Metal oxides from acidic solutions

Seo, Dong-Kyun; Mieritz, Daniel; Chan, Candace; Zhao, Ran

Metal oxides from acidic solutions

Patent · 01 January 2019

OSTI ID:1492821

Seo, Dong-Kyun; Mieritz, Daniel; Chan, Candace; Zhao, Ran

Forming a metal oxide by treating an acidic solution containing a metal to yield a precursor in the form of a semi-liquid, semi-solid or solid, and treating the precursor to yield a product including the metal oxide. An organic or inorganic component may be combined with the precursor to yield a second semi-liquid, semi-solid or solid. The product may be treated to yield a new material. In some cases, the metal oxide has an empirical formula H.sub.xM.sub.2A.sup.1.sub.y-A.sup.2.sub.z, where M represents a transition metal or any combination of transition metals in Groups 3-12; A.sup.1 is a first oxyanion; A.sup.2 is a second oxyanion; 0.ltoreq.x.ltoreq.3; 0.ltoreq.y.ltoreq.3; 0.ltoreq.z.ltoreq.3; and y+z>0.

View Patent

Research Organization:: Arizona Board of Regents on behalf of Arizona State University, Scottsdale, AZ (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: SC0001016

Assignee:: Arizona Board of Regents on behalf of Arizona State University (Scottsdale, AZ)

Patent Number(s):: 10,170,759

Application Number:: 14/899,953

OSTI ID:: 1492821

Country of Publication:: United States

Language:: English

References (50)

