Probing charge transfer characteristics in a donor–acceptor metal–organic framework by Raman spectroelectrochemistry and pressure-dependence studies

Usov, Pavel M.; Leong, Chanel F.; Chan, Bun; Hayashi, Mikihiro; Kitagawa, Hiroshi; Sutton, Joshua J.; Gordon, Keith C.; Hod, Idan; Farha, Omar K.; Hupp, Joseph T.; Addicoat, Matthew; Kuc, Agnieszka Beata; Heine, Thomas; D’Alessandro, Deanna M.

doi:10.1039/C8CP04157A

Title: Probing charge transfer characteristics in a donor–acceptor metal–organic framework by Raman spectroelectrochemistry and pressure-dependence studies

Journal Article · Sun Jul 01 00:00:00 EDT 2018 · Physical Chemistry Chemical Physics. PCCP

DOI:https://doi.org/10.1039/C8CP04157A· OSTI ID:1491713

Usov, Pavel M. ^[1]; Leong, Chanel F. ^[1];

^[2]; Hayashi, Mikihiro ^[3];

^[3]; Sutton, Joshua J. ^[4];

^[4]; Hod, Idan ^[5]; Farha, Omar K. ^[5]; Hupp, Joseph T. ^[5]; Addicoat, Matthew ^[6]; Kuc, Agnieszka Beata ^[7];

^[8];

^[1]

Univ. of Sydney, NSW (Australia). School of Chemistry
Univ. of Sydney, NSW (Australia). School of Chemistry; Nagasaki Univ., Nagasaki (Japan). Graduate School of Engineering
Kyoto Univ. (Japan). Graduate School of Science, Division of Chemistry
Univ. of Otago, Dunedin (New Zealand). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Nottingham Trent Univ., Nottingham (England). School of Science and Technology; Univ. Leipzig, Leipzig (Germany). Wilhelm-Ostwald-Inst. for Physical and Theoretical Chemistry
Univ. Leipzig, Leipzig (Germany). Wilhelm-Ostwald-Inst. for Physical and Theoretical Chemistry; Helmholtz Center Dresden-Rossendorf, Inst. of Resource Ecology, Leipzig (Germany)
Univ. Leipzig, Leipzig (Germany). Wilhelm-Ostwald-Inst. for Physical and Theoretical Chemistry; Helmholtz Center Dresden-Rossendorf, Inst. of Resource Ecology, Leipzig (Germany); Dresden Univ. of Technology (Germany). School of Science, Faculty of Chemistry and Food Chemistry

The stimuli responsive behaviour of charge transfer donor–acceptor metal–organic frameworks (MOFs) remains an understudied phenomenon which may have applications in tuneable electronic materials. We now report the modification of donor–acceptor charge transfer characteristics in a semiconducting tetrathiafulvalene–naphthalene diimide-based MOF under applied electrochemical bias and pressure. Here, we employ a facile solid state in situ Raman spectroelectrochemical technique, applied for the first time in the characterisation of electroactive MOFs, to monitor the formation of a new complex TTFTC˙+–DPNI from a largely neutral system, upon electrochemical oxidation of the framework. In situ pressure-dependent Raman spectroscopy and powder X-ray diffraction experiments performed in a diamond anvil cell revealed blue shifts in the donor and acceptor vibrational modes in addition to contractions in the unit cell which are indicative of bond shortening. This study demonstrates the utility of in situ Raman spectroscopic techniques in the characterisation of redox-active MOFs and the elucidation of their electronic behaviours.

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Research Organization:: Univ. of Minnesota, Minneapolis, MN (United States). Nanoporous Materials Genome Center

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Contributing Organization:: Australian Research Council (ARC); SydneyNano; Vibrational Spectroscopy Core Facility at the University of Sydney

Grant/Contract Number:: SC0008688; FG02-17ER16362; Award DE-FG02-17ER16362; FG02-87ER13808

OSTI ID:: 1491713

Alternate ID(s):: OSTI ID: 1476118

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 20, Issue 40; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 24 works

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