Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission

Lin, Haoran; Zhou, Chenkun; Neu, Jennifer; Zhou, Yan; Han, Dan; Chen, Shiyou; Worku, Michael; Chaaban, Maya; Lee, Sujin; Berkwits, Ella; Siegrist, Theo; Du, Mao ‐Hua; Ma, Biwu

doi:10.1002/adom.201801474

Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission

Journal Article · Mon Jan 14 23:00:00 EST 2019 · Advanced Optical Materials

DOI:https://doi.org/10.1002/adom.201801474· OSTI ID:1507863

Lin, Haoran ^[1]; Zhou, Chenkun ^[2]; Neu, Jennifer ^[1]; Zhou, Yan ^[1]; ^[3]; Chen, Shiyou ^[4]; Worku, Michael ^[1]; Chaaban, Maya ^[1]; Lee, Sujin ^[1]; Berkwits, Ella ^[2]; Siegrist, Theo ^[5]; ^[3]; ^[1]

Florida State Univ., Tallahassee, FL (United States)
FAMU‐FSU College of Engineering, Tallahassee, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
East China Normal Univ., Shanghai (China)
FAMU‐FSU College of Engineering, Tallahassee, FL (United States); Florida State Univ., Tallahassee, FL (United States)

Here, the family of molecular level low–dimensional organic metal halide hybrids has expanded significantly over the last few years. Here a new type of 1D metal halide structure is reported, in which metal halide octahedra form a corrugated double–chain structure via nonplanar edge–sharing. This material with a chemical formula of C₅H₁₆N₂Pb₂Br₆ exhibits a broadband yellow emission under ultraviolet light excitation with a photoluminescence quantum efficiency of around 10%. The light–yellow emission is considered to be attributed to self–trapping excitons. Theoretical calculations show that the unique alignment of the octahedra leads to small band dispersion and large exciton binding energy. Together with previously reported 1D metal halide wires and tubes, this new bulk assembly of 1D metal halides suggests the potential to develop a library of bulk assemblies of metal halides with controlled structures and compositions.

View Accepted Manuscript (DOE)

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1507863

Alternate ID(s):: OSTI ID: 1490909

Journal Information:: Advanced Optical Materials, Journal Name: Advanced Optical Materials Journal Issue: 6 Vol. 7; ISSN 2195-1071

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (40)

