel, Boris; Lucht, Brett L. Electrochemical and Solid-State Letters, Vol. 13, Issue 8 https://doi.org/10.1149/1.3428515	journal	January 2010
Study on the Reversible Electrode Reaction of Na _{1– x} Ni _0.5 Mn _0.5 O ₂ for a Rechargeable Sodium-Ion Battery Komaba, Shinichi; Yabuuchi, Naoaki; Nakayama, Tetsuri Inorganic Chemistry, Vol. 51, Issue 11 https://doi.org/10.1021/ic300357d	journal	May 2012
Unexpected performance of layered sodium-ion cathode material in ionic liquid-based electrolyte Chagas, Luciana Gomes; Buchholz, Daniel; Wu, Liming Journal of Power Sources, Vol. 247 https://doi.org/10.1016/j.jpowsour.2013.08.118	journal	February 2014
Characterization of a P2-type chelating-agent-assisted Na _2/3 Fe _1/2 Mn _1/2 O ₂ cathode material for sodium-ion batteries Park, Kwangjin; Han, Dongwook; Kim, Hyunjin RSC Adv., Vol. 4, Issue 43 https://doi.org/10.1039/C4RA01391C	journal	January 2014
Synthesis and Characterization of High-Energy, High-Power Spinel-Layered Composite Cathode Materials for Lithium-Ion Batteries Bhaskar, Aiswarya; Krueger, Steffen; Siozios, Vassilios Advanced Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aenm.201401156	journal	November 2014
Li-Rich Layered/Spinel Heterostructured Special Morphology Cathode Material with High Rate Capability for Li-Ion Batteries Yi, Lanhua; Liu, Zhongshu; Yu, Ruizhi ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11 https://doi.org/10.1021/acssuschemeng.7b02906	journal	October 2017
A New Spinel-Layered Li-Rich Microsphere as a High-Rate Cathode Material for Li-Ion Batteries Luo, Dong; Li, Guangshe; Fu, Chaochao Advanced Energy Materials, Vol. 4, Issue 11 https://doi.org/10.1002/aenm.201400062	journal	April 2014
Electrochemical Performance of a Layered-Spinel Integrated Li[Ni _1/3 Mn _2/3 ]O ₂ as a High Capacity Cathode Material for Li-Ion Batteries Nayak, Prasant Kumar; Grinblat, Judith; Levi, Mikhael D. Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/acs.chemmater.5b00405	journal	March 2015
High-Capacity Layered-Spinel Cathodes for Li-Ion Batteries Nayak, Prasant Kumar; Levi, Elena; Grinblat, Judith ChemSusChem, Vol. 9, Issue 17 https://doi.org/10.1002/cssc.201600576	journal	August 2016
Ti-Substituted NaNi _0.5 Mn _0.5- _x Ti _x O ₂ Cathodes with Reversible O3−P3 Phase Transition for High-Performance Sodium-Ion Batteries Wang, Peng-Fei; Yao, Hu-Rong; Liu, Xin-Yu Advanced Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adma.201700210	journal	March 2017
The application of synchrotron techniques to the study of lithium-ion batteries McBreen, James Journal of Solid State Electrochemistry, Vol. 13, Issue 7 https://doi.org/10.1007/s10008-008-0685-1	journal	October 2008
Investigation of the Charge Compensation Mechanism on the Electrochemically Li-Ion Deintercalated Li ₁ _- _x Co _1/3 Ni _1/3 Mn _1/3 O ₂ Electrode System by Combination of Soft and Hard X-ray Absorption Spectroscopy Yoon, Won-Sub; Balasubramanian, Mahalingam; Chung, Kyung Yoon Journal of the American Chemical Society, Vol. 127, Issue 49 https://doi.org/10.1021/ja0530568	journal	December 2005
Revealing and suppressing surface Mn(II) formation of Na0.44MnO2 electrodes for Na-ion batteries Qiao, Ruimin; Dai, Kehua; Mao, Jing Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.06.024	journal	September 2015
In situ X-ray absorption spectroscopic study of Li-rich layered cathode material Li[Ni0.17Li0.2Co0.07Mn0.56]O2 Ito, Atsushi; Sato, Yuichi; Sanada, Takashi Journal of Power Sources, Vol. 196, Issue 16 https://doi.org/10.1016/j.jpowsour.2010.09.105	journal	August 2011
Advanced Na[Ni _0.25 Fe _0.5 Mn _0.25 ]O ₂ /C–Fe ₃ O ₄ Sodium-Ion Batteries Using EMS Electrolyte for Energy Storage Oh, Seung-Min; Myung, Seung-Taek; Yoon, Chong Seung Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl500077v	journal	February 2014
A quinary layer transition metal oxide of NaNi _1/4 Co _1/4 Fe _1/4 Mn _1/8 Ti _1/8 O ₂ as a high-rate-capability and long-cycle-life cathode material for rechargeable sodium ion batteries Yue, Ji-Li; Yin, Wen-Wen; Cao, Ming-Hui Chemical Communications, Vol. 51, Issue 86 https://doi.org/10.1039/C5CC06585B	journal	January 2015
In Situ Electrochemical XAFS Studies on an Iron Fluoride High-Capacity Cathode Material for Rechargeable Lithium Batteries Zhang, Wei; Duchesne, Paul N.; Gong, Zheng-Liang The Journal of Physical Chemistry C, Vol. 117, Issue 22 https://doi.org/10.1021/jp401200u	journal	May 2013
Effect of Chemical Extraction of Lithium on the Local Structure of Spinel Lithium Manganese Oxides Determined by X-ray Absorption Spectroscopy Ammundsen, Brett; Jones, Deborah J.; Rozière, Jacques Chemistry of Materials, Vol. 8, Issue 12 https://doi.org/10.1021/cm960287s	journal	January 1996
Synchrotron X-ray Analytical Techniques for Studying Materials Electrochemistry in Rechargeable Batteries Lin, Feng; Liu, Yijin; Yu, Xiqian Chemical Reviews, Vol. 117, Issue 21 https://doi.org/10.1021/acs.chemrev.7b00007	journal	September 2017
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering Yang, Wanli; Devereaux, Thomas P. Journal of Power Sources, Vol. 389 https://doi.org/10.1016/j.jpowsour.2018.04.018	journal	June 2018
Profiling the nanoscale gradient in stoichiometric layered cathode particles for lithium-ion batteries Lin, Feng; Nordlund, Dennis; Markus, Isaac M. Energy & Environmental Science, Vol. 7, Issue 9 https://doi.org/10.1039/C4EE01400F	journal	January 2014
Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy Liu, Xiaosong; Wang, Dongdong; Liu, Gao Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3568	journal	October 2013
Direct evidence of gradient Mn(II) evolution at charged states in LiNi0.5Mn1.5O4 electrodes with capacity fading Qiao, Ruimin; Wang, Yuesheng; Olalde-Velasco, Paul Journal of Power Sources, Vol. 273 https://doi.org/10.1016/j.jpowsour.2014.10.013	journal	January 2015
Preparation of a new crystal form of manganese dioxide: λ-MnO₂ Hunter, James C. Journal of Solid State Chemistry, Vol. 39, Issue 2, p. 142-147 https://doi.org/10.1016/0022-4596(81)90323-6	journal	September 1981
Soft X-ray XANES studies of various phases related to LiFePO4 based cathode materials Yang, Songlan; Wang, Dongniu; Liang, Guoxian Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee03445j	journal	January 2012
Empirical bond-strength–bond-length curves for oxides Brown, I. D.; Shannon, R. D. Acta Crystallographica Section A, Vol. 29, Issue 3 https://doi.org/10.1107/S0567739473000689	journal	May 1973
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/s0909049500016964	journal	March 2001

