Review—Multifunctional Separators: A Promising Approach for Improving the Durability and Performance of Li-Ion Batteries

Banerjee, Anjan; Ziv, Baruch; Shilina, Yuliya; Ziegelbauer, Joseph M.; Liu, Hanshuo; Harris, Kristopher J.; Botton, Gianluigi; Goward, Gillian R.; Luski, Shalom; Aurbach, Doron; Halalay, Ion C.

doi:10.1149/2.0561903jes

Title: Review—Multifunctional Separators: A Promising Approach for Improving the Durability and Performance of Li-Ion Batteries

Journal Article · Sat Jan 19 00:00:00 EST 2019 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0561903jes· OSTI ID:1491417

Banerjee, Anjan; Ziv, Baruch; Shilina, Yuliya; Ziegelbauer, Joseph M.; Liu, Hanshuo; Harris, Kristopher J.; Botton, Gianluigi; Goward, Gillian R.; Luski, Shalom;

;

Electrified vehicles require Li-ion batteries (LIBs) with 10-year useful life. We review herein our progress since 2016 in the understanding of dissolved Mn species and LIB performance degradation by multifunctional materials. Multifunctional separators (MFSs), can trap Mn cations, scavenge acid species, and/or dispense alkali metal ions, with significant battery performance benefits: increased capacity retention during electrochemical cycling and improved rate performance. Cells with LiMn₂O₄ (LMO), LiNi_0.6Mn_0.2Co_0.2O₂ (NCM622), or LiNi_0.5Mn_1.5O₄ (LNMO) positive electrodes, graphite negative electrodes, and LiPF₆/mixed organic carbonate solutions were investigated. XRD, ICP-OES, XANES, HR-SEM, FIB-SEM, and MAS-NMR on harvested cell components complemented and aided the interpretation of electrochemical test results.While in LIBs with positive electrodes affected by Mn dissolution cell performance improvements can be enabled by delaying and then impeding the deposition of transition metal (TM) ions deposition at negative electrodes through their trapping by MFS, acid scavenging separators provide a more general approach that can enable performance benefits in cells with non-spinel positive electrode materials such as NCM622, as well as with 5 V class positive electrode materials such as LNMO. We illustrate our discussion with both previously published and new data. We conclude with a discussion of remaining challenges, new opportunities, and recommendations for future work.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: Israel Science Foundation (ISF); Israeli Prime Minister Office; Israel Committee of High Education; Natural Sciences and Engineering Research Council of Canada (NSERC); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-06CH11357; CRDPJ494074-16

OSTI ID:: 1491417

Alternate ID(s):: OSTI ID: 1492971

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Vol. 166 Journal Issue: 3; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 22 works

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References (69)

