Investigation of Accessible Pore Structure Evolution under Pressurization and Adsorption for Coal and Shale Using Small-Angle Neutron Scattering

Liu, Shimin; Zhang, Rui; Karpyn, Zuleima; Yoon, Hongkyu; Dewers, Thomas

doi:10.1021/acs.energyfuels.8b03672

Investigation of Accessible Pore Structure Evolution under Pressurization and Adsorption for Coal and Shale Using Small-Angle Neutron Scattering

Journal Article · Sun Jan 06 23:00:00 EST 2019 · Energy and Fuels

DOI:https://doi.org/10.1021/acs.energyfuels.8b03672· OSTI ID:1492868

Liu, Shimin ^[1]; ^[1]; Karpyn, Zuleima ^[1]; Yoon, Hongkyu ^[2]; ^[2]

The Pennsylvania State Univ., University Park, PA (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Pore structure is an important parameter to quantify the reservoir rock adsorption capability and diffusivity, both of which are fundamental reservoir properties to evaluate the gas production and carbon sequestration potential for coalbed methane (CBM) and shale gas reservoirs. In this study, we applied small-angle neutron scattering (SANS) to characterize the total and accessible pore structures for two coal and two shale samples. We carried out in situ SANS measurements to probe the accessible pore structure differences under argon, deuterated methane (CD₄), and CO₂ penetrations. The results show that the total porosity ranges between 0.25 and 5.8% for the four samples. Less than 50% of the total pores are accessible to CD₄ for the two coals, while more than 75% of the pores were found to be accessible for the two shales. This result suggests that organic matter pores tend to be disconnected compared to mineral matter pores. Argon pressurization can induce pore contraction because of the mechanical compression of the solid skeleton in both the coal and shale samples. Hydrostatic compression has a higher effect on the nanopores of coal and shale with a higher accessible porosity. Both methane and CO₂ injection can reduce the accessible nanopore volume due to a combination of mechanical compression, sorption-induced matrix swelling, and adsorbed molecule occupation. CO₂ has higher effects on sorption-induced matrix swelling and pore filling compared to methane for both the coal and shale samples. Gas densification and pore filling could occur at higher pressures and smaller pore sizes. In conclusion, the compression and adsorption could create nanopores in the San Juan coal and Marcellus shale drilled core but could have an opposite effect in the other samples, namely, the processes could damage the nanopores in the Hazleton coal and Marcellus shale outcrop.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1492868

Report Number(s):: SAND--2019-0638J; 671702

Journal Information:: Energy and Fuels, Journal Name: Energy and Fuels Journal Issue: 2 Vol. 33; ISSN 0887-0624

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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