Synthesis and surface characteristics of silica– and alumina–carbon composite xerogels Moreno-Castilla, Carlos; Jose´ Maldonado-Hódar, Francisco Physical Chemistry Chemical Physics, Vol. 2, Issue 20, p. 4818-4822 https://doi.org/10.1039/b004223o	journal	January 2000
Thermodynamics of mixed-gas adsorption Myers, A. L.; Prausnitz, J. M. AIChE Journal, Vol. 11, Issue 1, p. 121-127 https://doi.org/10.1002/aic.690110125	journal	January 1965
Silica Sol as a Nanoglue: Flexible Synthesis of Composite Aerogels Morris, Catherine A.; Anderson, Michele L.; Stroud, Rhonda M. Science, Vol. 284, Issue 5414, p. 622-624 https://doi.org/10.1126/science.284.5414.622	journal	April 1999
Chapter 47: Microstructure and Nanoporosity of as-Set Geopolymers Kriven, W. M.; Bell, J. L.; Gordon, M. Mechanical Properties and Performance of Engineering Ceramics II: Ceramic Engineering and Science Proceedings, Vol. 27, Issue 2 https://doi.org/10.1002/9780470291313.ch47	book	January 2006
Synthesis of a self-supporting faujasite zeolite membrane using geopolymer gel for separation of alcohol/water mixture Zhang, Jin; He, Yan; Wang, Yi-pin Materials Letters, Vol. 116 https://doi.org/10.1016/j.matlet.2013.11.008	journal	February 2014
Geopolymer technology: the current state of the art Duxson, P.; Fernández-Jiménez, A.; Provis, J. L. Journal of Materials Science, Vol. 42, Issue 9, p. 2917-2933 https://doi.org/10.1007/s10853-006-0637-z	journal	December 2006
Low-temperature sintering method for NiCuZn ferrite and effect of Mn addition on electromagnetic properties Ju, Dong-ying; Bian, Pei Transactions of Nonferrous Metals Society of China, Vol. 16, p. s67-s70 https://doi.org/10.1016/S1003-6326(06)60144-1	journal	June 2006
Making Nanosized Oxide Powders from Precursors by Flame Spray Pyrolysis Laine, R. M.; Baranwal, R.; Hinklin, T. Key Engineering Materials, Vol. 159-160, p. 17-24 https://doi.org/10.4028/www.scientific.net/KEM.159-160.17	journal	May 1998
Preparation of phosphoric acid-based porous geopolymers Le-ping, Liu; Xue-min, Cui; Shu-heng, Qiu Applied Clay Science, Vol. 50, Issue 4, p. 600-603 https://doi.org/10.1016/j.clay.2010.10.004	journal	December 2010
Recent Advances in Electron Tomography: TEM and HAADF-STEM Tomography for Materials Science and Semiconductor Applications Kübel, Christian; Voigt, Andreas; Schoenmakers, Remco Microscopy and Microanalysis, Vol. 11, Issue 5, p. 378-400 https://doi.org/10.1017/S1431927605050361	journal	September 2005
Adsorption kinetics for CO2 on highly selective zeolites NaKA and nano-NaKA Cheung, Ocean; Bacsik, Zoltán; Liu, Qingling Applied Energy, Vol. 112 https://doi.org/10.1016/j.apenergy.2013.01.017	journal	December 2013
Characterization of monolithic porous carbon prepared from resorcinol/formaldehyde gels with cationic surfactant Bruno, M. M.; Cotella, N. G.; Miras, M. C. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 358, Issue 1-3, p. 13-20 https://doi.org/10.1016/j.colsurfa.2010.01.017	journal	April 2010
Harnessing the Sol–Gel Process for the Assembly of Non-Silicate Mesostructured Oxide Materials Boettcher, Shannon W.; Fan, Jie; Tsung, Chia-Kuang Accounts of Chemical Research, Vol. 40, Issue 9, p. 784-792 https://doi.org/10.1021/ar6000389	journal	September 2007
Silicoaluminophosphates as CO₂ sorbents Cheung, Ocean; Liu, Qingling; Bacsik, Zoltán Microporous and Mesoporous Materials, Vol. 156, p. 90-96 https://doi.org/10.1016/j.micromeso.2012.02.003	journal	July 2012
Colloidal processing and CO₂ capture performance of sacrificially templated zeolite monoliths Akhtar, Farid; Andersson, Linnéa; Keshavarzi, Neda Applied Energy, Vol. 97, p. 289-296 https://doi.org/10.1016/j.apenergy.2011.12.064	journal	September 2012
Definitions of terms relating to the structure and processing of sols, gels, networks, and inorganic-organic hybrid materials (IUPAC Recommendations 2007) Alemán, J. V.; Chadwick, A. V.; He, J. Pure and Applied Chemistry, Vol. 79, Issue 10, p. 1801-1829 https://doi.org/10.1351/pac200779101801	journal	January 2007
Sol-Gel Processing of Nanostructured Inorganic Scintillating Materials Nedelec, J. M. Journal of Nanomaterials, Vol. 2007, Article No. 36392 https://doi.org/10.1155/2007/36392	journal	January 2007