Green-Light-Emitting Diodes based on Tetrabromide Manganese(II) Complex through Solution Process Xu, Liang-Jin; Sun, Cheng-Zhe; Xiao, Hui Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605739	journal	December 2016
A Microscale Perovskite as Single Component Broadband Phosphor for Downconversion White-Light-Emitting Devices Yuan, Zhao; Zhou, Chenkun; Messier, Joshua Advanced Optical Materials, Vol. 4, Issue 12 https://doi.org/10.1002/adom.201600667	journal	September 2016
Semiconductive Nanotube Array Constructed from Giant [Pb ^II ₁₈ I ₅₄ (I ₂ ) ₉ ] Wheel Clusters Wang, Guan-E; Xu, Gang; Liu, Bin-Wen Angewandte Chemie, Vol. 128, Issue 2 https://doi.org/10.1002/ange.201507083	journal	November 2015
Semiconductive Nanotube Array Constructed from Giant [Pb ^II ₁₈ I ₅₄ (I ₂ ) ₉ ] Wheel Clusters Wang, Guan-E; Xu, Gang; Liu, Bin-Wen Angewandte Chemie International Edition, Vol. 55, Issue 2 https://doi.org/10.1002/anie.201507083	journal	November 2015
Progress and Perspective in Low-Dimensional Metal Halide Perovskites for Optoelectronic Applications Chen, Peng; Bai, Yang; Lyu, Miaoqiang Solar RRL, Vol. 2, Issue 3 https://doi.org/10.1002/solr.201700186	journal	February 2018
Low dimensional metal halide perovskites and hybrids Zhou, Chenkun; Lin, Haoran; He, Qingquan Materials Science and Engineering: R: Reports, Vol. 137 https://doi.org/10.1016/j.mser.2018.12.001	journal	July 2019
Synthesis, structure and optical properties of different dimensional organic–inorganic perovskites Li, Yinyan; Zheng, Guoli; Lin, Cuikun Solid State Sciences, Vol. 9, Issue 9 https://doi.org/10.1016/j.solidstatesciences.2007.06.011	journal	September 2007
Colloidal Synthesis of Strongly Fluorescent CsPbBr ₃ Nanowires with Width Tunable down to the Quantum Confinement Regime Imran, Muhammad; Di Stasio, Francesco; Dang, Zhiya Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b03081	journal	September 2016
Intriguing Optoelectronic Properties of Metal Halide Perovskites Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V. Chemical Reviews, Vol. 116, Issue 21 https://doi.org/10.1021/acs.chemrev.6b00136	journal	June 2016
The Role of Connectivity on Electronic Properties of Lead Iodide Perovskite-Derived Compounds Kamminga, Machteld E.; de Wijs, Gilles A.; Havenith, Remco W. A. Inorganic Chemistry, Vol. 56, Issue 14 https://doi.org/10.1021/acs.inorgchem.7b01096	journal	June 2017
Zero-Dimensional Hybrid Organic–Inorganic Halide Perovskite Modeling: Insights from First Principles Giorgi, Giacomo; Yamashita, Koichi The Journal of Physical Chemistry Letters, Vol. 7, Issue 5 https://doi.org/10.1021/acs.jpclett.6b00122	journal	February 2016
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites Hu, Te; Smith, Matthew D.; Dohner, Emma R. The Journal of Physical Chemistry Letters, Vol. 7, Issue 12 https://doi.org/10.1021/acs.jpclett.6b00793	journal	May 2016
Low-Dimensional Organometal Halide Perovskites Lin, Haoran; Zhou, Chenkun; Tian, Yu ACS Energy Letters, Vol. 3, Issue 1 https://doi.org/10.1021/acsenergylett.7b00926	journal	November 2017
A One-Dimensional Organic Lead Chloride Hybrid with Excitation-Dependent Broadband Emissions Wu, Guanhong; Zhou, Chenkun; Ming, Wenmei ACS Energy Letters, Vol. 3, Issue 6 https://doi.org/10.1021/acsenergylett.8b00661	journal	May 2018
Self-Assembly of Broadband White-Light Emitters Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja411045r	journal	January 2014
Trap States in Lead Iodide Perovskites Wu, Xiaoxi; Trinh, M. Tuan; Niesner, Daniel Journal of the American Chemical Society, Vol. 137, Issue 5 https://doi.org/10.1021/ja512833n	journal	January 2015
A Methylviologen Lead(II) Iodide: Novel [PbI ₃ ^- ] _∞ Chains with Mixed Octahedral and Trigonal Prismatic Coordination Tang, Zhongjia; Guloy, Arnold M. Journal of the American Chemical Society, Vol. 121, Issue 2 https://doi.org/10.1021/ja982702i	journal	January 1999
Ligand-Stabilized Reduced-Dimensionality Perovskites Quan, Li Na; Yuan, Mingjian; Comin, Riccardo Journal of the American Chemical Society, Vol. 138, Issue 8 https://doi.org/10.1021/jacs.5b11740	journal	February 2016
Broadband Emission in Two-Dimensional Hybrid Perovskites: The Role of Structural Deformation Cortecchia, Daniele; Neutzner, Stefanie; Srimath Kandada, Ajay Ram Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b10390	journal	December 2016
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C. Journal of the American Chemical Society, Vol. 139, Issue 14 https://doi.org/10.1021/jacs.7b01312	journal	March 2017