Spinel electrodes for lithium batteries — A review Thackeray, M. M.; de Picciotto, L. A.; de Kock, A. Journal of Power Sources, Vol. 21, Issue 1 https://doi.org/10.1016/0378-7753(87)80071-X	journal	August 1987
A facile method for construction of a functionalized multi-layered separator to enhance cycle performance of lithium manganese oxide Yim, Taeeun; Ha, Hyo-Jeong; Park, Min-Sik RSC Advances, Vol. 3, Issue 48 https://doi.org/10.1039/c3ra44917c	journal	January 2013
Editors' Choice—The Effectiveness of Multifunctional Li-Ion Battery Separators past Their Saturation with Transition Metal Ions Banerjee, Anjan; Ziv, Baruch; Luski, Shalom Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.0321810jes	journal	January 2018
Rechargeable Batteries: Grasping for the Limits of Chemistry Berg, Erik J.; Villevieille, Claire; Streich, Daniel Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0081514jes	journal	January 2015
Dissolution of Spinel Oxides and Capacity Losses in 4V Li / Li_xMn₂O₄ Cells Jang, Dong H.; Shin, Young J.; Oh, Seung M. Journal of The Electrochemical Society, Vol. 143, Issue 7, p. 2204-2211 https://doi.org/10.1149/1.1836981	journal	January 1996
Reaction Energy for LiMn[sub 2]O[sub 4] Spinel Dissolution in Acid Benedek, R.; Thackeray, M. M. Electrochemical and Solid-State Letters, Vol. 9, Issue 6 https://doi.org/10.1149/1.2188071	journal	January 2006
Ultrathin Surface Coatings for Improved Electrochemical Performance of Lithium Ion Battery Electrodes at Elevated Temperature Zhao, Jianqing; Wang, Ying The Journal of Physical Chemistry C, Vol. 116, Issue 22 https://doi.org/10.1021/jp3010629	journal	May 2012
Effect of lithium difluoro(oxalato)borate and heptamethyldisilazane with different concentrations on cycling performance of LiMn2O4 Wu, Xianwen; Wang, Zhixing; Li, Xinhai Journal of Power Sources, Vol. 204 https://doi.org/10.1016/j.jpowsour.2011.12.012	journal	April 2012
Manganese in Graphite Anode and Capacity Fade in Li Ion Batteries Shkrob, Ilya A.; Kropf, A. Jeremy; Marin, Timothy W. The Journal of Physical Chemistry C, Vol. 118, Issue 42 https://doi.org/10.1021/jp507833u	journal	October 2014
The elevated temperature performance of the LiMn₂O₄/C system: failure and solutions Amatucci, G.; Du Pasquier, A.; Blyr, A. Electrochimica Acta, Vol. 45, Issue 1-2, p. 255-271 https://doi.org/10.1016/S0013-4686(99)00209-1	journal	September 1999
Challenges Facing Lithium Batteries and Electrical Double-Layer Capacitors Choi, Nam-Soon; Chen, Zonghai; Freunberger, Stefan A. Angewandte Chemie International Edition, Vol. 51, Issue 40 https://doi.org/10.1002/anie.201201429	journal	September 2012
On the Oxidation State of Manganese Ions in Li-Ion Battery Electrolyte Solutions Banerjee, Anjan; Shilina, Yuliya; Ziv, Baruch Journal of the American Chemical Society, Vol. 139, Issue 5 https://doi.org/10.1021/jacs.6b10781	journal	January 2017
Mn(II) deposition on anodes and its effects on capacity fade in spinel lithium manganate–carbon systems Zhan, Chun; Lu, Jun; Jeremy Kropf, A. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3437	journal	September 2013
Synthesis and Electrochemical Properties of Layered Li_0.9Ni_0.45Ti_0.55O₂ Kang, Kisuk; Carlier, Dany; Reed, John Chemistry of Materials, Vol. 15, Issue 23 https://doi.org/10.1021/cm034455+	journal	October 2003
New Horizons for Conventional Lithium Ion Battery Technology Erickson, Evan M.; Ghanty, Chandan; Aurbach, Doron The Journal of Physical Chemistry Letters, Vol. 5, Issue 19 https://doi.org/10.1021/jz501387m	journal	September 2014
