Molecularly Mixed Composite Membranes for Advanced Separation Processes

Zhu, Guanghui; Zhang, Fengyi; Rivera, Matthew P.; Hu, Xunxiang; Zhang, Guoyan; Jones, Christopher W.; Lively, Ryan P.

doi:10.1002/ange.201811341

Molecularly Mixed Composite Membranes for Advanced Separation Processes

Journal Article · Thu Jan 24 23:00:00 EST 2019 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201811341· OSTI ID:1492098

Zhu, Guanghui ^[1]; Zhang, Fengyi ^[1]; Rivera, Matthew P. ^[1]; Hu, Xunxiang ^[2]; Zhang, Guoyan ^[1]; Jones, Christopher W. ^[1]; ^[1]

School of Chemical &, Biomolecular Engineering Georgia Institute of Technology 311 Ferst Drive NW Atlanta GA 30332 USA
Materials Science and Technology Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA

Abstract

Porous organic cages (POCs) are individual soluble, porous molecules. When fabricated into mixed‐matrix membranes (MMMs), the soluble POC molecules have the potential to exhibit intimate molecular‐level mixing with the polymer matrix. POCs have only recently been incorporated into mixed matrix membrane materials, but this process has not yet resulted in significant improvements of membrane performance. Now, vertex‐functionalized amorphous scrambled porous organic cages (ASPOCs) have been utilized as membrane performance enhancers and the amorphous ASPOC mixtures are observed to distribute throughout the matrix without any indication of particle formation or agglomeration, creating unique, molecularly mixed composite membranes. Overall, the molecularly mixed composite membrane provide significant increases in both membrane permeability and selectivity, offering new avenues for creation of membranes with unique properties in industrially relevant separations.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; SC0012577; AC05-00OR22725

OSTI ID:: 1492098

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 9 Vol. 131; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (31)