All-in-One: Achieving Robust, Strongly Luminescent and Highly Dispersible Hybrid Materials by Combining Ionic and Coordinate Bonds in Molecular Crystals Liu, Wei; Zhu, Kun; Teat, Simon J. Journal of the American Chemical Society, Vol. 139, Issue 27 https://doi.org/10.1021/jacs.7b04550	journal	June 2017
Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature Nazarenko, Olga; Kotyrba, Martin R.; Yakunin, Sergii Journal of the American Chemical Society, Vol. 140, Issue 11 https://doi.org/10.1021/jacs.8b00194	journal	February 2018
Hybrid Dion–Jacobson 2D Lead Iodide Perovskites Mao, Lingling; Ke, Weijun; Pedesseau, Laurent Journal of the American Chemical Society, Vol. 140, Issue 10 https://doi.org/10.1021/jacs.8b00542	journal	February 2018
Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites Mao, Lingling; Guo, Peijun; Kepenekian, Mikaël Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b08691	journal	September 2018
One-dimensional organic lead halide perovskites with efficient bluish white-light emission Yuan, Zhao; Zhou, Chenkun; Tian, Yu Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14051	journal	January 2017
[Bmim] ₂ SbCl ₅ : a main group metal-containing ionic liquid exhibiting tunable photoluminescence and white-light emission Wang, Ze-Ping; Wang, Jin-Yun; Li, Jian-Rong Chemical Communications, Vol. 51, Issue 15 https://doi.org/10.1039/C4CC08825E	journal	January 2015
Lead-free pseudo-three-dimensional organic–inorganic iodobismuthates for photovoltaic applications Li, Tianyue; Hu, Yue; Morrison, Carole A. Sustainable Energy & Fuels, Vol. 1, Issue 2 https://doi.org/10.1039/C6SE00061D	journal	January 2017
Bulk assembly of organic metal halide nanotubes Lin, Haoran; Zhou, Chenkun; Tian, Yu Chemical Science, Vol. 8, Issue 12 https://doi.org/10.1039/C7SC03675B	journal	January 2017
Luminescent zero-dimensional organic metal halide hybrids with near-unity quantum efficiency Zhou, Chenkun; Lin, Haoran; Tian, Yu Chemical Science, Vol. 9, Issue 3 https://doi.org/10.1039/C7SC04539E	journal	January 2018
Broadband white-light emission with a high color rendering index in a two-dimensional organic–inorganic hybrid perovskite Wu, Zhenyue; Ji, Chengmin; Sun, Zhihua Journal of Materials Chemistry C, Vol. 6, Issue 5 https://doi.org/10.1039/C7TC04868H	journal	January 2018
White-light emission in a chiral one-dimensional organic–inorganic hybrid perovskite Peng, Yu; Yao, Yunpeng; Li, Lina Journal of Materials Chemistry C, Vol. 6, Issue 22 https://doi.org/10.1039/C8TC01150H	journal	January 2018
Unraveling luminescence mechanisms in zero-dimensional halide perovskites Han, Dan; Shi, Hongliang; Ming, Wenmei Journal of Materials Chemistry C, Vol. 6, Issue 24 https://doi.org/10.1039/C8TC01291A	journal	January 2018
Preparation, structure and optical properties of [CH3SC(NH2)NH2]3PbI5, [CH3SC(NH2)NH2]4Pb2Br8and [CH3SC(NH2)NH2]3PbCl5·CH3SC(NH2)NH2Cl Mousdis, G. A.; Gionis, V.; Papavassiliou, G. C. Journal of Materials Chemistry, Vol. 8, Issue 10 https://doi.org/10.1039/a802926a	journal	January 1998
Organic–inorganic metal halide hybrids beyond perovskites Zhou, Chenkun; Lin, Haoran; Lee, Sujin Materials Research Letters, Vol. 6, Issue 10 https://doi.org/10.1080/21663831.2018.1500951	journal	July 2018
Direct observation of electron self-trapping in PbCl 2 crystals Nistor, S. V.; Goovaerts, E.; Schoemaker, D. Physical Review B, Vol. 48, Issue 13 https://doi.org/10.1103/PhysRevB.48.9575	journal	October 1993
Self-trapped electrons and holes in PbBr 2 crystals Iwanaga, Masanobu; Azuma, Junpei; Shirai, Masanobu Physical Review B, Vol. 65, Issue 21 https://doi.org/10.1103/PhysRevB.65.214306	journal	June 2002
Atomically thin two-dimensional organic-inorganic hybrid perovskites Dou, L.; Wong, A. B.; Yu, Y. Science, Vol. 349, Issue 6255 https://doi.org/10.1126/science.aac7660	journal	September 2015
Preparation, Structure and Optical Properties of [CH3SC(NH2)2]3SnI5, [CH3SC(NH2)2][HSC(NH2)2]SnBr4, (CH3C5H4NCH3)PbBr3, and [C6H5CH2SC(NH2)2]4Pb3I10 Raptopoulou, C. P.; Terzis, A.; Mousdis, G. A. Zeitschrift für Naturforschung B, Vol. 57, Issue 6 https://doi.org/10.1515/znb-2002-0609	journal	June 2002
Guanidinium-Formamidinium Lead Iodide: A Layered Perovskite-Related Compound with Red Luminescence at Room Temperature Nazarenko, Olga; Kotyrba, Martin R.; Yakunin, Sergii ETH Zurich https://doi.org/10.3929/ethz-b-000254379	text	January 2018
Colloidal Synthesis of Strongly Fluorescent CsPbBr3 Nanowires with Width Tunable down to the Quantum Confinement Regime Imran, Muhammad; Di Stasio, Francesco; Dang, Zhiya arXiv https://doi.org/10.48550/arxiv.1610.07909	text	January 2016

