Compositional and orientational control in metal halide perovskites of reduced dimensionality

Quintero-Bermudez, Rafael; Gold-Parker, Aryeh; Proppe, Andrew H.; Munir, Rahim; Yang, Zhenyu; Kelley, Shana O.; Amassian, Aram; Toney, Michael F.; Sargent, Edward H.

doi:10.1038/s41563-018-0154-x

Compositional and orientational control in metal halide perovskites of reduced dimensionality

Journal Article · Mon Sep 10 00:00:00 EDT 2018 · Nature Materials

DOI:https://doi.org/10.1038/s41563-018-0154-x· OSTI ID:1490652

Quintero-Bermudez, Rafael ^[1]; ^[2]; ^[1]; Munir, Rahim ^[3]; ^[1]; ^[1]; Amassian, Aram ^[3]; ^[4]; ^[1]

Univ. of Toronto, Toronto, ON (Canada)
SLAC National Accelerator Lab., Menlo Park, CA (United States); Stanford Univ., Stanford, CA (United States)
King Abdullah Univ. of Science and Technology (KAUST), Thuwal (Saudi Arabia)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

Reduced-dimensional metal halide perovskites (RDPs) have attracted significant attention in recent years due to their promising light harvesting and emissive properties. We sought to increase the systematic understanding of how RDPs are formed. Here we report that layered intermediate complexes formed with the solvent provide a scaffold that facilitates the nucleation and growth of RDPs during annealing, as observed via in situ X-ray scattering. Transient absorption spectroscopy of RDP single crystals and films enables the identification of the distribution of quantum well thicknesses. These insights allow us to develop a kinetic model of RDP formation that accounts for the experimentally observed size distribution of wells. RDPs exhibit a thickness distribution (with sizes that extend above n = 5) determined largely by the stoichiometric proportion between the intercalating cation and solvent complexes. Here, the results indicate a means to control the distribution, composition and orientation of RDPs via the selection of the intercalating cation, the solvent and the deposition technique.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1490652

Alternate ID(s):: OSTI ID: 1603145

Journal Information:: Nature Materials, Journal Name: Nature Materials Journal Issue: 10 Vol. 17; ISSN 1476-1122

Publisher:: Springer Nature - Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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