Amination of 1-hexanol on bimetallic AuPd/TiO2 catalysts

Ball, Madelyn R.; Wesley, Thejas S.; Rivera-Dones, Keishla R.; Huber, George W.; Dumesic, James A.

doi:10.1039/C8GC02321B

Amination of 1-hexanol on bimetallic AuPd/TiO₂ catalysts

Journal Article · Sun Dec 31 23:00:00 EST 2017 · Green Chemistry

DOI:https://doi.org/10.1039/C8GC02321B· OSTI ID:1493774

^[1]; ^[1]; Rivera-Dones, Keishla R. ^[1]; ^[1]; ^[1]

Department of Chemical and Biological Engineering; University of Wisconsin-Madison; Madison; USA

AuPd/TiO₂bimetallic catalysts, synthesized using controlled surface reactions, exhibit enhanced rates for amination of hexanol using ammonia compared to monometallic Au and Pd catalysts.

Research Organization:: Advanced Photon Source (APS), Argonne National Laboratory (ANL), Argonne, IL (US)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

OSTI ID:: 1493774

Journal Information:: Green Chemistry, Journal Name: Green Chemistry Journal Issue: 20 Vol. 20; ISSN GRCHFJ; ISSN 1463-9262

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: ENGLISH

References (92)

Development of transition-state theory Laidler, Keith J.; King, M. Christine The Journal of Physical Chemistry, Vol. 87, Issue 15 https://doi.org/10.1021/j100238a002	journal	July 1983
Orbital mixing in CO chemisorption on transition metal surfaces Hu, P.; King, D. A.; Lee, M. -H. Chemical Physics Letters, Vol. 246, Issue 1-2 https://doi.org/10.1016/0009-2614(95)01070-P	journal	November 1995
Preparation and characterization of silica-supported, group IB–Pd bimetallic catalysts prepared by electroless deposition methods Rebelli, Jayakiran; Rodriguez, Abraham A.; Ma, Shuguo Catalysis Today, Vol. 160, Issue 1 https://doi.org/10.1016/j.cattod.2010.06.011	journal	February 2011
Scalable synthesis of secondary and tertiary amines by heterogeneous Pt-Sn/γ-Al2O3 catalyzed N-alkylation of amines with alcohols Wu, Kaikai; He, Wei; Sun, Chenglin Tetrahedron, Vol. 72, Issue 51 https://doi.org/10.1016/j.tet.2016.11.029	journal	December 2016
Structure of Supported PdAu Clusters Determined by X-ray Absorption Spectroscopy Davis, Robert J.; Boudart, Michel The Journal of Physical Chemistry, Vol. 98, Issue 21 https://doi.org/10.1021/j100072a012	journal	May 1994
Highly Efficient Heterogeneous Gold-catalyzed Direct Synthesis of Tertiary and Secondary Amines from Alcohols and Urea He, Lin; Qian, Yue; Ding, Ran-Sheng ChemSusChem, Vol. 5, Issue 4 https://doi.org/10.1002/cssc.201100581	journal	March 2012
Catalytic reaction rates in thermodynamically non-ideal systems Madon, Rostam J.; Iglesia, Enrique Journal of Molecular Catalysis A: Chemical, Vol. 163, Issue 1-2 https://doi.org/10.1016/S1381-1169(00)00386-1	journal	December 2000
Structure of catalytically active Rh–In bimetallic phase for amination of alcohols Takanashi, Tsukasa; Tamura, Masazumi; Nakagawa, Yoshinao RSC Advances, Vol. 4, Issue 54 https://doi.org/10.1039/c4ra03984j	journal	January 2014
An Efficient and General Synthesis of Primary Amines by Ruthenium-Catalyzed Amination of Secondary Alcohols with Ammonia Imm, Sebastian; Bähn, Sebastian; Neubert, Lorenz Angewandte Chemie International Edition, Vol. 49, Issue 44 https://doi.org/10.1002/anie.201002576	journal	August 2010
Surface segregation energies in transition-metal alloys Ruban, A. V.; Skriver, H. L.; Nørskov, J. K. Physical Review B, Vol. 59, Issue 24 https://doi.org/10.1103/PhysRevB.59.15990	journal	June 1999
