skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Metal-organic frameworks for aromatic hydrocarbon separations

Patent ·
OSTI ID:1493306

The disclosure provides for metal organic frameworks (MOFs) that are selective adsorbents for aromatic hydrocarbons, devices comprising the MOFs thereof, and methods using the MOFS thereof for separating and/or storing aromatic hydrocarbons.

Research Organization:
Univ. of California, Oakland, CA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0001015
Assignee:
The Regents of the University of California (Oakland, CA)
Patent Number(s):
10,118,877
Application Number:
14/957,494
OSTI ID:
1493306
Resource Relation:
Patent File Date: 2015 Dec 02
Country of Publication:
United States
Language:
English

References (154)

Reversible Ethylene Oxide Capture in Porous Frameworks patent-application February 2012
Crystallography of metal–organic frameworks journal October 2014
Solvent-Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal-Organic Frameworks journal March 2014
Bone graft composition patent-application October 2007
Process for preparing hydrogen peroxide from the elements patent-application April 2004
Covalently linked organic frameworks and polyhedra patent September 2009
Fluorinated metal-organic frameworks for gas storage patent January 2013
Metal−Organic Frameworks As Templates for Nanoscale NaAlH4
  • Bhakta, Raghunandan K.; Herberg, Julie L.; Jacobs, Benjamin
  • Journal of the American Chemical Society, Vol. 131, Issue 37, p. 13198-13199 https://doi.org/10.1021/ja904431x
journal September 2009
Donor-acceptor rotaxanes with tetracationic cyclophane ring journal September 2012
Covalent Organic Frameworks and Methods of Making Same patent-application May 2014
Two new metal–triazole-benzenedicarboxylate frameworks affording an uncommon 3,4-connected net and unique 4,6-connected rod packing: hydrothermal synthesis, structure, thermostability and luminescence studies journal January 2009
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent October 2007
Gas storage system patent December 2007
Crystalline membranes patent-application January 2005
Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine
  • Demessence, Aude; D’Alessandro, Deanna M.; Foo, Maw Lin
  • Journal of the American Chemical Society, Vol. 131, Issue 25, p. 8784-8786 https://doi.org/10.1021/ja903411w
journal July 2009
High gas adsorption in a microporous metal-organic framework with open-metal sites patent-application November 2006
Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide journal January 2009
Reticular Synthesis of Microporous and Mesoporous 2D Covalent Organic Frameworks
  • Côté, Adrien P.; El-Kaderi, Hani M.; Furukawa, Hiroyasu
  • Journal of the American Chemical Society, Vol. 129, Issue 43, p. 12914-12915 https://doi.org/10.1021/ja0751781
journal October 2007
Metal catalyzed reactions patent February 2004
Porous Metal Organic Framework Based On Pyrroles And Pyridinones patent-application July 2009
CH4 storage and CO2 capture in highly porous zirconium oxide based metal–organic frameworks journal January 2012
Gas storage system patent-application December 2004
Preparation of metal-containing zeolite catalysts of increased stability and activity patent July 1985
Metal organic framework—polymer mixed matrix membranes patent December 2009
Polymerisation and oligomerisation catalysts patent June 2007
Oxidative Homo-Coupling Reactions of Aryl Boronic Acids Using a Porous Copper Metal-Organic Framework as a Highly Efficient Heterogeneous Catalyst patent-application May 2012
Implementation of a strategy for achieving extraordinary levels of surface area and porosity in crystals patent-application November 2004
Nanoporous three-dimensional networks topologically related to Cooperite from the self-assembly of copper(I) centres and the "‘square-planar’' building block 1,2,4,5-tetracyanobenzene journal January 1999
Porous, Conductive Metal-Triazolates and Their Structural Elucidation by the Charge-Flipping Method journal June 2012
Cu2O: A Versatile Reagent for Base-Free Direct Synthesis of NHC-Copper Complexes and Decoration of 3D-MOF with Coordinatively Unsaturated NHC-Copper Species journal April 2010
Gas sensor incorporating a porous framework patent May 2014
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application September 2005
Concomitant Formation of N-Heterocyclic Carbene−Copper Complexes within a Supramolecular Network in the Self-Assembly of Imidazolium Dicarboxylate with Metal Ions journal July 2009
