Comparative study of bulk and nano-structured mesoporous SnO2 electrodes on the electrochemical performances for next generation Li rechargeable batteries

Kim, Hyunchul; Yang, Dong -Seok; Um, Ji Hyun; Balasubramanian, Mahalingam; Yoo, Jaeseung; Kim, Hyunwoo; Park, Su Bin; Kim, Ji Man; Yoon, Won -Sub

doi:10.1016/j.jpowsour.2018.12.035

Title: Comparative study of bulk and nano-structured mesoporous SnO₂ electrodes on the electrochemical performances for next generation Li rechargeable batteries

Journal Article · Mon Dec 24 00:00:00 EST 2018 · Journal of Power Sources

DOI:https://doi.org/10.1016/j.jpowsour.2018.12.035· OSTI ID:1491845

^[1]; Yang, Dong -Seok ^[2]; Um, Ji Hyun ^[3]; Balasubramanian, Mahalingam ^[4]; Yoo, Jaeseung ^[3];

^[3]; Park, Su Bin ^[3]; Kim, Ji Man ^[3]; Yoon, Won -Sub ^[3]

Sungkyunkwan Univ., Suwon (South Korea); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Chungbuk National Univ., Cheongju (South Korea)
Sungkyunkwan Univ., Suwon (South Korea)
Argonne National Lab. (ANL), Argonne, IL (United States)

For next generation Li-ion batteries, advanced electrode materials with high energy densities are mightily important issue. Since the partial oxidation of Sn with Li₂O to form SnO_x was demonstrated upon delithiation in SnO₂ anode, the additional conversion reaction has contributed that the theoretical capacity of SnO₂ can be extended from 783 to 1494 mAh g^-1. Herein, with the design of additional conversion reaction, we discuss key factors for high electrochemical performances of the SnO₂ anodes through comparative analysis between nano-structured mesoporous SnO₂ and conventional bulk SnO₂, based on synchrotron radiation-based techniques, quantitative analysis of extended X-ray absorption fine structure spectra, and bond strength calculation. In this way, we demonstrate that the mesoporous SnO₂ has a nano-engineering structure, inducing the facilitated electrochemical reaction and the weak Sn-O bond strength that would have an advantage in the additional conversion reaction as well as a void structure, relieving the severe volume changes during lithiation/delithiation. Consequently, excellent electrochemical performance is obtained in the mesoporous SnO₂. Furthermore, insight from this research enables important advance in the development of metal oxide-based anode materials by making irreversible reaction reversible, providing a realizable strategy for the design and creation of high-energy storage devices.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Research Foundation of Korea (NRF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1491845

Journal Information:: Journal of Power Sources, Vol. 413, Issue C; ISSN 0378-7753

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 29 works

Citation information provided by
Web of Science

References (60)

