Review of Time-Series Data for the Agra Interim Measure, Fall 2013
- Argonne National Lab. (ANL), Argonne, IL (United States)
The Commodity Credit Corporation of the U.S. Department of Agriculture (CCC/USDA) operated a grain storage facility at Agra, Kansas, from the 1950s to the early 1970s. No structures remain on the property, and the land is used for agricultural purposes, specifically wheat production. The property is currently owned by the Kyle Railroad Co. and is leased to Mr. Herb VanEaton. The Pro-Ag Marketing grain storage facility is directly south of the former CCC/USDA facility. In 1985, carbon tetrachloride was detected in groundwater samples collected from Agra public water supply wells PWS-3 and PWS-4, located approximately 2,000 ft south of the former CCC/USDA facility and approximately 1,800 ft south of the Pro-Ag Marketing Facility, at levels below the maximum contaminant level of 5.0 μg/L. In 1986, in response to an increase in carbon tetrachloride to 12 μg/L in well PWS-3, the city was required to remove both PWS-3 and PWS-4 from service. The Agra public water supply system is served by three other wells (PWS-1, PWS-2, and PWS-5) that are outside the area of contamination. In 2005, the Environmental Science Division of Argonne National Laboratory conducted a comprehensive investigation of potential contaminant source areas at Agra, on behalf of the CCC/USDA. Data collected during the 2005 investigation identified three primary source areas for the carbon tetrachloride contamination (Argonne 2006). One source is located on the former CCC/USDA property, and the other two sources are on property owned by Pro-Ag Marketing. In 2008-2009, to address the carbon tetrachloride contamination detected on its former property, the CCC/USDA initiated source area cleanup as an interim measure (IM) in accord with the document Interim Measure Work Plan/Design for Agra, Kansas (IMWP/D; Argonne 2008). The cleanup employs five large-diameter boreholes (LDBs) that were excavated by auger drilling. The purposes of these borings were to (1) physically remove soils impacted by carbon tetrachloride from the most contaminated area for treatment by onsite land farming and (2) provide locations for the installation of coupled soil vapor extraction (SVE) and air sparging (AS) wells to facilitate in situ treatment of the remaining carbon tetrachloride in the soils and groundwater. Construction data for the SVE wells, the AS wells, and groundwater and soil gas observation points installed to monitor the progress of the cleanup (as reported on the Kansas Review of Time-Series Data for the Agra Interim Measure 1-2 Version 01, 10/24/13 WWC-5 forms for these installations) are summarized in Table 1.1. The locations of the wells are shown in Figure 1.1. The IMWP/D was approved by the Kansas Department of Health and Environment in November 2008 (KDHE 2008), and operation of the SVE/AS systems began in May 2009. With the approval of the KDHE (2009), landfarming operations to treat the contaminated soils excavated from the LDBs were completed on October 12, 2010. Since start-up, the IM activities have been documented periodically (Argonne 2009a,b,c; Argonne 2010a,b,c,d, 2011a,b,c, 2012, 2013a,b), in accord with the requirements of the KDHEapproved IMWP/D (Argonne 2008). Each of the reports primarily summarizes the operations and maintenance of the SVE and AS equipment and the results of sampling of the groundwater, soil gas, and system effluents for analyses for volatile organic compounds (VOCs) over a specific 3- to 6-month period. Hence, the focus is the incremental performance of the IM. To complement these documents, this report provides a broader perspective by examining the collective data acquired since start-up on May 29, 2009, and through June 2013. The objectives of this approach are to evaluate possible longer-term trends in (1) the operational characteristics of the remedial systems and (2) the corresponding responses in the subsurface environment and their potential relationships to the progress of the cleanup. To facilitate this investigation, time-series diagrams have been developed to illustrate key parameter data for the SVE and AS systems, as well as sampling and additional supporting data obtained from the monitoring program. An overview of the information compiled is in Section 2. In Section 3, observations drawn from these data are discussed. The principal findings of the evaluation and recommendations for consideration are summarized in Sections 4 and 5, respectively.
- Research Organization:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC02-06CH11357
- OSTI ID:
- 1490809
- Report Number(s):
- ANL/EVS/AGEM/CHRON-1821; 148465
- Country of Publication:
- United States
- Language:
- English
Similar Records
Results of Temporary Shutdown Testing and Groundwater Pump-Testing at Agra, Kansas, February-September 2016 and march 2017, and Assessment of Groundwater and Contaminant Migration
Interim measure work plan/design for Agra, Kansas.