CO Adsorption on Pd Nanoparticles: Density Functional and Vibrational Spectroscopy Studies Yudanov, Ilya V.; Sahnoun, Riadh; Neyman, Konstantin M. The Journal of Physical Chemistry B, Vol. 107, Issue 1 https://doi.org/10.1021/jp022052b	journal	January 2003
Platinum-Based Oxygen Reduction Electrocatalysts Wu, Jianbo; Yang, Hong Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300359w	journal	April 2013
Supported ?bimetallic cluster? catalysts Sinfelt, J. Journal of Catalysis, Vol. 29, Issue 2 https://doi.org/10.1016/0021-9517(73)90234-0	journal	May 1973
Au Promotional Effects on the Synthesis of H ₂ O ₂ Directly from H ₂ and O ₂ on Supported Pd−Au Alloy Catalysts Han, Yi-Fan; Zhong, Ziyi; Ramesh, Kanaparthi The Journal of Physical Chemistry C, Vol. 111, Issue 24 https://doi.org/10.1021/jp072934g	journal	June 2007
Catalysis by alloys and bimetallic clusters Sinfelt, John H. Accounts of Chemical Research, Vol. 10, Issue 1 https://doi.org/10.1021/ar50109a003	journal	January 1977
CO Oxidation over AuPd(100) from Ultrahigh Vacuum to Near-Atmospheric Pressures: CO Adsorption-Induced Surface Segregation and Reaction Kinetics Gao, Feng; Wang, Yilin; Goodman, D. Wayne The Journal of Physical Chemistry C, Vol. 113, Issue 33 https://doi.org/10.1021/jp9053132	journal	July 2009
Dependence of stretching frequency on surface coverage and adsorbate–adsorbate interactions: a density-functional theory approach of CO on Pd (111) Loffreda, D.; Simon, D.; Sautet, P. Surface Science, Vol. 425, Issue 1 https://doi.org/10.1016/S0039-6028(99)00186-7	journal	April 1999
The Composition and Structure of Pd−Au Surfaces Yi, C. -W.; Luo, K.; Wei, T. The Journal of Physical Chemistry B, Vol. 109, Issue 39 https://doi.org/10.1021/jp053515r	journal	October 2005
Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution Lu, Qi; Hutchings, Gregory S.; Yu, Weiting Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7567	journal	March 2015
Study of adsorption states and interactions of CO on evaporated noble metal surfaces by infrared absorption spectroscopy Dumas, P.; Tobin, R. G.; Richards, P. L. Surface Science, Vol. 171, Issue 3 https://doi.org/10.1016/0039-6028(86)91061-7	journal	June 1986
Bimetallic Au–Pd Alloy Catalysts for N ₂ O Decomposition: Effects of Surface Structures on Catalytic Activity Wei, Xing; Yang, Xiao-Feng; Wang, Ai-Qin The Journal of Physical Chemistry C, Vol. 116, Issue 10 https://doi.org/10.1021/jp210555s	journal	March 2012
Facile preparation of Ni/Al2O3 catalytic formulations with the aid of cyclodextrin complexes: Towards highly active and robust catalysts for the direct amination of alcohols Tomer, Ajay; Wyrwalski, Frédéric; Przybylski, Cédric Journal of Catalysis, Vol. 356 https://doi.org/10.1016/j.jcat.2017.10.006	journal	December 2017
Supported bimetallic nano-alloys as highly active catalysts for the one-pot tandem synthesis of imines and secondary amines from nitrobenzene and alcohols Sankar, Meenakshisundaram; He, Qian; Dawson, Simon Catalysis Science & Technology, Vol. 6, Issue 14 https://doi.org/10.1039/C6CY00425C	journal	January 2016
Interactions of CO molecules adsorbed on gold France, J.; Hollins, P. Journal of Electron Spectroscopy and Related Phenomena, Vol. 64-65 https://doi.org/10.1016/0368-2048(93)80086-2	journal	December 1993
