Effects of nano-confinement on Zn(II) adsorption to nanoporous silica

Nelson, Joey; Bargar, John R.; Wasylenki, Laura; Brown, Jr., Gordon E.; Maher, Kate

doi:10.1016/j.gca.2018.08.017

Effects of nano-confinement on Zn(II) adsorption to nanoporous silica

Journal Article · Wed Aug 22 00:00:00 EDT 2018 · Geochimica et Cosmochimica Acta

DOI:https://doi.org/10.1016/j.gca.2018.08.017· OSTI ID:1490626

Nelson, Joey ^[1]; Bargar, John R. ^[2]; Wasylenki, Laura ^[3]; Brown, Jr., Gordon E. ^[4]; Maher, Kate ^[1]

Stanford Univ., Stanford, CA (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Indiana Univ., Bloomington, IN (United States); Northern Arizona Univ., Flagstaff, AZ (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Here, nanopores (at least one dimension ≤100 nm and no dimension <1 nm) are commonly observed features of grain coatings and primary silicate minerals and can contribute substantially to the total surface area available for chemical reactions. Despite the ubiquity of nanopores in natural and synthetic porous media, a generalizable framework for evaluating the effects of nanopore confinement on both fluid and sorbate properties across the entire nanoscale has yet to emerge. As a result, we have a poor understanding of the effect of pore size on molecular-scale processes controlling nano-confinement phenomena in systems in which mineral surfaces are in contact with aqueous solutions.

View Accepted Manuscript (DOE)

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1490626

Alternate ID(s):: OSTI ID: 1702349

Journal Information:: Geochimica et Cosmochimica Acta, Journal Name: Geochimica et Cosmochimica Acta Journal Issue: C Vol. 240; ISSN 0016-7037

Publisher:: The Geochemical Society; The Meteoritical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (106)