The development of lithium ion secondary batteries Nishi, Yoshio The Chemical Record, Vol. 1, Issue 5 https://doi.org/10.1002/tcr.1024	journal	January 2001
Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Ordered, Nanostructured Tin-Based Oxides/Carbon Composite as the Negative-Electrode Material for Lithium-Ion Batteries Fan, J.; Wang, T.; Yu, C. Advanced Materials, Vol. 16, Issue 16 https://doi.org/10.1002/adma.200400106	journal	August 2004
Manganese oxide nanoparticle-loaded porous carbon nanofibers as anode materials for high-performance lithium-ion batteries Ji, Liwen; Zhang, Xiangwu Electrochemistry Communications, Vol. 11, Issue 4 https://doi.org/10.1016/j.elecom.2009.01.039	journal	April 2009
Intercalation of lithium into graphite and other carbons Guerard, D.; Herold, A. Carbon, Vol. 13, Issue 4 https://doi.org/10.1016/0008-6223(75)90040-8	journal	August 1975
Lithium Batteries: A Practical Application of Chemical Principles Treptow, Richard S. Journal of Chemical Education, Vol. 80, Issue 9 https://doi.org/10.1021/ed080p1015	journal	September 2003
Recent advances in lithium ion battery materials Scrosati, Bruno Electrochimica Acta, Vol. 45, Issue 15-16 https://doi.org/10.1016/S0013-4686(00)00333-9	journal	May 2000
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
High-performance lithium battery anodes using silicon nanowires Chan, Candace K.; Peng, Hailin; Liu, Gao Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35 https://doi.org/10.1038/nnano.2007.411	journal	December 2007
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Positive Electrode Materials for Li-Ion and Li-Batteries ^† Ellis, Brian L.; Lee, Kyu Tae; Nazar, Linda F. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm902696j	journal	February 2010
Prospective materials and applications for Li secondary batteries Jeong, Goojin; Kim, Young-Ugk; Kim, Hansu Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c0ee00831a	journal	January 2011
Electrochemical Performance of M2GeO4(M = Co, Fe and Ni) as Anode Materials with High Capacity for Lithium-Ion Batteries Yuvaraj, Subramanian; Park, Myung-Soo; Kumar, Veerasubramani Ganesh Journal of Electrochemical Science and Technology, Vol. 8, Issue 4 https://doi.org/10.33961/JECST.2017.8.4.323	journal	December 2017
A New Way to Prepare MoO3/C as Anode of Lithium ion Battery for Enhancing the Electrochemical Performance at Room Temperature Yu, Zhian; Jiang, Hongying; Gu, Dawei Journal of Electrochemical Science and Technology, Vol. 7, Issue 2 https://doi.org/10.33961/JECST.2016.7.2.170	journal	June 2016
Cobalt Oxide Nanorods Prepared by a Template-Free Method for Lithium Battery Application Kim, Seong-Jun; Kim, Eun-Ji; Liu, Meilin Journal of Electrochemical Science and Technology, Vol. 7, Issue 3 https://doi.org/10.33961/JECST.2016.7.3.206	journal	September 2016
Three-dimensional porous amorphous SnO₂ thin films as anodes for Li-ion batteries Yu, Yan; Gu, Lin; Dhanabalan, Abirami Electrochimica Acta, Vol. 54, Issue 28, p. 7227-7230 https://doi.org/10.1016/j.electacta.2009.07.028	journal	December 2009
Facile synthesis and superior anodic performance of ultrafine SnO2-containing nanocomposites Liu, Hongpeng; Long, Donghui; Liu, Xiaojun Electrochimica Acta, Vol. 54, Issue 24 https://doi.org/10.1016/j.electacta.2009.05.030	journal	October 2009
The role of carbon incorporation in SnO2 nanoparticles for Li rechargeable batteries Nam, Seunghoon; Kim, Sungsoo; Wi, Sungun Journal of Power Sources, Vol. 211 https://doi.org/10.1016/j.jpowsour.2012.03.061	journal	August 2012
Electrochemical and In Situ X-Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites Courtney, Ian A.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 144, Issue 6, p. 2045-2052 https://doi.org/10.1149/1.1837740	journal	January 1997
Key Factors Controlling the Reversibility of the Reaction of Lithium with SnO2 and Sn2 BPO 6 Glass Courtney, Ian A.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 144, Issue 9 https://doi.org/10.1149/1.1837941	journal	September 1997
Lithium alloy negative electrodes formed from convertible oxides Huggins, R. Solid State Ionics, Vol. 113-115, Issue 1-2 https://doi.org/10.1016/S0167-2738(98)00275-6	journal	December 1998
Preparation of SnO ₂ /Carbon Composite Hollow Spheres and Their Lithium Storage Properties Lou, Xiong Wen; Deng, Da; Lee, Jim Yang Chemistry of Materials, Vol. 20, Issue 20 https://doi.org/10.1021/cm801607e	journal	October 2008