Improving Stability of Li-Ion Batteries by Means of Transition Metal Ions Trapping Separators Banerjee, Anjan; Ziv, Baruch; Shilina, Yuliya Journal of The Electrochemical Society, Vol. 163, Issue 6 https://doi.org/10.1149/2.0081607jes	journal	January 2016
Experimental and Theoretical Investigations of Dimethylacetamide (DMAc) as Electrolyte Stabilizing Additive for Lithium Ion Batteries Xu, Mengqing; Hao, Liansheng; Liu, Yanlin The Journal of Physical Chemistry C, Vol. 115, Issue 13 https://doi.org/10.1021/jp109562u	journal	March 2011
Surface Structure Evolution of LiMn ₂ O ₄ Cathode Material upon Charge/Discharge Tang, Daichun; Sun, Yang; Yang, Zhenzhong Chemistry of Materials, Vol. 26, Issue 11 https://doi.org/10.1021/cm501125e	journal	May 2014
LiNi0.5+δMn0.5–δO2—A High-Rate, High-Capacity Cathode for Lithium Rechargeable Batteries Schougaard, S. B.; Bréger, J.; Jiang, M. Advanced Materials, Vol. 18, Issue 7 https://doi.org/10.1002/adma.200500113	journal	April 2006
Electrolyte Effects on Spinel Dissolution and Cathodic Capacity Losses in 4 V Li∕Li[sub x]Mn[sub 2]O[sub 4] Rechargeable Cells Jang, Dong H. Journal of The Electrochemical Society, Vol. 144, Issue 10 https://doi.org/10.1149/1.1838016	journal	January 1997
Improved lithium-ion battery performance of LiNi0.5Mn1.5−xTixO4 high voltage spinel in full-cells paired with graphite and Li4Ti5O12 negative electrodes Kim, Jung-Hyun; Pieczonka, Nicholas P. W.; Sun, Yang-Kook Journal of Power Sources, Vol. 262 https://doi.org/10.1016/j.jpowsour.2014.03.107	journal	September 2014
Role of surface coating on cathode materials for lithium-ion batteries Chen, Zonghai; Qin, Yan; Amine, Khalil Journal of Materials Chemistry, Vol. 20, Issue 36, p. 7606-7612 https://doi.org/10.1039/c0jm00154f	journal	January 2010
Surface Analysis of Electrodes from Cells Containing Electrolytes with Stabilizing Additives Exposed to High Temperature Li, W.; Xiao, A.; Lucht, B. L. Journal of The Electrochemical Society, Vol. 155, Issue 9 https://doi.org/10.1149/1.2949507	journal	January 2008
Influence of Manganese Dissolution on the Degradation of Surface Films on Edge Plane Graphite Negative-Electrodes in Lithium-Ion Batteries Ochida, Manabu; Domi, Yasuhiro; Doi, Takayuki Journal of The Electrochemical Society, Vol. 159, Issue 7 https://doi.org/10.1149/2.031207jes	journal	January 2012
Materials' effects on the elevated and room temperature performance of CLiMn2O4 Li-ion batteries Amatucci, G. G.; Schmutz, C. N.; Blyr, A. Journal of Power Sources, Vol. 69, Issue 1-2 https://doi.org/10.1016/S0378-7753(97)02542-1	journal	November 1997
Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li ₂ MnO ₃ −LiCo _1/3 Ni _1/3 Mn _1/3 O ₂ Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek Journal of the American Chemical Society, Vol. 133, Issue 12 https://doi.org/10.1021/ja108588y	journal	March 2011
Manganese sequestration and improved high-temperature cycling of Li-ion batteries by polymeric aza-15-crown-5 Li, Zicheng; Pauric, Allen D.; Goward, Gillian R. Journal of Power Sources, Vol. 272 https://doi.org/10.1016/j.jpowsour.2014.04.073	journal	December 2014
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Acid-Scavenging Separators: A Novel Route for Improving Li-Ion Batteries’ Durability Banerjee, Anjan; Ziv, Baruch; Shilina, Yuliya ACS Energy Letters, Vol. 2, Issue 10 https://doi.org/10.1021/acsenergylett.7b00763	journal	September 2017