Precipitation of Calcium Carbonate in Confinement Loste, E.; Park, R. J.; Warren, J. Advanced Functional Materials, Vol. 14, Issue 12 https://doi.org/10.1002/adfm.200400268	journal	December 2004
Mesoporous Silica Nanoparticles: Synthesis, Biocompatibility and Drug Delivery Tang, Fangqiong; Li, Linlin; Chen, Dong Advanced Materials, Vol. 24, Issue 12 https://doi.org/10.1002/adma.201104763	journal	February 2012
Gas Storage in Nanoporous Materials Morris, Russell E.; Wheatley, Paul S. Angewandte Chemie International Edition, Vol. 47, Issue 27 https://doi.org/10.1002/anie.200703934	journal	June 2008
Avoiding Interferences from Good's Buffers: A Contiguous Series of Noncomplexing Tertiary Amine Buffers Covering the Entire Range of pH 3–11 Yu, Qiuyue; Kandegedara, Ashoka; Xu, Yanping Analytical Biochemistry, Vol. 253, Issue 1 https://doi.org/10.1006/abio.1997.2349	journal	November 1997
Specific Adsorption of Nickel and ζ Potential of Silica at Various Solid-to-Liquid Ratios Kosmulski, Marek; Eriksson, Patrik; Gustafsson, Jan Journal of Colloid and Interface Science, Vol. 220, Issue 1 https://doi.org/10.1006/jcis.1999.6520	journal	December 1999
Adsorption and Precipitation of Aqueous Zn(II) on Alumina Powders Trainor, Thomas P.; Brown, Gordon E.; Parks, George A. Journal of Colloid and Interface Science, Vol. 231, Issue 2 https://doi.org/10.1006/jcis.2000.7111	journal	November 2000
Mercury Porosimetry: Contact Angle Hysteresis of Materials with Controlled Pore Structure Salmas, Constantinos; Androutsopoulos, George Journal of Colloid and Interface Science, Vol. 239, Issue 1 https://doi.org/10.1006/jcis.2001.7531	journal	July 2001
Grazing-Incidence XAFS Study of Aqueous Zn(II) Sorption on α-Al2O3 Single Crystals Trainor, Thomas P.; Fitts, Jeffrey P.; Templeton, Alexis S. Journal of Colloid and Interface Science, Vol. 244, Issue 2 https://doi.org/10.1006/jcis.2001.7951	journal	December 2001
The Influence of Mercury Contact Angle, Surface Tension, and Retraction Mechanism on the Interpretation of Mercury Porosimetry Data Rigby, Sean P.; Edler, Karen J. Journal of Colloid and Interface Science, Vol. 250, Issue 1 https://doi.org/10.1006/jcis.2002.8286	journal	June 2002
Interface Chemistry of Nanostructured Materials: Ion Adsorption on Mesoporous Alumina Wang, Yifeng; Bryan, Charles; Xu, Huifang Journal of Colloid and Interface Science, Vol. 254, Issue 1 https://doi.org/10.1006/jcis.2002.8571	journal	October 2002
Changes in density and surface tension of water in silica pores Takei, T.; Mukasa, K.; Kofuji, M. Colloid & Polymer Science, Vol. 278, Issue 5 https://doi.org/10.1007/s003960050542	journal	May 2000
Reactive transport codes for subsurface environmental simulation Steefel, C. I.; Appelo, C. A. J.; Arora, B. Computational Geosciences, Vol. 19, Issue 3 https://doi.org/10.1007/s10596-014-9443-x	journal	September 2014
Free metal ion depletion by “Good's” buffers Nakon, Robert Analytical Biochemistry, Vol. 95, Issue 2 https://doi.org/10.1016/0003-2697(79)90767-X	journal	June 1979
Free metal ion depletion by “good's” buffers Pope, John M.; Stevens, Philip R.; Angotti, Michael T. Analytical Biochemistry, Vol. 103, Issue 1 https://doi.org/10.1016/0003-2697(80)90258-4	journal	March 1980
Free metal ion depletion by “good's” buffers Lance, Edward A.; Rhodes, Charles W.; Nakon, Robert Analytical Biochemistry, Vol. 133, Issue 2 https://doi.org/10.1016/0003-2697(83)90115-X	journal	September 1983
Radicals from “Good's” buffers Grady, John K.; Chasteen, N. Dennis; Harris, Daniel C. Analytical Biochemistry, Vol. 173, Issue 1 https://doi.org/10.1016/0003-2697(88)90167-4	journal	August 1988