Advances in One-Pot Synthesis through Borrowing Hydrogen Catalysis Corma, Avelino; Navas, Javier; Sabater, Maria J. Chemical Reviews, Vol. 118, Issue 4 https://doi.org/10.1021/acs.chemrev.7b00340	journal	January 2018
Kinetics of Heterogeneous Catalytic Reactions Boudart, Michel; Djega-Mariadassou, G. https://doi.org/10.1515/9781400853335	book	January 1984
Ligand and ensemble effects in adsorption on alloy surfaces Liu, P.; Nørskov, J. K. Physical Chemistry Chemical Physics, Vol. 3, Issue 17 https://doi.org/10.1039/b103525h	journal	January 2001
The chemisorption of carbon monoxide on palladium single crystal surfaces: IR spectroscopic evidence for localised site adsorption Bradshaw, A. M.; Hoffmann, F. M. Surface Science, Vol. 72, Issue 3 https://doi.org/10.1016/0039-6028(78)90367-9	journal	April 1978
The Second Rideal Lecture. What makes a catalyst selective ? Sachtler, Wolfgang M. H. Faraday Discussions of the Chemical Society, Vol. 72 https://doi.org/10.1039/dc9817200007	journal	January 1981
Synergistic Catalysis over Bimetallic Alloy Nanoparticles Singh, Ashish Kumar; Xu, Qiang ChemCatChem, Vol. 5, Issue 3 https://doi.org/10.1002/cctc.201200591	journal	January 2013
Insight into active sites of Pd–Au/TiO2 catalysts in hydrogen peroxide synthesis directly from H2 and O2 Ouyang, Like; Da, Guo-jin; Tian, Peng-fei Journal of Catalysis, Vol. 311 https://doi.org/10.1016/j.jcat.2013.11.008	journal	March 2014
PtMo Bimetallic Catalysts Synthesized by Controlled Surface Reactions for Water Gas Shift Sener, Canan; Wesley, Thejas S.; Alba-Rubio, Ana C. ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b02028	journal	January 2016
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D. Science, Vol. 335, Issue 6073 https://doi.org/10.1126/science.1215864	journal	March 2012
Synthesis Gas Conversion over Rh-Based Catalysts Promoted by Fe and Mn Liu, Yifei; Göeltl, Florian; Ro, Insoo ACS Catalysis, Vol. 7, Issue 7 https://doi.org/10.1021/acscatal.7b01381	journal	June 2017
Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide Tauster, S. J.; Fung, S. C.; Garten, R. L. Journal of the American Chemical Society, Vol. 100, Issue 1 https://doi.org/10.1021/ja00469a029	journal	January 1978
Atomic Layer-by-Layer Deposition of Pt on Pd Nanocubes for Catalysts with Enhanced Activity and Durability toward Oxygen Reduction Xie, Shuifen; Choi, Sang-Il; Lu, Ning Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl501205j	journal	May 2014
Ligand and ensemble effects in the adsorption of carbon monoxide on supported palladium-gold alloys Kugler, E.; Boudart, M. Journal of Catalysis, Vol. 59, Issue 2 https://doi.org/10.1016/S0021-9517(79)80025-1	journal	October 1979
Design of a Surface Alloy Catalyst for Steam Reforming Besenbacher, F. Science, Vol. 279, Issue 5358 https://doi.org/10.1126/science.279.5358.1913	journal	March 1998
Effect of Zn addition on the water–gas shift reaction over supported palladium catalysts Bollmann, L.; Ratts, J.; Joshi, A. Journal of Catalysis, Vol. 257, Issue 1 https://doi.org/10.1016/j.jcat.2008.04.005	journal	July 2008
A kinetic study of vinyl acetate synthesis over Pd-based catalysts: kinetics of vinyl acetate synthesis over Pd–Au/SiO and Pd/SiO catalysts Han, Y.; Wang, J.; Kumar, D. Journal of Catalysis, Vol. 232, Issue 2 https://doi.org/10.1016/j.jcat.2005.04.001	journal	June 2005