Bleaching composition for dry cleaning containing transition metal bleach catalyst patent November 2002
Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids journal January 2005
A Crystalline Mesoporous Coordination Copolymer with High Microporosity journal January 2008
Reversible ethylene oxide capture in porous frameworks patent April 2014
Adsorption of Harmful Organic Vapors by Flexible Hydrophobic Bis-pyrazolate Based MOFs journal March 2010
Isoreticular synthesis and modification of frameworks with the UiO-66 topology journal January 2010
“Clickable” Metal−Organic Framework journal November 2008
Evaluating metal–organic frameworks for natural gas storage journal January 2014
Microporous Coordination Polymers as Novel Sorbents for Gas Separation patent-application October 2010
Gas sensor incorporating a porous framework patent July 2013
Large-Pore Apertures in a Series of Metal-Organic Frameworks journal May 2012
Mixed-component metal–organic frameworks (MC-MOFs): enhancing functionality through solid solution formation and surface modifications journal January 2011
Framework mobility in the metal–organic framework crystal IRMOF-3: Evidence for aromatic ring and amine rotation journal October 2011
Metal-Organic Frameworks with Exceptionally Large Pore Aperatures patent-application April 2013
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application April 2003
Gas Odorous Substance Separation patent-application August 2008
Synthesis of inorganic membranes on supports patent July 1998
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent August 2005
Separation of methane from higher carbon number hydrocarbons utilizing zeolitic imidazolate framework materials patent-application August 2009
Porous, Crystalline, Covalent Organic Frameworks journal November 2005
Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets journal September 2011
PREPARATION OF FUNCTIONALIZED ZEOLITIC FRAMEWORKS patent-application August 2007
Systematic Functionalization of a Metal−Organic Framework via a Postsynthetic Modification Approach journal July 2008
A zinc(ii) metal–organic framework based on triazole and dicarboxylate ligands for selective adsorption of hexane isomers journal January 2011
Highly porous and stable metal–organic frameworks for uranium extraction journal January 2013
Four Novel Three-Dimensional Triazole-Based Zinc(II) Metal−Organic Frameworks Controlled by the Spacers of Dicarboxylate Ligands: Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties journal October 2007
Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials journal September 2008
Metal-organic polyhedra patent-application June 2005
Chemical Modification of a Bridging Ligand Inside a Metal–Organic Framework while Maintaining the 3D Structure (Eur. J. Inorg. Chem. 10/2008) journal April 2008
Reversible Interpenetration in a Metal-Organic Framework Triggered by Ligand Removal and Addition journal July 2012
Zeolite synthesis using an alcohol or like molecules patent November 1992
Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates journal June 2009
Metal–Organic Frameworks with Precisely Designed Interior for Carbon Dioxide Capture in the Presence of Water
  • Fracaroli, Alejandro M.; Furukawa, Hiroyasu; Suzuki, Mitsuharu
  • Journal of the American Chemical Society, Vol. 136, Issue 25, p. 8863-8866 https://doi.org/10.1021/ja503296c
journal June 2014
Shaped bodies containing metal-organic frameworks patent May 2005
Metal-organic framework materials for gaseous hydrocarbon storage patent March 2008
Method of storing, uptaking, releasing of gases by novel framework materials patent-application August 2003
Process for preparing hydrogen peroxide from the elements patent-application March 2006
Metal-organic frameworks with exceptionally large pore aperatures patent July 2015
Zeolitic imidazolate framework materials: recent progress in synthesis and applications journal January 2014
Process for preparing and organometallic framework material patent August 2008
Homocoupling of Arylboronic Acids Catalyzed by 1,10-Phenanthroline-Ligated Copper Complexes in Air journal March 2009
Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene patent-application November 2011
A Multiunit Catalyst with Synergistic Stability and Reactivity: A Polyoxometalate–Metal Organic Framework for Aerobic Decontamination journal October 2011
Introduction to Metal–Organic Frameworks journal September 2011
Storage of Hydrogen, Methane, and Carbon Dioxide in Highly Porous Covalent Organic Frameworks for Clean Energy Applications journal July 2009
Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room-temperature patent-application March 2007
Isomers of Metal–Organic Complex Arrays journal June 2012
Selective Bifunctional Modification of a Non-catenated Metal−Organic Framework Material via “Click” Chemistry
  • Gadzikwa, Tendai; Farha, Omar K.; Malliakas, Christos D.
  • Journal of the American Chemical Society, Vol. 131, Issue 38, p. 13613-13615 https://doi.org/10.1021/ja904189d
journal September 2009
Tandem Modification of Metal–Organic Frameworks by a Postsynthetic Approach journal June 2008
Metal-organic frameworks based on iron oxide octahedral chains connected by benzenedicarboxylate dianions journal September 2005
Covalent Organic Framework Films, and Methods of Making and Uses of Same patent-application February 2014
Process for the alkoxylation of organic compounds in the presence of novel framework materials patent-application December 2004
Organic Porous Materials Comprising Shape-Persistent Three-Dimensional Molecular Cage Building Blocks patent-application February 2013
Adsorbing Agent, Dust Collection Chamber And Method For Adsorbing Odours patent-application January 2008
1,2,3-triazole based metal-organic framework as photo-active materials patent-application November 2011
Adsorption Mechanism and Uptake of Methane in Covalent Organic Frameworks: Theory and Experiment
  • Mendoza-Cortés, José L.; Han, Sang Soo; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry A, Vol. 114, Issue 40, p. 10824-10833 https://doi.org/10.1021/jp1044139
journal October 2010
Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework
  • Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A.
  • Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315 https://doi.org/10.1021/ja206525x
journal October 2011
Polymeric Foams with Nanocellular Morphology and Methods for Making Them patent-application October 2009
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent March 2007
Post-Synthetic Modification of Tagged Metal-Organic Frameworks journal October 2008
Gas Sensor Incorporating a Porous Framework patent-application February 2012
Preparation of Single Crystals of Coordination Solids in Silica Gels: Synthesis and Structure of CuII(1,4-C4H4N2)(C4O4)(OH2)4 journal July 1995
Synthesis of a Zinc(II) Imidazolium Dicarboxylate Ligand Metal−Organic Framework (MOF): a Potential Precursor to MOF-Tethered N-Heterocyclic Carbene Compounds journal February 2010
Gas Adsorption on Metal-Organic Frameworks patent-application March 2010
Metal-organic frameworks with high capacity and selectivity for harmful gases journal August 2008
Hydrogen Storage in New Metal–Organic Frameworks
  • Tranchemontagne, David J.; Park, Kyo Sung; Furukawa, Hiroyasu
  • The Journal of Physical Chemistry C, Vol. 116, Issue 24, p. 13143-13151 https://doi.org/10.1021/jp302356q
journal June 2012
Postsynthetic Covalent Modification of a Neutral Metal−Organic Framework journal October 2007
Substituted benzazoloporphyrazines for polymerization and surface attachment and articles formed therefrom patent-application January 2011
Tuning the structure and function of metal–organic frameworks via linker design journal January 2014
Metal oxides from metal-organic framework materials patent August 2013
Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals journal September 2011
A Thermally Stable Pt/Y-Based Metal−Organic Framework:  Exploring the Accessibility of the Metal Centers with Spectroscopic Methods Using H2O, CH3OH, and CH3CN as Probes journal November 2006
Isoreticular metal-organic frameworks, process for forming the same, and systematic design of pore size and functionality therein, with application for gas storage patent-application January 2003
Adsorption process with on-line adsorbent removal patent-application November 2006
Novel Eclipsed 2D Cadmium(II) Coordination Polymers with Open-Channel Structure Constructed from Terephthalate and 3-(2-Pyridyl)pyrazole:  Crystal Structures, Emission Properties, and Inclusion of Guest Molecules journal August 2004
Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane Storage journal January 2002
Reversible oxygen sorbent compositions patent May 1993
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks journal June 2012
A Metal−Organic Framework with Covalently Bound Organometallic Complexes journal July 2010
Mapping of Functional Groups in Metal-Organic Frameworks journal July 2013
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application January 2005
Carbon Dioxide Capture and Storage Using Open Frameworks patent-application May 2012