Relationships between mineral surfaces and organic carbon concentrations in soils and sediments Mayer, Lawrence M. Chemical Geology, Vol. 114, Issue 3-4 https://doi.org/10.1016/0009-2541(94)90063-9	journal	June 1994
Adsorption of Fe(III), Co(II) and Zn(II) onto particulates in fresh waters on the basis of the surface complexation model I. Stabilities of metal species adsorbed on particulates Osaki, Susumu; Miyoshi, Tomoko; Sugihara, Shinji Science of The Total Environment, Vol. 99, Issue 1-2 https://doi.org/10.1016/0048-9697(90)90215-G	journal	December 1990
Surface areas and porosities of particulate matter in turbid estuaries Titley, J. G.; Glegg, G. A.; Glasson, D. R. Continental Shelf Research, Vol. 7, Issue 11-12 https://doi.org/10.1016/0278-4343(87)90041-0	journal	November 1987
New perspectives in mercury porosimetry León y. León, Carlos A. Advances in Colloid and Interface Science, Vol. 76-77 https://doi.org/10.1016/S0001-8686(98)00052-9	journal	July 1998
Electrochemical investigations of the effect of N-substituted aminosulfonic acids with a piperazinic ring pH buffers on heavy metal processes which may have implications on speciation studies Soares, Helena M. V. M.; Conde, Paula C. F. L. Analytica Chimica Acta, Vol. 421, Issue 1 https://doi.org/10.1016/S0003-2670(00)01028-X	journal	September 2000
Nanoscience and technology: the next revolution in the Earth sciences Hochella, Michael F. Earth and Planetary Science Letters, Vol. 203, Issue 2 https://doi.org/10.1016/S0012-821X(02)00818-X	journal	October 2002
Surface complexation and precipitate geometry for aqueous Zn(II) sorption on ferrihydrite I: X-ray absorption extended fine structure spectroscopy analysis Waychunas, G. A.; Fuller, C. C.; Davis, J. A. Geochimica et Cosmochimica Acta, Vol. 66, Issue 7 https://doi.org/10.1016/S0016-7037(01)00853-5	journal	April 2002
There’s plenty of room at the bottom: nanoscience in geochemistry Hochella, Michael F. Geochimica et Cosmochimica Acta, Vol. 66, Issue 5 https://doi.org/10.1016/S0016-7037(01)00868-7	journal	March 2002
Structure of heavy metal sorbed birnessite. Part III: Results from powder and polarized extended X-ray absorption fine structure spectroscopy Manceau, Alain; Lanson, Bruno; Drits, Victor A. Geochimica et Cosmochimica Acta, Vol. 66, Issue 15 https://doi.org/10.1016/S0016-7037(02)00869-4	journal	August 2002
X-ray absorption spectroscopy study of Cu2+ and Zn2+ adsorption complexes at the calcite surface Elzinga, E. J.; Reeder, R. J. Geochimica et Cosmochimica Acta, Vol. 66, Issue 22 https://doi.org/10.1016/S0016-7037(02)00971-7	journal	November 2002
Surface complexation of arsenic(V) to iron(III) (hydr)oxides: structural mechanism from ab initio molecular geometries and EXAFS spectroscopy Sherman, David M.; Randall, Simon R. Geochimica et Cosmochimica Acta, Vol. 67, Issue 22 https://doi.org/10.1016/S0016-7037(03)00237-0	journal	November 2003
Controlled-pore glass as a stationary phase in chromatography Schnabel, R.; Langer, P. Journal of Chromatography A, Vol. 544 https://doi.org/10.1016/S0021-9673(01)83983-2	journal	May 1991
Kinetics and mechanisms of Zn complexation on metal oxides using EXAFS spectroscopy Roberts, Darryl R.; Ford, Robert G.; Sparks, Donald L. Journal of Colloid and Interface Science, Vol. 263, Issue 2 https://doi.org/10.1016/S0021-9797(03)00281-9	journal	July 2003