Pt-Sn/γ-Al2O3-Catalyzed Highly Efficient Direct Synthesis of Secondary and Tertiary Amines and Imines He, Wei; Wang, Liandi; Sun, Chenglin Chemistry - A European Journal, Vol. 17, Issue 47 https://doi.org/10.1002/chem.201101725	journal	October 2011
Catalysts synthesized by selective deposition of Fe onto Pt for the water-gas shift reaction Aragao, Isaias Barbosa; Ro, Insoo; Liu, Yifei Applied Catalysis B: Environmental, Vol. 222 https://doi.org/10.1016/j.apcatb.2017.10.004	journal	March 2018
Pd, Cu, and Au particles on Al2O3 thin films: An infrared reflection absorption spectroscopy study of monometallic and bimetallic planar model supported catalysts Rainer, D. R.; Xu, C.; Holmblad, P. M. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 15, Issue 3 https://doi.org/10.1116/1.580648	journal	May 1997
Synthesis of supported bimetallic nanoparticles with controlled size and composition distributions for active site elucidation Hakim, Sikander H.; Sener, Canan; Alba-Rubio, Ana C. Journal of Catalysis, Vol. 328 https://doi.org/10.1016/j.jcat.2014.12.015	journal	August 2015
Bimetallic Surface Chemistry Campbell, C. T. Annual Review of Physical Chemistry, Vol. 41, Issue 1 https://doi.org/10.1146/annurev.pc.41.100190.004015	journal	October 1990
Bimetallic catalysts for upgrading of biomass to fuels and chemicals Alonso, David Martin; Wettstein, Stephanie G.; Dumesic, James A. Chemical Society Reviews, Vol. 41, Issue 24, p. 8075-8098 https://doi.org/10.1039/c2cs35188a	journal	January 2012
N-alkylation of ammonia and amines with alcohols catalyzed by Ni-loaded CaSiO3 Shimizu, Ken-ichi; Kanno, Shota; Kon, Kenichi Catalysis Today, Vol. 232 https://doi.org/10.1016/j.cattod.2013.09.002	journal	September 2014
Selective hydrogenation of acetylene in excess ethylene using Ag- and Au–Pd/SiO2 bimetallic catalysts prepared by electroless deposition Zhang, Yunya; Diao, Weijian; Williams, Christopher T. Applied Catalysis A: General, Vol. 469 https://doi.org/10.1016/j.apcata.2013.10.024	journal	January 2014
Selective Hydrogenation of Unsaturated Carbon–Carbon Bonds in Aromatic-Containing Platform Molecules Schwartz, Thomas J.; Lyman, Spencer D.; Motagamwala, Ali Hussain ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.6b00072	journal	February 2016
Methane reforming to synthesis gas over Ni catalysts modified with noble metals Li, Dalin; Nakagawa, Yoshinao; Tomishige, Keiichi Applied Catalysis A: General, Vol. 408, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.09.018	journal	November 2011
CO Adsorption and Reaction on Clean and Oxygen-Covered Au(211) Surfaces Kim, Jooho; Samano, Enrique; Koel, Bruce E. The Journal of Physical Chemistry B, Vol. 110, Issue 35 https://doi.org/10.1021/jp061685d	journal	September 2006
Reverse Water–Gas Shift on Interfacial Sites Formed by Deposition of Oxidized Molybdenum Moieties onto Gold Nanoparticles Carrasquillo-Flores, Ronald; Ro, Insoo; Kumbhalkar, Mrunmayi D. Journal of the American Chemical Society, Vol. 137, Issue 32 https://doi.org/10.1021/jacs.5b05945	journal	August 2015
The Catalytic Amination of Alcohols Bähn, Sebastian; Imm, Sebastian; Neubert, Lorenz ChemCatChem, Vol. 3, Issue 12 https://doi.org/10.1002/cctc.201100255	journal	October 2011
Effect of molybdenum addition on supported platinum catalysts for the water–gas shift reaction Williams, W. Damion; Bollmann, Luis; Miller, Jeffrey T. Applied Catalysis B: Environmental, Vol. 125 https://doi.org/10.1016/j.apcatb.2012.05.037	journal	August 2012
