Sorption of Np (V) by U (VI) hydroxide solids
Conference
·
OSTI ID:14942
- LLNL
The distribution of {sup 237}Np(V) between aqueous NaHCO{sub 3} solutions and U(VI) hydroxide solids was investigated. Experiments were initiated by addition of U solids to Np solutions and by coprecipitation of U and Np. Analysis by U L{sub III} extended X-ray absorption fine structure (EXAFS) spectroscopy and infrared absorption spectroscopy indicated the solid phase was synthetic schoepite. Equilibrium Np distribution coefficients were 5-44 mL/g in the pH range 6-8. The results are consistent with adsorption of Np by the solids and provide no evidence of Np incorporation in the bulk solid.
- Research Organization:
- Lawrence Livermore National Lab., CA (US)
- Sponsoring Organization:
- USDOE Office of Defense Programs (DP) (US)
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 14942
- Report Number(s):
- UCRL-JC-135791; YN0100000; YN0100000
- Country of Publication:
- United States
- Language:
- English
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