SnO2 nanosheet hollow spheres with improved lithium storage capabilities Ding, Shujiang; Wen (David) Lou, Xiong Nanoscale, Vol. 3, Issue 9 https://doi.org/10.1039/c1nr10581g	journal	January 2011
In Situ Transmission Electron Microscopy Observation of Microstructure and Phase Evolution in a SnO ₂ Nanowire during Lithium Intercalation Wang, Chong-Min; Xu, Wu; Liu, Jun Nano Letters, Vol. 11, Issue 5 https://doi.org/10.1021/nl200272n	journal	May 2011
In Situ TEM Study of Lithiation Behavior of Silicon Nanoparticles Attached to and Embedded in a Carbon Matrix Gu, Meng; Li, Ying; Li, Xiaolin ACS Nano, Vol. 6, Issue 9 https://doi.org/10.1021/nn303312m	journal	August 2012
The state of understanding of the lithium-ion-battery graphite solid electrolyte interphase (SEI) and its relationship to formation cycling An, Seong Jin; Li, Jianlin; Daniel, Claus Carbon, Vol. 105 https://doi.org/10.1016/j.carbon.2016.04.008	journal	August 2016
Ordered mesoporous SnO2 with a highly crystalline state as an anode material for lithium ion batteries with enhanced electrochemical performance Wang, Xuekun; Li, Zhaoqiang; Li, Qun CrystEngComm, Vol. 15, Issue 18 https://doi.org/10.1039/c3ce40087e	journal	January 2013
Electrochemical properties of SnO ₂ nanorods as anode materials in lithium-ion battery Song-Lin, Shi; Yong-Gang, Liu; Jing-Yuan, Zhang Chinese Physics B, Vol. 18, Issue 10 https://doi.org/10.1088/1674-1056/18/10/078	journal	September 2009
Graphene Nanoribbon and Nanostructured SnO ₂ Composite Anodes for Lithium Ion Batteries Lin, Jian; Peng, Zhiwei; Xiang, Changsheng ACS Nano, Vol. 7, Issue 7 https://doi.org/10.1021/nn4016899	journal	June 2013
New Insight into the Reaction Mechanism for Exceptional Capacity of Ordered Mesoporous SnO ₂ Electrodes via Synchrotron-Based X-ray Analysis Kim, Hyunchul; Park, Gwi Ok; Kim, Yunok Chemistry of Materials, Vol. 26, Issue 22 https://doi.org/10.1021/cm5025603	journal	November 2014
¹¹⁹ Sn NMR probe of magnetic fluctuations in SnO ₂ nanoparticles Dey, Tusharkanti; Khuntia, P.; Mahajan, A. V. EPL (Europhysics Letters), Vol. 96, Issue 6 https://doi.org/10.1209/0295-5075/96/67008	journal	December 2011
On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential Laruelle, S.; Grugeon, S.; Poizot, P. Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634 https://doi.org/10.1149/1.1467947	journal	January 2002
Synthesis, Characterization, and Li-Electrochemical Performance of Highly Porous Co ₃ O ₄ Powders Binotto, G.; Larcher, D.; Prakash, A. S. Chemistry of Materials, Vol. 19, Issue 12 https://doi.org/10.1021/cm070048c	journal	June 2007
TiO2-(B) Nanotubes as Anodes for Lithium Batteries: Origin and Mitigation of Irreversible Capacity Brutti, Sergio; Gentili, Valentina; Menard, Hervé Advanced Energy Materials, Vol. 2, Issue 3 https://doi.org/10.1002/aenm.201100492	journal	January 2012
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism Kresge, C. T.; Leonowicz, M. E.; Roth, W. J. Nature, Vol. 359, Issue 6397, p. 710-712 https://doi.org/10.1038/359710a0	journal	October 1992
Triblock Copolymer Syntheses of Mesoporous Silica with Periodic 50 to 300 Angstrom Pores Zhao, Dongyuan; Feng, Jianglin; Huo, Qisheng Science, Vol. 279, Issue 5350, p. 548-552 https://doi.org/10.1126/science.279.5350.548	journal	January 1998
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles Joo, Sang Hoon; Choi, Seong Jae; Oh, Ilwhan Nature, Vol. 412, Issue 6843 https://doi.org/10.1038/35084046	journal	July 2001
Spontaneous Phase Separation Mediated Synthesis of 3D Mesoporous Carbon with Controllable Cage and Window Size Lee, Hyung Ik; Stucky, Galen D.; Kim, Jin Hoe Advanced Materials, Vol. 23, Issue 20 https://doi.org/10.1002/adma.201003599	journal	April 2011
Inorganic materials for the negative electrode of lithium-ion batteries: state-of-the-art and future prospects Tirado, José L. Materials Science and Engineering: R: Reports, Vol. 40, Issue 3 https://doi.org/10.1016/S0927-796X(02)00125-0	journal	February 2003
In Situ Growth of Mesoporous SnO2 on Multiwalled Carbon Nanotubes: A Novel Composite with Porous-Tube Structure as Anode for Lithium Batteries Wen, Z.; Wang, Q.; Zhang, Q. Advanced Functional Materials, Vol. 17, Issue 15 https://doi.org/10.1002/adfm.200600739	journal	October 2007
Sodiation vs. lithiation phase transformations in a high rate – high stability SnO ₂ in carbon nanocomposite Ding, Jia; Li, Zhi; Wang, Huanlei Journal of Materials Chemistry A, Vol. 3, Issue 13 https://doi.org/10.1039/C5TA00399G	journal	January 2015