Low temperature preparation of crystalline ZrO2 coatings for improved elevated-temperature performances of Li-ion battery cathodes Zhao, Jianqing; Qu, Guoying; Flake, John C. Chemical Communications, Vol. 48, Issue 65 https://doi.org/10.1039/c2cc33522k	journal	January 2012
Study of Mn dissolution from LiMn2O4 spinel electrodes using in situ total reflection X-ray fluorescence analysis and fluorescence XAFS technique Terada, Yasuko; Nishiwaki, Yoshinori; Nakai, Izumi Journal of Power Sources, Vol. 97-98 https://doi.org/10.1016/S0378-7753(01)00741-8	journal	July 2001
Effect of heptamethyldisilazane as an additive on the stability performance of LiMn2O4 cathode for lithium-ion battery Li, Yongkun; Zhang, Ruoxin; Liu, Jiansheng Journal of Power Sources, Vol. 189, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.08.075	journal	April 2009
A review of advanced and practical lithium battery materials Marom, Rotem; Amalraj, S. Francis; Leifer, Nicole Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/c0jm04225k	journal	January 2011
Revealing the Reconstructed Surface of Li[Mn ₂ ]O ₄ Amos, Charles D.; Roldan, Manuel A.; Varela, Maria Nano Letters, Vol. 16, Issue 5 https://doi.org/10.1021/acs.nanolett.5b03926	journal	April 2016
A review on the key issues for lithium-ion battery management in electric vehicles Lu, Languang; Han, Xuebing; Li, Jianqiu Journal of Power Sources, Vol. 226, p. 272-288 https://doi.org/10.1016/j.jpowsour.2012.10.060	journal	March 2013
Effect of Ti Substitution for Mn on the Structure of LiNi[sub 0.5]Mn[sub 1.5−x]Ti[sub x]O[sub 4] and Their Electrochemical Properties as Lithium Insertion Material Kim, J. -H.; Myung, S. -T.; Yoon, C. S. Journal of The Electrochemical Society, Vol. 151, Issue 11 https://doi.org/10.1149/1.1805524	journal	January 2004
Factors Influencing the Capacity Fade of Spinel Lithium Manganese Oxides Shin, Youngjoon; Manthiram, Arumugam Journal of The Electrochemical Society, Vol. 151, Issue 2 https://doi.org/10.1149/1.1634274	journal	January 2004
Improved cycle lives of LiMn2O4 cathodes in lithium ion batteries by an alginate biopolymer from seaweed Ryou, Myung-Hyun; Hong, Seonki; Winter, Martin Journal of Materials Chemistry A, Vol. 1, Issue 48 https://doi.org/10.1039/c3ta13514d	journal	January 2013
Optimization of Insertion Compounds Such as LiMn₂O₄ for Li-Ion Batteries Amatucci, G.; Tarascon, J.-M. Journal of The Electrochemical Society, Vol. 149, Issue 12, p. K31-K46 https://doi.org/10.1149/1.1516778	journal	November 2002
Atomic layer deposition of epitaxial ZrO2 coating on LiMn2O4 nanoparticles for high-rate lithium ion batteries at elevated temperature Zhao, Jianqing; Wang, Ying Nano Energy, Vol. 2, Issue 5 https://doi.org/10.1016/j.nanoen.2013.03.005	journal	September 2013
Review—Multifunctional Materials for Enhanced Li-Ion Batteries Durability: A Brief Review of Practical Options Banerjee, Anjan; Shilina, Yuliya; Ziv, Baruch Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0451701jes	journal	January 2017
A comparative study of different binders and their effects on electrochemical properties of LiMn 2 O 4 cathode in lithium ion batteries Zhang, Zhian; Zeng, Tao; Lai, Yanqing Journal of Power Sources, Vol. 247 https://doi.org/10.1016/j.jpowsour.2013.08.051	journal	February 2014
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P. Journal of The Electrochemical Society, Vol. 164, Issue 2 https://doi.org/10.1149/2.1111702jes	journal	December 2016