Porous Organic Cage Thin Films and Molecular-Sieving Membranes Song, Qilei; Jiang, Shan; Hasell, Tom Advanced Materials, Vol. 28, Issue 13 https://doi.org/10.1002/adma.201505688	journal	January 2016
Nanoporous Organic Polymer/Cage Composite Membranes Bushell, Alexandra F.; Budd, Peter M.; Attfield, Martin P. Angewandte Chemie, Vol. 125, Issue 4 https://doi.org/10.1002/ange.201206339	journal	December 2012
Mixed-Matrix-Membranen Dechnik, Janina; Gascon, Jorge; Doonan, Christian J. Angewandte Chemie, Vol. 129, Issue 32 https://doi.org/10.1002/ange.201701109	journal	July 2017
Nanoporous Organic Polymer/Cage Composite Membranes Bushell, Alexandra F.; Budd, Peter M.; Attfield, Martin P. Angewandte Chemie International Edition, Vol. 52, Issue 4 https://doi.org/10.1002/anie.201206339	journal	December 2012
Mixed-Matrix Membranes Dechnik, Janina; Gascon, Jorge; Doonan, Christian J. Angewandte Chemie International Edition, Vol. 56, Issue 32 https://doi.org/10.1002/anie.201701109	journal	July 2017
The study of defects in crystals by positron annihilation Seeger, Alfred Applied Physics, Vol. 4, Issue 3 https://doi.org/10.1007/BF00884229	journal	August 1974
The temperature dependence of positron lifetimes in solid pivalic acid Eldrup, M.; Lightbody, D.; Sherwood, J. N. Chemical Physics, Vol. 63, Issue 1-2 https://doi.org/10.1016/0301-0104(81)80307-2	journal	December 1981
Mixed-matrix membranes incorporated with porous shape-persistent organic cages for gas separation Mao, Hongchao; Zhang, Suobo Journal of Colloid and Interface Science, Vol. 490 https://doi.org/10.1016/j.jcis.2016.11.023	journal	March 2017
Development of polycarbonate based zeolite 4A filled mixed matrix gas separation membranes Şen, Değer; Kalıpçılar, Halil; Yilmaz, Levent Journal of Membrane Science, Vol. 303, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.07.010	journal	October 2007
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations Zhang, Chen; Dai, Ying; Johnson, Justin R. Journal of Membrane Science, Vol. 389 https://doi.org/10.1016/j.memsci.2011.10.003	journal	February 2012
Metal-organic polyhedra 18 mixed-matrix membranes for gas separation Perez, Edson V.; Balkus, Kenneth J.; Ferraris, John P. Journal of Membrane Science, Vol. 463 https://doi.org/10.1016/j.memsci.2014.03.045	journal	August 2014
A robust thin film composite membrane incorporating thermally rearranged polymer support for organic solvent nanofiltration and pressure retarded osmosis Kim, Ji Hoon; Moon, Sun Ju; Park, Sang Hyun Journal of Membrane Science, Vol. 550 https://doi.org/10.1016/j.memsci.2018.01.008	journal	March 2018
Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation Chung, Tai-Shung; Jiang, Lan Ying; Li, Yi Progress in Polymer Science, Vol. 32, Issue 4, p. 483-507 https://doi.org/10.1016/j.progpolymsci.2007.01.008	journal	April 2007
Mixed Matrix Membranes (MMMs) Comprising Exfoliated 2D Covalent Organic Frameworks (COFs) for Efficient CO ₂ Separation Kang, Zixi; Peng, Yongwu; Qian, Yuhong Chemistry of Materials, Vol. 28, Issue 5 https://doi.org/10.1021/acs.chemmater.5b02902	journal	February 2016
Molecular Separation with Organic Solvent Nanofiltration: A Critical Review Marchetti, Patrizia; Jimenez Solomon, Maria F.; Szekely, Gyorgy Chemical Reviews, Vol. 114, Issue 21 https://doi.org/10.1021/cr500006j	journal	October 2014
Porous Organic Cages for Sulfur Hexafluoride Separation Hasell, Tom; Miklitz, Marcin; Stephenson, Andrew Journal of the American Chemical Society, Vol. 138, Issue 5 https://doi.org/10.1021/jacs.5b11797	journal	January 2016
Feasibility of Mixed Matrix Membrane Gas Separations Employing Porous Organic Cages Evans, Jack D.; Huang, David M.; Hill, Matthew R. The Journal of Physical Chemistry C, Vol. 118, Issue 3 https://doi.org/10.1021/jp4079184	journal	January 2014
Seven chemical separations to change the world Sholl, David S.; Lively, Ryan P. Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/532435a	journal	April 2016
Liquids with permanent porosity Giri, Nicola; Del Pópolo, Mario G.; Melaugh, Gavin Nature, Vol. 527, Issue 7577 https://doi.org/10.1038/nature16072	journal	November 2015
Ultra-selective high-flux membranes from directly synthesized zeolite nanosheets Jeon, Mi Young; Kim, Donghun; Kumar, Prashant Nature, Vol. 543, Issue 7647 https://doi.org/10.1038/nature21421	journal	March 2017
Porous organic molecular solids by dynamic covalent scrambling Jiang, Shan; Jones, James T. A.; Hasell, Tom Nature Communications, Vol. 2, Issue 1 https://doi.org/10.1038/ncomms1207	journal	February 2011
Porous organic cages Tozawa, Tomokazu; Jones, James T. A.; Swamy, Shashikala I. Nature Materials, Vol. 8, Issue 12, p. 973-978 https://doi.org/10.1038/nmat2545	journal	October 2009
Mixed matrix formulations with MOF molecular sieving for key energy-intensive separations Liu, Gongping; Chernikova, Valeriya; Liu, Yang Nature Materials, Vol. 17, Issue 3 https://doi.org/10.1038/s41563-017-0013-1	journal	February 2018
Functional porous composites by blending with solution-processable molecular pores Jiang, S.; Chen, L.; Briggs, M. E. Chemical Communications, Vol. 52, Issue 42 https://doi.org/10.1039/C6CC01034B	journal	January 2016
Understanding gas capacity, guest selectivity, and diffusion in porous liquids Greenaway, Rebecca L.; Holden, Daniel; Eden, Edward G. B. Chemical Science, Vol. 8, Issue 4 https://doi.org/10.1039/C6SC05196K	journal	January 2017
Molecular blends of methylated-poly(ethylenimine) and amorphous porous organic cages for SO ₂ adsorption Zhu, Guanghui; Carrillo, Jan-Michael Y.; Sujan, Achintya Journal of Materials Chemistry A, Vol. 6, Issue 44 https://doi.org/10.1039/C8TA02788A	journal	January 2018
Positronium Annihilation in Molecular Substances Tao, S. J. The Journal of Chemical Physics, Vol. 56, Issue 11 https://doi.org/10.1063/1.1677067	journal	June 1972
Merocyanine 540 as an optical probe of transmembrane electrical activity in the heart Salama, G.; Morad, M. Science, Vol. 191, Issue 4226, p. 485-487 https://doi.org/10.1126/science.1082169	journal	March 2003
Interfacial microfluidic processing of metal-organic framework hollow fiber membranes Brown, Andrew J.; Brunelli, Nicholas A.; Eum, Kiwon Science, Vol. 345, Issue 6192 https://doi.org/10.1126/science.1251181	journal	July 2014
The Selectivity Challenge in Organic Solvent Nanofiltration: Membrane and Process Solutions Marchetti, Patrizia; Peeva, Ludmila; Livingston, Andrew Annual Review of Chemical and Biomolecular Engineering, Vol. 8, Issue 1 https://doi.org/10.1146/annurev-chembioeng-060816-101325	journal	June 2017

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