Cited By (6)

Microwave Absorption of Organic Metal Halide Nanotubes Lin, Haoran; Green, Michael; Xu, Liang‐Jin Advanced Materials Interfaces, Vol. 7, Issue 3 https://doi.org/10.1002/admi.201901270	journal	December 2019
[DMEDA]PbCl ₄ : a one-dimensional organic lead halide perovskite with efficient yellow emission Sun, Chen; Yue, Yun-Di; Zhang, Wei-Feng CrystEngComm, Vol. 22, Issue 8 https://doi.org/10.1039/c9ce01816f	journal	January 2020
A hybrid blue perovskite@metal–organic gel (MOG) nanocomposite: simultaneous improvement of luminescence and stability Mollick, Samraj; Mandal, Tarak Nath; Jana, Atanu Chemical Science, Vol. 10, Issue 45 https://doi.org/10.1039/c9sc03829a	journal	January 2019
A three-dimensional cuprous lead bromide framework with highly efficient and stable thermochromic luminescence properties Jing, Chang-Qing; Wu, Jia-Hang; Cao, Yao-Yao Chemical Communications https://doi.org/10.1039/d0cc01779e	journal	January 2020
Microscopic origin of multiple exciton emission in low-dimensional lead halide perovskites Du, Mao-Hua The Journal of Chemical Physics, Vol. 151, Issue 18 https://doi.org/10.1063/1.5127933	journal	November 2019
Optical anisotropy of one-dimensional perovskite C ₄ N ₂ H ₁₄ PbI ₄ crystals Cheng, Xue; Ma, Jiaqi; Zhou, Yunxi Journal of Physics: Photonics, Vol. 2, Issue 1 https://doi.org/10.1088/2515-7647/ab6743	journal	January 2020

Similar Records

Bulk assembly of organic metal halide nanotubes

Journal Article · Mon Oct 16 00:00:00 EDT 2017 · Chemical Science · OSTI ID:1410201

A One-Dimensional Organic Lead Chloride Hybrid with Excitation-Dependent Broadband Emissions

Journal Article · Wed May 23 00:00:00 EDT 2018 · ACS Energy Letters · OSTI ID:1440827

Related Subjects

1D structures
36 MATERIALS SCIENCE
exciton self‐trapping
organic metal halide hybrids
photoluminescence
quantum confinement effect

Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission

Citation Formats

References (40)

Cited By (6)

Linked Research (1)

Similar Records

Related Subjects