Mixed metal framework compositions for monoalkylene glycol production patent November 1991
Metal–organic frameworks as heterogeneous catalysts for oxidation reactions journal January 2011
Porous organo-metallic skeleton material containing an additional polymer patent October 2010
Covalently linked organic frameworks and polyhedra patent-application July 2006
Photoluminescent Metal−Organic Polymer Constructed from Trimetallic Clusters and Mixed Carboxylates journal February 2003
Covalent modification of a metal–organic framework with isocyanates: probing substrate scope and reactivity journal January 2008
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent-application June 2006
High Methane Storage Capacity in Aluminum Metal–Organic Frameworks journal February 2014
In Situ Hydrothermal Growth of Metal−Organic Framework 199 Films on Stainless Steel Fibers for Solid-Phase Microextraction of Gaseous Benzene Homologues journal December 2009
Process for preparing porous metal-organic frameworks based on aluminum fumarate patent September 2013
Method of using a metal organic frameworks based on aluminum fumarate patent August 2013
Role of Copper Species in the Oxidative Dimerization of Arylboronic Acids: Synthesis of Symmetrical Biaryls journal December 2003
Late transition metal catalyst complexes and oligomers therefrom patent December 2002
Shaped bodies containing metal-organic frameworks patent April 2009
Process for the epoxidation of an organic compound with oxygen or an oxygen-delivering compounds using catalysts containing metal-organic frame-work materials patent September 2003
Metal-organic framework materials for gaseous hydrocarbon storage patent-application August 2006
Non-regenerating carbon monoxide sensor patent March 1998
Preparation of metal-catecholate frameworks patent June 2014
Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc) journal April 2012
Role of Exposed Metal Sites in Hydrogen Storage in MOFs journal July 2008
A High-Throughput Investigation of the Role of pH, Temperature, Concentration, and Time on the Synthesis of Hybrid Inorganic-Organic Materials journal November 2005
Air Collector with Functionalized Ion Exchange Membrane for Capturing Ambient CO2 patent-application September 2007
From MOFs to zeolites: zirconium sites for epoxide rearrangement journal January 2013
Shaped bodies containing metal-organic frameworks patent-application December 2003
Characterization of a New Porous Pt-Containing Metal-Organic Framework Containing Potentially Catalytically Active Sites:  Local Electronic Structure at the Metal Centers journal January 2007
An Efficient High Yielding Approach for the Homocoupling of Aryl Boronic Acids journal January 2002
A large-cavity zeolite with wide pore windows and potential as an oil refining catalyst journal August 2002
Process for producing polyalkylene carbonates patent September 2003
Direction of unusual mixed-ligand metal–organic frameworks: a new type of 3-D polythreading involving 1-D and 2-D structural motifs and a 2-fold interpenetrating porous network journal January 2005
SHAPED BODIES CONTAINING METAL-ORGANIC FRAMEWORKS patent-application June 2009
Crystalline metal-organic microporous materials patent July 1997
Process for preparing an organometallic framework material patent-application July 2005
Process for Manufacture of Olefin Oxides patent July 1954
Zeolite-like metal organic frameworks (ZMOFS): modular approach to the synthesis of organic-inorganic hybrid porous materials having a zeolite like topology patent-application December 2006
Process for the alkoxylation of monools in the presence of metallo-organic framework materials patent April 2007
Metal-Organic Frameworks Incorporating Copper-Complexed Rotaxanes journal January 2012
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials journal March 2014
Facile Synthesis of a Highly Crystalline, Covalently Linked Porous Boronate Network journal October 2006
Method of storing, uptaking, releasing of gases by novel framework materials patent August 2005

Similar Records

Redox-active metal-organic frameworks for the catalytic oxidation of hydrocarbons
Patent · Tue Aug 28 00:00:00 EDT 2018 · OSTI ID:1493306

In silico screening of metal–organic frameworks in separation applications
Journal Article · Tue May 03 00:00:00 EDT 2011 · Physical Chemistry Chemical Physics. PCCP (Print) · OSTI ID:1493306

Acid, solvent, and thermal resistant metal-organic frameworks
Patent · Tue May 14 00:00:00 EDT 2019 · OSTI ID:1493306