The surface chemistry of amorphous silica. Zhuravlev model Zhuravlev, L. T. Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 173, Issue 1-3 https://doi.org/10.1016/S0927-7757(00)00556-2	journal	November 2000
Characterisation of porous solids using integrated nitrogen sorption and mercury porosimetry P. Rigby, Sean; S. Fletcher, Robin; N. Riley, Sandra Chemical Engineering Science, Vol. 59, Issue 1 https://doi.org/10.1016/j.ces.2003.09.017	journal	January 2004
CO2 percolation experiment through chlorite/zeolite-rich sandstone (Pretty Hill Formation – Otway Basin–Australia) Luquot, Linda; Andreani, Muriel; Gouze, Philippe Chemical Geology, Vol. 294-295 https://doi.org/10.1016/j.chemgeo.2011.11.018	journal	February 2012
Nanogeochemistry: Nanostructures, emergent properties and their control on geochemical reactions and mass transfers Wang, Yifeng Chemical Geology, Vol. 378-379 https://doi.org/10.1016/j.chemgeo.2014.04.007	journal	June 2014
U(VI) and Sr(II) batch sorption and diffusion kinetics into mesoporous silica (MCM-41) Singer, David M.; Guo, Hua; Davis, James A. Chemical Geology, Vol. 390 https://doi.org/10.1016/j.chemgeo.2014.10.027	journal	December 2014
A review of the coordination chemistry of hydrothermal systems, or do coordination changes make ore deposits? Brugger, Joël; Liu, Weihua; Etschmann, Barbara Chemical Geology, Vol. 447 https://doi.org/10.1016/j.chemgeo.2016.10.021	journal	December 2016
Post-combustion CO2 capture with chemical absorption: A state-of-the-art review Wang, M.; Lawal, A.; Stephenson, P. Chemical Engineering Research and Design, Vol. 89, Issue 9 https://doi.org/10.1016/j.cherd.2010.11.005	journal	September 2011
Zinc sorption to biogenic hexagonal-birnessite particles within a hydrated bacterial biofilm Toner, Brandy; Manceau, Alain; Webb, Samuel M. Geochimica et Cosmochimica Acta, Vol. 70, Issue 1 https://doi.org/10.1016/j.gca.2005.08.029	journal	January 2006
Zn isotopic fractionation caused by sorption on goethite and 2-Lines ferrihydrite Juillot, F.; Maréchal, C.; Ponthieu, M. Geochimica et Cosmochimica Acta, Vol. 72, Issue 19 https://doi.org/10.1016/j.gca.2008.07.007	journal	October 2008
The non-oxidative dissolution of galena nanocrystals: Insights into mineral dissolution rates as a function of grain size, shape, and aggregation state Liu, Juan; Aruguete, Deborah M.; Jinschek, Joerg R. Geochimica et Cosmochimica Acta, Vol. 72, Issue 24 https://doi.org/10.1016/j.gca.2008.10.010	journal	December 2008
Zinc surface complexes on birnessite: A density functional theory study Kwon, Kideok D.; Refson, Keith; Sposito, Garrison Geochimica et Cosmochimica Acta, Vol. 73, Issue 5 https://doi.org/10.1016/j.gca.2008.11.033	journal	March 2009
Uranyl–chlorite sorption/desorption: Evaluation of different U(VI) sequestration processes Singer, David M.; Maher, Kate; Brown, Gordon E. Geochimica et Cosmochimica Acta, Vol. 73, Issue 20 https://doi.org/10.1016/j.gca.2009.07.002	journal	October 2009
Mechanisms of nickel sorption by a bacteriogenic birnessite Peña, Jasquelin; Kwon, Kideok D.; Refson, Keith Geochimica et Cosmochimica Acta, Vol. 74, Issue 11 https://doi.org/10.1016/j.gca.2010.02.035	journal	June 2010
Interfacial energy effects and the evolution of pore size distributions during quartz precipitation in sandstone Emmanuel, Simon; Ague, Jay J.; Walderhaug, Olav Geochimica et Cosmochimica Acta, Vol. 74, Issue 12 https://doi.org/10.1016/j.gca.2010.03.019	journal	June 2010
Diagenetic changes in macro- to nano-scale porosity in the St. Peter Sandstone: An (ultra) small angle neutron scattering and backscattered electron imaging analysis Anovitz, L. M.; Cole, D. R.; Rother, G. Geochimica et Cosmochimica Acta, Vol. 102 https://doi.org/10.1016/j.gca.2012.07.035	journal	February 2013