Amination of Alcohols with Ammonia in Water over Rh–In Catalyst Takanashi, Tsukasa; Nakagawa, Yoshinao; Tomishige, Keiichi Chemistry Letters, Vol. 43, Issue 6 https://doi.org/10.1246/cl.140051	journal	June 2014
Molecular Orbital View of Chemisorbed Carbon Monoxide Blyholder, George The Journal of Physical Chemistry, Vol. 68, Issue 10 https://doi.org/10.1021/j100792a006	journal	October 1964
The effect of heat treatment on the performance and structure of carbon-supported Au–Pd catalysts for the direct synthesis of hydrogen peroxide Edwards, Jennifer K.; Pritchard, James; Piccinini, Marco Journal of Catalysis, Vol. 292 https://doi.org/10.1016/j.jcat.2012.05.018	journal	August 2012
Preparation of Highly Dispersed Pt Particles in Zeolite Y with a Narrow Particle Size Distribution: Characterization by Hydrogen Chemisorption, TEM, EXAFS Spectroscopy, and Particle Modeling de Graaf, J.; van Dillen, A. J.; de Jong, K. P. Journal of Catalysis, Vol. 203, Issue 2 https://doi.org/10.1006/jcat.2001.3337	journal	October 2001
Enhanced activity of Pd/TiO2 catalysts for the CO/H2 reaction in the absence of strong metal-support interactions (SMSI) Bracey, J. Journal of Catalysis, Vol. 86, Issue 2 https://doi.org/10.1016/0021-9517(84)90383-X	journal	April 1984
New insight on the nature of catalytically active gold sites: Quantitative CO chemisorption data and analysis of FTIR spectra of adsorbed CO and of isotopic mixtures Chiorino, Anna; Manzoli, Maela; Menegazzo, Federica Journal of Catalysis, Vol. 262, Issue 1 https://doi.org/10.1016/j.jcat.2008.12.017	journal	February 2009
Biphasic Pd−Au Alloy Catalyst for Low-Temperature CO Oxidation Xu, Jing; White, Tim; Li, Ping Journal of the American Chemical Society, Vol. 132, Issue 30 https://doi.org/10.1021/ja102617r	journal	August 2010
Designing bimetallic catalysts for a green and sustainable future Sankar, Meenakshisundaram; Dimitratos, Nikolaos; Miedziak, Peter J. Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35296f	journal	January 2012
A View from the Inside: Complexity in the Atomic Scale Ordering of Supported Metal Nanoparticles Frenkel, Anatoly I.; Hills, Charles W.; Nuzzo, Ralph G. The Journal of Physical Chemistry B, Vol. 105, Issue 51 https://doi.org/10.1021/jp012769j	journal	December 2001
Pd–Au bimetallic catalysts: understanding alloy effects from planar models and (supported) nanoparticles Gao, Feng; Goodman, D. Wayne Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35160a	journal	January 2012
Selectivity in Catalysis by Alloys Ponec, V. Catalysis Reviews, Vol. 11, Issue 1 https://doi.org/10.1080/01614947508079981	journal	January 1975
Catalytic Enantioselective Amination of Alcohols by the Use of Borrowing Hydrogen Methodology: Cooperative Catalysis by Iridium and a Chiral Phosphoric Acid Zhang, Yao; Lim, Ching-Si; Sim, Derek Sui Boon Angewandte Chemie International Edition, Vol. 53, Issue 5 https://doi.org/10.1002/anie.201307789	journal	December 2013
Determination of IR extinction coefficients for linear- and bridged-bonded carbon monoxide on supported palladium Vannice, M. A.; Wang, S. Y. The Journal of Physical Chemistry, Vol. 85, Issue 17 https://doi.org/10.1021/j150617a026	journal	August 1981