Electrically conductive oxide aerogels: new materials in electrochemistry Rolison, Debra R.; Dunn, Bruce Journal of Materials Chemistry, Vol. 11, Issue 4, p. 963-980 https://doi.org/10.1039/b007591o	journal	January 2001
Zeolite monoliths with hierarchical designed pore network structure: Synthesis and performance Hasan, Fatin A.; Xiao, Penny; Singh, Ranjeet K. Chemical Engineering Journal, Vol. 223 https://doi.org/10.1016/j.cej.2013.02.100	journal	May 2013
Low-temperature synthetic method for size-controlled CdSe nanocrystals: utilization of boron selenide Iancu, Nora; Sharma, Renu; Seo, Dong-Kyun Chemical Communications, Vol. 0, Issue 20, p. 2298-2299 https://doi.org/10.1039/b408702j	journal	January 2004
Surface and catalytic properties of acid metal–carbons prepared by the sol–gel method Aguado-Serrano, J.; Rojas-Cervantes, M. L.; Martín-Aranda, R. M. Applied Surface Science, Vol. 252, Issue 17, p. 6075-6079 https://doi.org/10.1016/j.apsusc.2005.11.033	journal	June 2006
Synthesis of High-Surface-Area Alumina Aerogels without the Use of Alkoxide Precursors Baumann, Theodore F.; Gash, Alexander E.; Chinn, Sarah C. Chemistry of Materials, Vol. 17, Issue 2, p. 395-401 https://doi.org/10.1021/cm048800m	journal	January 2005
Nano- and Microporosity in Geopolymer Gels Bell, J. L.; Gordon, M.; Kriven, W. M. Microscopy and Microanalysis, Vol. 12, Issue S02, p. 552-553 https://doi.org/10.1017/S143192760606987X	journal	July 2006
Synthesis strategies in the search for hierarchical zeolites Serrano, D. P.; Escola, J. M.; Pizarro, P. Chem. Soc. Rev., Vol. 42, Issue 9 https://doi.org/10.1039/C2CS35330J	journal	January 2013
Rheology of geopolymer by DOE approach Romagnoli, Marcello; Leonelli, Cristina; Kamse, Elie Construction and Building Materials, Vol. 36, p. 251-258 https://doi.org/10.1016/j.conbuildmat.2012.04.122	journal	November 2012
Mesostructured Forms of γ-Al₂O₃ Zhang, Zhaorong; Hicks, Randall W.; Pauly, Thomas R. Journal of the American Chemical Society, Vol. 124, Issue 8, p. 1592-1593 https://doi.org/10.1021/ja016974o	journal	February 2002
A Novel Combustion Synthesis Preparation of CuO/ZnO/ZrO₂/Pd for Oxidative Hydrogen Production from Methanol Schuyten, Stephen; Dinka, Peter; Mukasyan, Alexander S. Catalysis Letters, Vol. 121, Issue 3-4, p. 189-198 https://doi.org/10.1007/s10562-007-9336-x	journal	December 2007
Andreasen Particle Packing Method on the Development of Geopolymer Concrete for Civil Engineering Borges, Paulo H. R.; Fonseca, Lucas F.; Nunes, Vitor A. Journal of Materials in Civil Engineering, Vol. 26, Issue 4, p. 692-697 https://doi.org/10.1061/(ASCE)MT.1943-5533.0000838	journal	April 2014
Amorphous Zeolites Thomas, John M.; Bursill, Leslie A. Angewandte Chemie International Edition in English, Vol. 19, Issue 9, p. 745-746 https://doi.org/10.1002/anie.198007451	journal	September 1980
Do Geopolymers Actually Contain Nanocrystalline Zeolites? A Reexamination of Existing Results Provis, John L.; Lukey, Grant C.; van Deventer, Jannie S. J. Chemistry of Materials, Vol. 17, Issue 12, p. 3075-3085 https://doi.org/10.1021/cm050230i	journal	June 2005
Preparation of templated mesoporous silica membranes on macroporous α-alumina supports via direct coating of thixotropic polymeric sols Boffa, V.; Elshof, J. E. ten; Blank, D. H. A. Microporous and Mesoporous Materials, Vol. 100, Issue 1-3, p. 173-182 https://doi.org/10.1016/j.micromeso.2006.10.035	journal	March 2007
Penta-coordinated Al³⁺ ions as preferential nucleation sites for BaO on γ-Al₂O₃: An ultra-high-magnetic field ²⁷Al MAS NMR study Kwak, J.; Hu, J.; Kim, D. Journal of Catalysis, Vol. 251, Issue 1, p. 189-194 https://doi.org/10.1016/j.jcat.2007.06.029	journal	October 2007
Consolidation of Metal Oxide Nanocrystals. Reactive Pellets with Controllable Pore Structure That Represent a New Family of Porous, Inorganic Materials Richards, Ryan; Li, Weifeng; Decker, Shawn Journal of the American Chemical Society, Vol. 122, Issue 20, p. 4921-4925 https://doi.org/10.1021/ja994383g	journal	May 2000
A thixotropic nanocomposite gel for three-dimensional cell culture Pek, Y. Shona; Wan, Andrew C. A.; Shekaran, Asha Nature Nanotechnology, Vol. 3, Issue 11, p. 671-675 https://doi.org/10.1038/nnano.2008.270	journal	September 2008
Rheological behavior of alkali-activated metakaolin during geopolymerization Poulesquen, A.; Frizon, F.; Lambertin, D. Journal of Non-Crystalline Solids, Vol. 357, Issue 21, p. 3565-3571 https://doi.org/10.1016/j.jnoncrysol.2011.07.013	journal	November 2011