Small molecule – Silica interactions in porous silica structures Wu, Di; Navrotsky, Alexandra Geochimica et Cosmochimica Acta, Vol. 109 https://doi.org/10.1016/j.gca.2013.01.038	journal	May 2013
Multi-scale characterization of pore evolution in a combustion metamorphic complex, Hatrurim basin, Israel: Combining (ultra) small-angle neutron scattering and image analysis Wang, Hsiu-Wen; Anovitz, Lawrence M.; Burg, Avihu Geochimica et Cosmochimica Acta, Vol. 121 https://doi.org/10.1016/j.gca.2013.07.034	journal	November 2013
Zinc isotope fractionation during adsorption onto Mn oxyhydroxide at low and high ionic strength Bryan, Allison L.; Dong, Shuofei; Wilkes, Elise B. Geochimica et Cosmochimica Acta, Vol. 157 https://doi.org/10.1016/j.gca.2015.01.026	journal	May 2015
Probing the sorption reactivity of the edge surfaces in birnessite nanoparticles using nickel(II) Simanova, Anna A.; Kwon, Kideok D.; Bone, Sharon E. Geochimica et Cosmochimica Acta, Vol. 164 https://doi.org/10.1016/j.gca.2015.04.050	journal	September 2015
A spatially resolved surface kinetic model for forsterite dissolution Maher, Kate; Johnson, Natalie C.; Jackson, Ariel Geochimica et Cosmochimica Acta, Vol. 174 https://doi.org/10.1016/j.gca.2015.11.019	journal	February 2016
Effects of surface structural disorder and surface coverage on isotopic fractionation during Zn(II) adsorption onto quartz and amorphous silica surfaces Nelson, Joey; Wasylenki, Laura; Bargar, John R. Geochimica et Cosmochimica Acta, Vol. 215 https://doi.org/10.1016/j.gca.2017.08.003	journal	October 2017
Effect of iron oxide coatings on zinc sorption mechanisms at the clay-mineral/water interface Nachtegaal, Maarten; Sparks, Donald L. Journal of Colloid and Interface Science, Vol. 276, Issue 1 https://doi.org/10.1016/j.jcis.2004.03.031	journal	August 2004
In situ small-angle neutron scattering study of nitrogen adsorption and condensation in mesoporous silica glass CPG-10-75 Hoinkis, E.; Röhl-Kuhn, B. Journal of Colloid and Interface Science, Vol. 296, Issue 1 https://doi.org/10.1016/j.jcis.2005.08.044	journal	April 2006
Electrokinetics in nanochannels Baldessari, Fabio Journal of Colloid and Interface Science, Vol. 325, Issue 2 https://doi.org/10.1016/j.jcis.2008.06.007	journal	September 2008
Cu(II) complexation by “non-coordinating” N-2-hydroxyethylpiperazine-N′-2-ethanesulfonic acid (HEPES buffer)☆ Sokołowska, Magdalena; Bal, Wojciech Journal of Inorganic Biochemistry, Vol. 99, Issue 8 https://doi.org/10.1016/j.jinorgbio.2005.05.007	journal	August 2005
Comparison of U(VI) removal from contaminated groundwater by nanoporous alumina and non-nanoporous alumina Sun, Yubing; Yang, Shitong; Sheng, Guodong Separation and Purification Technology, Vol. 83 https://doi.org/10.1016/j.seppur.2011.09.050	journal	November 2011
Synthesis, characterization and adsorption studies of several heavy metal ions on amino-functionalized silica nano hollow sphere and silica gel Najafi, M.; Yousefi, Y.; Rafati, A. A. Separation and Purification Technology, Vol. 85 https://doi.org/10.1016/j.seppur.2011.10.011	journal	February 2012
Internal Domains of Natural Porous Media Revealed: Critical Locations for Transport, Storage, and Chemical Reaction Zachara, John; Brantley, Sue; Chorover, Jon Environmental Science & Technology, Vol. 50, Issue 6 https://doi.org/10.1021/acs.est.5b05015	journal	February 2016