CO Adsorption-Driven Surface Segregation of Pd on Au/Pd Bimetallic Surfaces: Role of Defects and Effect on CO Oxidation Kim, Hyun You; Henkelman, Graeme ACS Catalysis, Vol. 3, Issue 11 https://doi.org/10.1021/cs4006259	journal	October 2013
Variation of SMSI with the Au:Pd Ratio of Bimetallic Nanoparticles on TiO2(110) Gubó, Richard; Yim, Chi M.; Allan, Michael Topics in Catalysis, Vol. 61, Issue 5-6 https://doi.org/10.1007/s11244-017-0854-5	journal	September 2017
Direct Synthesis of Hydrogen Peroxide Over Au–Pd Catalysts Prepared by Electroless Deposition Alba-Rubio, Ana C.; Plauck, Anthony; Stangland, Eric E. Catalysis Letters, Vol. 145, Issue 12 https://doi.org/10.1007/s10562-015-1621-5	journal	September 2015
Heterogeneous Ni Catalyst for Direct Synthesis of Primary Amines from Alcohols and Ammonia Shimizu, Ken-ichi; Kon, Kenichi; Onodera, Wataru ACS Catalysis, Vol. 3, Issue 1 https://doi.org/10.1021/cs3007473	journal	December 2012
Catalytic hydrogenolysis and dehydrogenation over copper-nickel alloys Sinfelt, J. Journal of Catalysis, Vol. 24, Issue 2 https://doi.org/10.1016/0021-9517(72)90072-3	journal	February 1972
Segregation at the surface of an Au/Pd alloy exposed to CO Soto-Verdugo, Víctor; Metiu, Horia Surface Science, Vol. 601, Issue 23 https://doi.org/10.1016/j.susc.2007.08.022	journal	December 2007
Microcalorimetric, Infrared Spectroscopic, and DFT Studies of Ethylene Adsorption on Pt/SiO ₂ and Pt−Sn/SiO ₂ Catalysts Shen, Jianyi; Hill, Josephine M.; Watwe, Ramchandra M. The Journal of Physical Chemistry B, Vol. 103, Issue 19 https://doi.org/10.1021/jp9902452	journal	May 1999
Study of CO adsorption on crystalline-silica-supported palladium particles Giorgi, Javier B.; Schroeder, Thomas; Bäumer, Marcus Surface Science, Vol. 498, Issue 1-2 https://doi.org/10.1016/S0039-6028(01)01756-3	journal	February 2002
Support Induced Control of Surface Composition in Cu–Ni/TiO ₂ Catalysts Enables High Yield Co-Conversion of HMF and Furfural to Methylated Furans Seemala, Bhogeswararao; Cai, Charles M.; Wyman, Charles E. ACS Catalysis, Vol. 7, Issue 6 https://doi.org/10.1021/acscatal.7b01095	journal	May 2017
Engineering Catalyst Microenvironments for Metal-Catalyzed Hydrogenation of Biologically Derived Platform Chemicals Schwartz, Thomas J.; Johnson, Robert L.; Cardenas, Javier Angewandte Chemie International Edition, Vol. 53, Issue 47 https://doi.org/10.1002/anie.201407615	journal	September 2014
Physical and chemical properties of bimetallic surfaces Rodriguez, José A. Surface Science Reports, Vol. 24, Issue 7-8, p. 223-287 https://doi.org/10.1016/0167-5729(96)00004-0	journal	January 1996
Ni–Ru bimetallic catalysts for the CO2 reforming of methane Crisafulli, Carmelo; Scirè, Salvatore; Minicò, Simona Applied Catalysis A: General, Vol. 225, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)00585-3	journal	February 2002
Mixed oxides supported low-nickel formulations for the direct amination of aliphatic alcohols with ammonia Tomer, A.; Yan, Z.; Ponchel, A. Journal of Catalysis, Vol. 356 https://doi.org/10.1016/j.jcat.2017.08.015	journal	December 2017
Borrowing Hydrogen in the Activation of Alcohols Hamid, Malai Haniti S. A.; Slatford, Paul A.; Williams, Jonathan M. J. Advanced Synthesis & Catalysis, Vol. 349, Issue 10 https://doi.org/10.1002/adsc.200600638	journal	July 2007