Cited By (2)

Ni-based cathode materials for Na-ion batteries Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan Nano Research, Vol. 12, Issue 9 https://doi.org/10.1007/s12274-019-2451-3	journal	June 2019
Layer‐Based Heterostructured Cathodes for Lithium‐Ion and Sodium‐Ion Batteries Deng, Ya‐Ping; Wu, Zhen‐Guo; Liang, Ruilin Advanced Functional Materials, Vol. 29, Issue 19 https://doi.org/10.1002/adfm.201808522	journal	February 2019

Figures / Tables (5)

Similar Records

Li-substituted layered spinel cathode materials for sodium ion batteries

Patent · Tue Nov 02 00:00:00 EDT 2021 · OSTI ID:1542342

Xiong, Hui; Deng, Changjian; Xu, Jing

Insight into Ca-Substitution Effects on O3-Type NaNi_1/3Fe_1/3Mn_1/3O₂ Cathode Materials for Sodium-Ion Batteries Application

Journal Article · Wed Apr 18 00:00:00 EDT 2018 · Small · OSTI ID:1542342

Sun, Liqi; Xie, Yingying; Liao, Xiao-Zhen; +9 more

Boosting electrochemical reaction and suppressing phase transition with a high-entropy O3-type layered oxide for sodium-ion batteries

Journal Article · Fri Jun 17 00:00:00 EDT 2022 · Journal of Materials Chemistry. A · OSTI ID:1542342

Tian, Kanghui; He, Huan; Li, Xiao; +6 more

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Intergrowth
layered oxide
spinel
cathode
sodium ion battery