What is the effect of lipophilic polymeric ionic liquids on friction and wear?

Bapat, Abhijeet P.; Erck, Robert; Seymour, Bryan T.; Zhao, Bin; Cosimbescu, Lelia

doi:10.1016/j.reactfunctpolym.2018.07.020

What is the effect of lipophilic polymeric ionic liquids on friction and wear?

Journal Article · Mon Oct 01 00:00:00 EDT 2018 · Reactive and Functional Polymers

DOI:https://doi.org/10.1016/j.reactfunctpolym.2018.07.020· OSTI ID:1492619

Bapat, Abhijeet P.; Erck, Robert; Seymour, Bryan T.; Zhao, Bin; Cosimbescu, Lelia

In this work, methacrylate-type ionic liquid (IL) monomers containing a quaternary ammonium cation and two different counter-anions were synthesized and used as co-monomers to obtain functional poly(alkyl methacrylates) (PAMAs) as friction and wear reducing additives for lubricants. The effect of molecular weight, polymer topology (random or diblock), and IL counter anion on friction and wear behavior of polymer PAO (poly-alpha olefin) solutions have been investigated. The results were compared to those of PAO solutions additized with a small molecule, non-polymeric ionic liquid, or non-ionic copolymers containing 2-(dimethylamino)ethyl methacrylate (DMAEMA) as the polar comonomer. No clear correlation between polymer molecular weight and friction or wear behavior was observed. Random ionic liquid copolymers led to lower wear volumes than their block counterparts. Polymers containing dicyanamide (DCA) counter anion showed lower wear volume compared to those containing bis((trifluoromethyl)sulfonyl)imide (TFSI) anion. Surprisingly, none of the IL copolymers studied outperformed the DMAEMA containing block copolymer in terms of wear volume reduction, suggesting the IL moiety had no beneficial effect on wear.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technology; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357; AC05-76RL01830; AC06-76RL01830

OSTI ID:: 1492619

Alternate ID(s):: OSTI ID: 1500117
OSTI ID: 1548004

Report Number(s):: PNNL-SA--134552

Journal Information:: Reactive and Functional Polymers, Journal Name: Reactive and Functional Polymers Journal Issue: C Vol. 131; ISSN 1381-5148

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (19)

Antiwear and extreme-pressure additives in lubricants Papay, A. G. Lubrication Science, Vol. 10, Issue 3 https://doi.org/10.1002/ls.3010100304	journal	May 1998
Reduction of Friction by Functionalised Viscosity Index Improvers Fan, J.; Müller, M.; Stöhr, T. Tribology Letters, Vol. 28, Issue 3 https://doi.org/10.1007/s11249-007-9272-3	journal	October 2007
Friction Modifier Additives Spikes, Hugh Tribology Letters, Vol. 60, Issue 1 https://doi.org/10.1007/s11249-015-0589-z	journal	September 2015
A review of recent developments of friction modifiers for liquid lubricants (2007–present) Tang, Zhenglin; Li, Shaohui Current Opinion in Solid State and Materials Science, Vol. 18, Issue 3 https://doi.org/10.1016/j.cossms.2014.02.002	journal	June 2014
Polymeric ionic liquids: Broadening the properties and applications of polyelectrolytes Mecerreyes, David Progress in Polymer Science, Vol. 36, Issue 12 https://doi.org/10.1016/j.progpolymsci.2011.05.007	journal	December 2011
Environmental friendly polyisobutylene-based ionic liquid containing chelated orthoborate as lubricant additive: Synthesis, tribological properties and synergistic interactions with ZDDP in hydrocarbon oils Zhang, Yunxiao; Cai, Tao; Shang, Wangji Tribology International, Vol. 115 https://doi.org/10.1016/j.triboint.2017.05.038	journal	November 2017
Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids Zhang, Zhanrong; Song, Jinliang; Han, Buxing Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.6b00457	journal	November 2016
Ionic Liquids in Selective Oxidation: Catalysts and Solvents Dai, Chengna; Zhang, Jie; Huang, Chongpin Chemical Reviews, Vol. 117, Issue 10 https://doi.org/10.1021/acs.chemrev.7b00030	journal	February 2017
Ionic Liquids as Lubricant Additives: A Review Zhou, Yan; Qu, Jun ACS Applied Materials & Interfaces, Vol. 9, Issue 4 https://doi.org/10.1021/acsami.6b12489	journal	January 2017
Antiwear Performance and Mechanism of an Oil-Miscible Ionic Liquid as a Lubricant Additive Qu, Jun; Bansal, Dinesh G.; Yu, Bo ACS Applied Materials & Interfaces, Vol. 4, Issue 2, p. 997-1002 https://doi.org/10.1021/am201646k	journal	February 2012
Structure and Nanostructure in Ionic Liquids Hayes, Robert; Warr, Gregory G.; Atkin, Rob Chemical Reviews, Vol. 115, Issue 13 https://doi.org/10.1021/cr500411q	journal	June 2015
Interactions and Ordering of Ionic Liquids at a Metal Surface Mendonça, Ana C. F.; Malfreyt, Patrice; Pádua, Agílio A. H. Journal of Chemical Theory and Computation, Vol. 8, Issue 9 https://doi.org/10.1021/ct300452u	journal	August 2012
A Simple and Universal Gel Permeation Chromatography Technique for Precise Molecular Weight Characterization of Well-Defined Poly(ionic liquid)s He, Hongkun; Zhong, Mingjiang; Adzima, Brian Journal of the American Chemical Society, Vol. 135, Issue 11 https://doi.org/10.1021/ja4012645	journal	March 2013
Ionic liquid polymer electrolytes Ye, Yun-Sheng; Rick, John; Hwang, Bing-Joe J. Mater. Chem. A, Vol. 1, Issue 8 https://doi.org/10.1039/C2TA00126H	journal	January 2013
Room-temperature Ye, Chengfeng; Liu, Weimin; Chen, Yunxia Chemical Communications, Issue 21, p. 2244-2245 https://doi.org/10.1039/b106935g	journal	October 2001
Biocatalysis in ionic liquids Sheldon, Roger A.; Lau, Rute Madeira; Sorgedrager, Menno J. Green Chemistry, Vol. 4, Issue 2 https://doi.org/10.1039/b110008b	journal	March 2002
Ionic liquid lubricants: designed chemistry for engineering applications Zhou, Feng; Liang, Yongmin; Liu, Weimin Chemical Society Reviews, Vol. 38, Issue 9 https://doi.org/10.1039/b817899m	journal	January 2009
A Review of Ionic Liquid Lubricants Somers, Anthony; Howlett, Patrick; MacFarlane, Douglas Lubricants, Vol. 1, Issue 1 https://doi.org/10.3390/lubricants1010003	journal	January 2013
Ionic Liquids as Advanced Lubricant Fluids Bermúdez, María-Dolores; Jiménez, Ana-Eva; Sanes, José Molecules, Vol. 14, Issue 8 https://doi.org/10.3390/molecules14082888	journal	August 2009

Cited By (1)

Poly(alkylimidazolium bis(trifluoromethylsulfonyl)imide)-Based Polymerized Ionic Liquids: A Potential High-Performance Lubricating Grease Wu, Jian; Mu, Liwen; Feng, Xin Advanced Materials Interfaces, Vol. 6, Issue 5 https://doi.org/10.1002/admi.201801796	journal	January 2019

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