XAFS investigations of tin nitrides Lützenkirchen-Hecht, Dirk; Scotti, Nicole; Jacobs, Herbert Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/S0909049500015119	journal	March 2001
Probing the chemical state of tin oxide NP catalysts during CO2 electroreduction: A complementary operando approach Dutta, Abhijit; Kuzume, Akiyoshi; Kaliginedi, Veerabhadrarao Nano Energy, Vol. 53 https://doi.org/10.1016/j.nanoen.2018.09.033	journal	November 2018
Effects of alloying elements on the electronic structure and ductility of NiAl compounds investigated by X-ray absorption fine structure Tian, J. S.; Han, G. M.; Wei, H. Philosophical Magazine, Vol. 93, Issue 17 https://doi.org/10.1080/14786435.2013.765984	journal	June 2013
In Situ X-Ray Absorption and Diffraction Study of the Li Reaction with a Tin Composite Oxide Glass Mansour, A. N.; Mukerjee, S.; Yang, X. Q. Journal of The Electrochemical Society, Vol. 147, Issue 3 https://doi.org/10.1149/1.1393284	journal	January 2000
Darstellung und Struktur der Phase Li ₇ Sn ₃ / Preparation und Crystal Structure of Li ₇ Sn ₃ Müller, Wiking Zeitschrift für Naturforschung B, Vol. 29, Issue 5-6 https://doi.org/10.1515/znb-1974-5-602	journal	June 1974
Die Struktur der Phase Li ₅ Sn ₂ / The Crystal Structure of Li ₅ Sn ₂ Frank, Ursula; Müller, Wiking; Schäfer, Herbert Zeitschrift für Naturforschung B, Vol. 30, Issue 1-2 https://doi.org/10.1515/znb-1975-1-202	journal	February 1975
Darstellung und Struktur der Phase Li13Sn5 und die strukturelle Verwandtschaft der Phasen in den Systemen Li-Sn und Li-Pb / The Preparation and Crystal Structure of Li13Sn5 and the Structural Relations Between the Phases of the Systems Li-Sn and Li-Pb Frank, Ursula; Müller, Wiking Zeitschrift für Naturforschung B, Vol. 30, Issue 5-6 https://doi.org/10.1515/znb-1975-5-605	journal	June 1975
Die Kristallstruktur der Phase Li ₇ Sn ₂ / The Crystal Structure of Li ₇ Sn ₂ Frank, Ursula; Müller, Wiking; Schäfer, Herbert Zeitschrift für Naturforschung B, Vol. 30, Issue 1-2 https://doi.org/10.1515/znb-1975-1-203	journal	February 1975
In situ XAS of the reaction mechanism of lithium with tin-based composite oxide glass Mansour, A. N.; Mukerjee, S.; Yang, X. Q. Journal of Synchrotron Radiation, Vol. 6, Issue 3 https://doi.org/10.1107/S0909049598017026	journal	May 1999
EXAFS study for slightly anharmonic vibrational system Yang, D. S.; Joo, S. K. Solid State Communications, Vol. 105, Issue 9 https://doi.org/10.1016/S0038-1098(97)10167-3	journal	March 1998
Temperature and polarization dependence of extended x-ray absorption fine-structure spectra Beni, G.; Platzman, P. M. Physical Review B, Vol. 14, Issue 4 https://doi.org/10.1103/PhysRevB.14.1514	journal	August 1976
New developments in NEXAFS/EXAFS theory Rehr, J. J.; Ankudinov, A.; Zabinsky, S. I. Catalysis Today, Vol. 39, Issue 4 https://doi.org/10.1016/S0920-5861(97)00109-0	journal	March 1998
Remarkable spreading behavior of molybdena on silica catalysts. Anin situ EXAFS-Raman study de Boer, M.; van Dillen, A. J.; Koningsberger, D. C. Catalysis Letters, Vol. 11, Issue 2 https://doi.org/10.1007/BF00764089	journal	March 1991
High Lithium Electroactivity of Nanometer-Sized Rutile TiO₂ Hu, Y.-S.; Kienle, L.; Guo, Y.-G. Advanced Materials, Vol. 18, Issue 11, p. 1421-1426 https://doi.org/10.1002/adma.200502723	journal	June 2006
Research on Advanced Materials for Li-ion Batteries Li, Hong; Wang, Zhaoxiang; Chen, Liquan Advanced Materials, Vol. 21, Issue 45, p. 4593-4607 https://doi.org/10.1002/adma.200901710	journal	December 2009
Synthesis and Electrode Performance of Nanostructured V ₂ O ₅ by Using a Carbon Tube-in-Tube as a Nanoreactor and an Efficient Mixed-Conducting Network Hu, Yong-Sheng; Liu, Xi; Müller, Jens-O. Angewandte Chemie International Edition, Vol. 48, Issue 1 https://doi.org/10.1002/anie.200802988	journal	November 2008
Ultrahigh Capacity Due to Multi-Electron Conversion Reaction in Reduced Graphene Oxide-Wrapped MoO ₂ Porous Nanobelts Tang, Wei; Peng, Cheng Xin; Nai, Chang Tai Small, Vol. 11, Issue 20 https://doi.org/10.1002/smll.201403018	journal	January 2015
Oxygen Bridges between NiO Nanosheets and Graphene for Improvement of Lithium Storage Zhou, Guangmin; Wang, Da-Wei; Yin, Li-Chang ACS Nano, Vol. 6, Issue 4 https://doi.org/10.1021/nn300098m	journal	March 2012
XANES study of the support effect on the state of platinum catalysts Yoshida, H.; Yazawa, Y.; Takagi, N. Journal of Synchrotron Radiation, Vol. 6, Issue 3 https://doi.org/10.1107/S0909049598017919	journal	May 1999