Silica/C composites prepared by the sol–gel method. Influence of the synthesis parameters on textural characteristics Aguado-Serrano, J.; Rojas-Cervantes, M. L.; López-Peinado, A. J. Microporous and Mesoporous Materials, Vol. 74, Issue 1-3, p. 111-119 https://doi.org/10.1016/j.micromeso.2004.06.008	journal	September 2004
Mesoporous zeolite single crystal catalysts: Diffusion and catalysis in hierarchical zeolites Christensen, C.; Johannsen, K.; Tornqvist, E. Catalysis Today, Vol. 128, Issue 3-4, p. 117-122 https://doi.org/10.1016/j.cattod.2007.06.082	journal	October 2007
One-Pot Synthesis of Interpenetrating Inorganic/Organic Networks of CuO/Resorcinol-Formaldehyde Aerogels: Nanostructured Energetic Materials Leventis, Nicholas; Chandrasekaran, Naveen; Sadekar, Anand G. Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4576-4577 https://doi.org/10.1021/ja809746t	journal	April 2009
Visualizing single-molecule diffusion in mesoporous materials Zürner, Andreas; Kirstein, Johanna; Döblinger, Markus Nature, Vol. 450, Issue 7170, p. 705-708 https://doi.org/10.1038/nature06398	journal	November 2007
Queensland: State Report Rutley, Ward Australian Endodontic Journal, Vol. 37, Issue 1 https://doi.org/10.1111/j.1747-4477.2011.00300.x	journal	March 2011
Hierarchically Structured Zeolite Bodies: Assembling Micro-, Meso-, and Macroporosity Levels in Complex Materials with Enhanced Properties Michels, Nina-Luisa; Mitchell, Sharon; Milina, Maria Advanced Functional Materials, Vol. 22, Issue 12, p. 2509-2518 https://doi.org/10.1002/adfm.201103120	journal	March 2012
The effect of silica template structure on the pore structure of mesoporous carbons Han, Sangjin; Lee, Kyu T.; Oh, Seung M. Carbon, Vol. 41, Issue 5, p. 1049-1056 https://doi.org/10.1016/S0008-6223(02)00439-6	journal	January 2003
Time-Efficient Acid-Catalyzed Synthesis of Resorcinol−Formaldehyde Aerogels Mulik, Sudhir; Sotiriou-Leventis, Chariklia; Leventis, Nicholas Chemistry of Materials, Vol. 19, Issue 25, p. 6138-6144 https://doi.org/10.1021/cm071572m	journal	December 2007
Diffusion in zeolites: is surface resistance a critical parameter? Gueudré, Laurent; Jolimaîte, Elsa; Bats, Nicolas Adsorption, Vol. 16, Issue 1-2, p. 17-27 https://doi.org/10.1007/s10450-010-9213-6	journal	April 2010
A versatile approach for the processing of polymer nanocomposites with self-assembled nanofibre templates Capadona, Jeffrey R.; Van Den Berg, Otto; Capadona, Lynn A. Nature Nanotechnology, Vol. 2, Issue 12, p. 765-769 https://doi.org/10.1038/nnano.2007.379	journal	November 2007
Recent Progress in the Synthesis of Porous Carbon Materials Lee, J.; Kim, J.; Hyeon, T. Advanced Materials, Vol. 18, Issue 16, p. 2073-2094 https://doi.org/10.1002/adma.200501576	journal	August 2006
A one step process for grafting organic pendants on alumina via the reaction of alumina and phosphonate under microwave irradiation Villemin, Didier; Moreau, Bernard; SimÃ©on, Fabrice Chemical Communications, Vol. 0, Issue 20, p. 2060-2061 https://doi.org/10.1039/b105240n	journal	October 2001
Glycine-Assisted Sol-Gel Combustion Synthesis and Characterization of Aluminum-Doped LiNiVO₄ for Use in Lithium-Ion Batteries Sivashanmugam, A.; Thirunakaran, R.; Zou, Meijing Journal of The Electrochemical Society, Vol. 153, Issue 3, p. A497-A503 https://doi.org/10.1149/1.2162454	journal	January 2006
Combustion synthesis of gadolinia doped ceria powder Mahata, T.; Das, G.; Mishra, R. K. Journal of Alloys and Compounds, Vol. 391, Issue 1-2, p. 129-135 https://doi.org/10.1016/j.jallcom.2004.07.085	journal	April 2005
Geopolymerisation: A review and prospects for the minerals industry Komnitsas, Kostas; Zaharaki, Dimitra Minerals Engineering, Vol. 20, Issue 14, p. 1261-1277 https://doi.org/10.1016/j.mineng.2007.07.011	journal	November 2007

Similar Records

Efficient reversible electrodes for solid oxide electrolyzer cells

Patent · 2011 · OSTI ID:1019434

Tri-metallic ferrite oxygen carriers for chemical looping combustion

Patent · 2017 · OSTI ID:1404933

Phosphors for LED lamps

Patent · 2013 · OSTI ID:1093223

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Metal oxides from acidic solutions

Citation Formats

References (50)

Similar Records

Related Subjects