Zn Isotope Fractionation during Sorption onto Kaolinite Guinoiseau, Damien; Gélabert, Alexandre; Moureau, Julien Environmental Science & Technology, Vol. 50, Issue 4 https://doi.org/10.1021/acs.est.5b05347	journal	January 2016
Effects of Confinement on the Dielectric Response of Water Extends up to Mesoscale Dimensions De Luca, Sergio; Kannam, Sridhar Kumar; Todd, B. D. Langmuir, Vol. 32, Issue 19 https://doi.org/10.1021/acs.langmuir.6b00791	journal	May 2016
Hydrogen Ion Buffers for Biological Research ^* Good, Norman E.; Winget, G. Douglas; Winter, Wilhelmina Biochemistry, Vol. 5, Issue 2 https://doi.org/10.1021/bi00866a011	journal	February 1966
Nanoporous Structure and Medium-Range Order in Synthetic Amorphous Calcium Carbonate Goodwin, Andrew L.; Michel, F. Marc; Phillips, Brian L. Chemistry of Materials, Vol. 22, Issue 10 https://doi.org/10.1021/cm100294d	journal	May 2010
Modeling the Mass-Action Expression for Bidentate Adsorption Benjamin, Mark M. Environmental Science & Technology, Vol. 36, Issue 3 https://doi.org/10.1021/es010936n	journal	February 2002
EXAFS Study of Zn Sorption Mechanisms on Montmorillonite Lee, Shinwoo; Anderson, Paul R.; Bunker, Grant B. Environmental Science & Technology, Vol. 38, Issue 20 https://doi.org/10.1021/es0350076	journal	October 2004
Effects of Zwitterionic Buffers on Sorption of Ferrous Iron at Goethite and Its Oxidation by CCl ₄ Buchholz, Anke; Laskov, Christine; Haderlein, Stefan B. Environmental Science & Technology, Vol. 45, Issue 8 https://doi.org/10.1021/es103172c	journal	April 2011
An Investigation of Strong Sodium Retention Mechanisms in Nanopore Environments Using Nuclear Magnetic Resonance Spectroscopy Ferreira, Daniel R.; Schulthess, Cristian P.; Giotto, Marcus V. Environmental Science & Technology, Vol. 46, Issue 1 https://doi.org/10.1021/es2033394	journal	November 2011
Collection of Lanthanides and Actinides from Natural Waters with Conventional and Nanoporous Sorbents Johnson, Bryce E.; Santschi, Peter H.; Chuang, Chia-Ying Environmental Science & Technology, Vol. 46, Issue 20 https://doi.org/10.1021/es204192r	journal	October 2012
Redox Behavior of Uranium at the Nanoporous Aluminum Oxide-Water Interface: Implications for Uranium Remediation Jung, Hun Bok; Boyanov, Maxim I.; Konishi, Hiromi Environmental Science & Technology, Vol. 46, Issue 13 https://doi.org/10.1021/es2044163	journal	June 2012
Tracing Bioavailability of ZnO Nanoparticles Using Stable Isotope Labeling Larner, Fiona; Dogra, Yuktee; Dybowska, Agnieszka Environmental Science & Technology, Vol. 46, Issue 21 https://doi.org/10.1021/es302602j	journal	October 2012
Pore-Size-Dependent Calcium Carbonate Precipitation Controlled by Surface Chemistry Stack, Andrew G.; Fernandez-Martinez, Alejandro; Allard, Lawrence F. Environmental Science & Technology, Vol. 48, Issue 11 https://doi.org/10.1021/es405574a	journal	May 2014
Application of the Surface Complexation Concept to Complex Mineral Assemblages Davis, J. A.; Coston, J. A.; Kent, D. B. Environmental Science & Technology, Vol. 32, Issue 19 https://doi.org/10.1021/es980312q	journal	October 1998
Interaction of copper(II) with N-(2-hydroxyethyl)piperazine-N'-ethanesulfonic acid (HEPES) Hegetschweiler, Kaspar; Saltman, Paul Inorganic Chemistry, Vol. 25, Issue 1 https://doi.org/10.1021/ic00221a028	journal	January 1986
EXAFS Investigations of Zn(II) in Concentrated Aqueous Hydroxide Solutions Pandya, Kaumudi I.; Russell, Andrea E.; McBreen, J. The Journal of Physical Chemistry, Vol. 99, Issue 31 https://doi.org/10.1021/j100031a026	journal	August 1995