Shapes of optical spectra of solvated electrons. Effect of pressure Jou, Fang-Yuan; Freeman, Gordon R. The Journal of Physical Chemistry, Vol. 81, Issue 9 https://doi.org/10.1021/j100524a021	journal	May 1977
Amination of phenols with ammonia over palladium supported on alumina Ono, Y. Journal of Catalysis, Vol. 72, Issue 1 https://doi.org/10.1016/0021-9517(81)90083-X	journal	November 1981
Influence of the preparation method on the morphological and composition properties of Pd–Au/ZrO2 catalysts and their effect on the direct synthesis of hydrogen peroxide from hydrogen and oxygen Menegazzo, Federica; Signoretto, Michela; Manzoli, Maela Journal of Catalysis, Vol. 268, Issue 1 https://doi.org/10.1016/j.jcat.2009.09.010	journal	November 2009
Role of the Cu-ZrO ₂ Interfacial Sites for Conversion of Ethanol to Ethyl Acetate and Synthesis of Methanol from CO ₂ and H ₂ Ro, Insoo; Liu, Yifei; Ball, Madelyn R. ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b01805	journal	September 2016
CO Oxidation over AuPd(100) from Ultrahigh Vacuum to Near-Atmospheric Pressures: The Critical Role of Contiguous Pd Atoms Gao, Feng; Wang, Yilin; Goodman, D. Wayne Journal of the American Chemical Society, Vol. 131, Issue 16 https://doi.org/10.1021/ja9008437	journal	April 2009
Highly reproducible syntheses of active Au/TiO2 catalysts for CO oxidation by deposition–precipitation or impregnation Li, W.; Comotti, M.; Schuth, F. Journal of Catalysis, Vol. 237, Issue 1 https://doi.org/10.1016/j.jcat.2005.11.006	journal	January 2006
Infrared studies of chemisorbed layers on single crystals Hollins, P.; Pritchard, J. Progress in Surface Science, Vol. 19, Issue 4 https://doi.org/10.1016/0079-6816(85)90015-2	journal	January 1985
Structural Rearrangement of Au–Pd Nanoparticles under Reaction Conditions: An ab Initio Molecular Dynamics Study Xu, Cong-Qiao; Lee, Mal-Soon; Wang, Yang-Gang ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.6b07409	journal	January 2017
1,3-Butadiene selective hydrogenation over Pd/alumina and CuPd/alumina catalysts Furlong, Brian K.; Hightower, Joe W.; Chan, Tammy Y. -L. Applied Catalysis A: General, Vol. 117, Issue 1 https://doi.org/10.1016/0926-860X(94)80157-6	journal	September 1994
Direct n -octanol amination by ammonia on supported Ni and Pd catalysts: activity is enhanced by “spectator” ammonia adsorbates Dumon, Alexandre S.; Wang, Tao; Ibañez, Javier Catalysis Science & Technology, Vol. 8, Issue 2 https://doi.org/10.1039/C7CY02208E	journal	January 2018
Surface Structure and Reactivity in the Cyclization of Acetylene to Benzene with Pd Overlayers and Pd/Au Surface Alloys on Au{111} Baddeley, Christopher J.; Ormerod, R. Mark; Stephenson, Andrew W. The Journal of Physical Chemistry, Vol. 99, Issue 14 https://doi.org/10.1021/j100014a039	journal	April 1995

Similar Records

Amination of 1-hexanol on bimetallic AuPd/TiO ₂ catalysts

Journal Article · Mon Oct 15 00:00:00 EDT 2018 · Green Chemistry · OSTI ID:1475220

Selective Oxidation of Glycerol over Carbon-Supported AuPd Catalysts

Journal Article · Sun Dec 31 23:00:00 EST 2006 · Journal of Catalysis · OSTI ID:929926

Ethanol Electrooxidation at 1–2 nm AuPd Nanoparticles

Journal Article · Sun Nov 20 23:00:00 EST 2022 · Nanomaterials · OSTI ID:1899379

Amination of 1-hexanol on bimetallic AuPd/TiO2 catalysts

Citation Formats

References (92)

Similar Records

Related Subjects

Amination of 1-hexanol on bimetallic AuPd/TiO₂ catalysts