Elucidating the Li-Ion Battery Performance Benefits Enabled by Multifunctional Separators Liu, Hanshuo; Banerjee, Anjan; Ziv, Baruch ACS Applied Energy Materials, Vol. 1, Issue 5 https://doi.org/10.1021/acsaem.8b00436	journal	April 2018
Combined Electron Paramagnetic Resonance and Atomic Absorption Spectroscopy/Inductively Coupled Plasma Analysis As Diagnostics for Soluble Manganese Species from Mn-Based Positive Electrode Materials in Li-ion Cells Shilina, Yuliya; Ziv, Baruch; Meir, Aviv Analytical Chemistry, Vol. 88, Issue 8 https://doi.org/10.1021/acs.analchem.6b00204	journal	April 2016
Superior Capacity Retention Spinel Oxyfluoride Cathodes for Lithium-Ion Batteries Choi, W.; Manthiram, A. Electrochemical and Solid-State Letters, Vol. 9, Issue 5, p. A245-A248 https://doi.org/10.1149/1.2186022	journal	March 2006
A Study on the Cause of Deterioration in Float-Charged Lithium-Ion Batteries Using LiMn[sub 2]O[sub 4] as a Cathode Active Material Tsujikawa, Tomonobu; Yabuta, Kaho; Matsushita, Takashi Journal of The Electrochemical Society, Vol. 158, Issue 3 https://doi.org/10.1149/1.3543651	journal	January 2011
Preparation and performance of layered Li[Li 0.182 Ni 0.182 Co 0.091 Mn 0.545 ]O 2 cathode with different binders Han, Zenghui; Zhan, Hui; Zhou, Yunhong Materials Letters, Vol. 114 https://doi.org/10.1016/j.matlet.2013.09.072	journal	January 2014
Mechanism for Limited 55°C Storage Performance of Li[sub 1.05]Mn[sub 1.95]O[sub 4] Electrodes Du Pasquier, A. Journal of The Electrochemical Society, Vol. 146, Issue 2 https://doi.org/10.1149/1.1391625	journal	January 1999
Lithium Polyacrylate (LiPAA) as an Advanced Binder and a Passivating Agent for High-Voltage Li-Ion Batteries Pieczonka, Nicholas P. W.; Borgel, Valentina; Ziv, Baruch Advanced Energy Materials, Vol. 5, Issue 23 https://doi.org/10.1002/aenm.201501008	journal	September 2015
Degradation of spinel lithium manganese oxides by low oxidation durability of LiPF6-based electrolyte at 60°C Choi, Nam-Soon; Yeon, Jin-Tak; Lee, Yong-Won Solid State Ionics, Vol. 219 https://doi.org/10.1016/j.ssi.2012.05.012	journal	July 2012
Tris(trimethylsilyl) borate as an electrolyte additive to improve the cyclability of LiMn2O4 cathode for lithium-ion battery Liu, Yanbo; Tan, Lei; Li, Lei Journal of Power Sources, Vol. 221 https://doi.org/10.1016/j.jpowsour.2012.08.028	journal	January 2013
Multifunctional Manganese Ions Trapping and Hydrofluoric Acid Scavenging Separator for Lithium Ion Batteries Based on Poly(ethylene- alternate -maleic acid) Dilithium Salt Banerjee, Anjan; Ziv, Baruch; Shilina, Yuliya Advanced Energy Materials, Vol. 7, Issue 3 https://doi.org/10.1002/aenm.201601556	journal	October 2016
Positive Electrode Materials for Li-Ion and Li-Batteries ^† Ellis, Brian L.; Lee, Kyu Tae; Nazar, Linda F. Chemistry of Materials, Vol. 22, Issue 3 https://doi.org/10.1021/cm902696j	journal	February 2010
Who will drive electric vehicles, olivine or spinel? Park, Ok Kyung; Cho, Yonghyun; Lee, Sanghan Energy & Environmental Science, Vol. 4, Issue 5 https://doi.org/10.1039/c0ee00559b	journal	January 2011
Self-Discharge of LiMn[sub 2]O[sub 4]/C Li-Ion Cells in Their Discharged State Blyr, A. Journal of The Electrochemical Society, Vol. 145, Issue 1 https://doi.org/10.1149/1.1838235	journal	January 1998