Cited By (2)

Lattice Distortion in Hollow Multi‐Shelled Structures for Efficient Visible‐Light CO ₂ Reduction with a SnS ₂ /SnO ₂ Junction You, Feifei; Wan, Jiawei; Qi, Jian Angewandte Chemie, Vol. 132, Issue 2 https://doi.org/10.1002/ange.201912069	journal	November 2019
Lattice Distortion in Hollow Multi‐Shelled Structures for Efficient Visible‐Light CO ₂ Reduction with a SnS ₂ /SnO ₂ Junction You, Feifei; Wan, Jiawei; Qi, Jian Angewandte Chemie International Edition, Vol. 59, Issue 2 https://doi.org/10.1002/anie.201912069	journal	January 2020

Similar Records

The electrochemical reactions of SnO₂ with Li and Na: A study using thin films and mesoporous carbons

Journal Article · Sat Feb 28 00:00:00 EST 2015 · Journal of Power Sources · OSTI ID:1491845

Górka, Joanna; Baggetto, Loïc; Keum, Jong K.; +4 more

In Situ Generation of Few-Layer Graphene Coatings on SnO₂-SiC Core-Shell Nanoparticles for High-Performance Lithium-Ion Storage

Journal Article · Wed Nov 16 00:00:00 EST 2011 · Advanced Energy Materials · OSTI ID:1491845

Chen, Zhongxue; Zhou, Min; Cao, Yuliang; +3 more

Dramatically enhanced reversibility of Li₂O in SnO₂-based electrodes: the effect of nanostructure on high initial reversible capacity

Journal Article · Tue Dec 01 00:00:00 EST 2015 · Energy & Environmental Science · OSTI ID:1491845

Hu, Renzong; Chen, Dongchang; Waller, Gordon; +7 more

Related Subjects

25 ENERGY STORAGE
36 MATERIALS SCIENCE
Li storage mechanism
SnO2 anodes
high electrochemical performance
metal oxide
nano-engineering

Title: Comparative study of bulk and nano-structured mesoporous SnO2 electrodes on the electrochemical performances for next generation Li rechargeable batteries

Citation Formats

References (60)

Cited By (2)

Similar Records

Related Subjects

Title: Comparative study of bulk and nano-structured mesoporous SnO₂ electrodes on the electrochemical performances for next generation Li rechargeable batteries