In Situ Formation of a Cathode-Electrolyte Interface with Enhanced Stability by Titanium Substitution for High Voltage Spinel Lithium-Ion Batteries Kim, Jung-Hyun; Pieczonka, Nicholas P. W.; Lu, Peng Advanced Materials Interfaces, Vol. 2, Issue 10 https://doi.org/10.1002/admi.201500109	journal	May 2015
Cathode materials modified by surface coating for lithium ion batteries Li, C.; Zhang, H. P.; Fu, L. J. Electrochimica Acta, Vol. 51, Issue 19 https://doi.org/10.1016/j.electacta.2005.11.015	journal	May 2006
An update on the high temperature ageing mechanism in LiMn2O4-based Li-ion cells du Pasquier, A.; Blyr, A.; Cressent, A. Journal of Power Sources, Vol. 81-82 https://doi.org/10.1016/S0378-7753(99)00136-6	journal	September 1999
Oxidation state of cross-over manganese species on the graphite electrode of lithium-ion cells Gowda, Sanketh R.; Gallagher, Kevin G.; Croy, Jason R. Physical Chemistry Chemical Physics, Vol. 16, Issue 15 https://doi.org/10.1039/c4cp00764f	journal	January 2014
Strategies for improving the cyclability and thermo-stability of LiMn ₂ O ₄ -based batteries at elevated temperatures Xu, Gaojie; Liu, Zhihong; Zhang, Chuanjian Journal of Materials Chemistry A, Vol. 3, Issue 8 https://doi.org/10.1039/C4TA06264G	journal	January 2015
Influence of manganese(II), cobalt(II), and nickel(II) additives in electrolyte on performance of graphite anode for lithium-ion batteries Komaba, Shinichi; Kumagai, Naoaki; Kataoka, Yoichi Electrochimica Acta, Vol. 47, Issue 8 https://doi.org/10.1016/S0013-4686(01)00847-7	journal	February 2002
Ion-Exchangeable Functional Binders and Separator for High Temperature Performance of Li _1.1 Mn _1.86 Mg _0.04 O ₄ Spinel Electrodes in Lithium Ion Batteries Woo, Seung Hee; Lim, Hyung-Woo; Jeon, Sangbin Journal of The Electrochemical Society, Vol. 160, Issue 11 https://doi.org/10.1149/2.092311jes	journal	January 2013
Increasing the durability of Li-ion batteries by means of manganese ion trapping materials with nitrogen functionalities Banerjee, Anjan; Ziv, Baruch; Luski, Shalom Journal of Power Sources, Vol. 341 https://doi.org/10.1016/j.jpowsour.2016.12.036	journal	February 2017
Surface modification of cathode materials from nano- to microscale for rechargeable lithium-ion batteries Myung, Seung-Taek; Amine, Khalil; Sun, Yang-Kook Journal of Materials Chemistry, Vol. 20, Issue 34 https://doi.org/10.1039/c0jm00508h	journal	January 2010
The Formation Mechanism of Fluorescent Metal Complexes at the Li _x Ni _0.5 Mn _1.5 O _4−δ /Carbonate Ester Electrolyte Interface Jarry, Angélique; Gottis, Sébastien; Yu, Young-Sang Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/ja5116698	journal	March 2015
Understanding Transition-Metal Dissolution Behavior in LiNi _0.5 Mn _1.5 O ₄ High-Voltage Spinel for Lithium Ion Batteries Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng The Journal of Physical Chemistry C, Vol. 117, Issue 31 https://doi.org/10.1021/jp405158m	journal	July 2013
Simulation of Aqueous Dissolution of Lithium Manganate Spinel from First Principles Benedek, R.; Thackeray, M. M.; Low, J. The Journal of Physical Chemistry C, Vol. 116, Issue 6 https://doi.org/10.1021/jp208793k	journal	February 2012
Manganese Sequestration and Li-Ion Batteries Durability Enhancement by Polymeric 18-Crown-6 Ethers Ziv, Baruch; Levy, Naomi; Borgel, Valentina Journal of The Electrochemical Society, Vol. 161, Issue 9 https://doi.org/10.1149/2.0091409jes	journal	January 2014

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