Role of Biologically Important Zwitterionic Buffer Secondary Ligands on the Stability of the Mixed-Ligand Complexes of Divalent Metal Ions and Adenosine 5‘-Mono-, 5‘-Di-, and 5‘-Triphosphate Azab, Hassan A.; Orabi, Adel S.; El-Salam, Enas T. Abd. Journal of Chemical & Engineering Data, Vol. 46, Issue 2 https://doi.org/10.1021/je0001779	journal	March 2001
Dielectric Constant of Water Confined in a Nanocavity Senapati, Sanjib; Chandra, Amalendu The Journal of Physical Chemistry B, Vol. 105, Issue 22 https://doi.org/10.1021/jp011058i	journal	June 2001
Effect of Nanoscale Pore Space Confinement on Cadmium Adsorption from Aqueous Solution onto Ordered Mesoporous Silica: A Combined Adsorption and Flow Calorimetry Study Prelot, Benedicte; Lantenois, Sebastien; Chorro, Claude The Journal of Physical Chemistry C, Vol. 115, Issue 40 https://doi.org/10.1021/jp2015885	journal	September 2011
Molecular Dynamics Simulations of Water Structure and Diffusion in Silica Nanopores Bourg, Ian C.; Steefel, Carl I. The Journal of Physical Chemistry C, Vol. 116, Issue 21 https://doi.org/10.1021/jp301299a	journal	May 2012
Size-Dependent Surface Charging of Nanoparticles Abbas, Zareen; Labbez, Christophe; Nordholm, Sture The Journal of Physical Chemistry C, Vol. 112, Issue 15 https://doi.org/10.1021/jp709667u	journal	April 2008
On the Effect of Nanoparticle Size on Water-Oxide Interfacial Chemistry Vayssieres, Lionel The Journal of Physical Chemistry C, Vol. 113, Issue 12 https://doi.org/10.1021/jp810721f	journal	March 2009
Strongly Anisotropic Dielectric Relaxation of Water at the Nanoscale Zhang, Cui; Gygi, François; Galli, Giulia The Journal of Physical Chemistry Letters, Vol. 4, Issue 15 https://doi.org/10.1021/jz401108n	journal	July 2013
Nanoporous Membranes Derived from Block Copolymers: From Drug Delivery to Water Filtration Jackson, Elizabeth A.; Hillmyer, Marc A. ACS Nano, Vol. 4, Issue 7 https://doi.org/10.1021/nn1014006	journal	June 2010
Physical surface-complexation models for sorption at the mineral–water interface Sverjensky, Dimitri A. Nature, Vol. 364, Issue 6440 https://doi.org/10.1038/364776a0	journal	August 1993
Structure and stability of the (001) α-quartz surface Goumans, T. P. M.; Wander, Adrian; Brown, Wendy A. Phys. Chem. Chem. Phys., Vol. 9, Issue 17 https://doi.org/10.1039/B701176H	journal	January 2007
High efficiency nanocomposite sorbents for CO2 capture based on amine-functionalized mesoporous capsules Qi, Genggeng; Wang, Yanbing; Estevez, Luis Energy Environ. Sci., Vol. 4, Issue 2 https://doi.org/10.1039/C0EE00213E	journal	January 2011
Heavy metal complexation on hybrid mesoporous silicas: an approach to analytical applications Sierra, Isabel; Pérez-Quintanilla, Damián Chem. Soc. Rev., Vol. 42, Issue 9 https://doi.org/10.1039/C2CS35221D	journal	January 2013
Size-effects in the dissolution of hydroxyapatite: an understanding of biological demineralization Tang, Ruikang; Wang, Lijun; Nancollas, George H. Journal of Materials Chemistry, Vol. 14, Issue 14 https://doi.org/10.1039/b401097c	journal	January 2004
A trapped water network in nanoporous material: the role of interfaces Le Caër, S.; Pin, S.; Esnouf, S. Physical Chemistry Chemical Physics, Vol. 13, Issue 39 https://doi.org/10.1039/c1cp21980d	journal	January 2011
Effects of nanoscale pores in soils on carbon evolution under extremely dry conditions Suetsugu, Atsushi; Imoto, Hiromi; Mizoguchi, Masaru Soil Science and Plant Nutrition, Vol. 50, Issue 6 https://doi.org/10.1080/00380768.2004.10408551	journal	February 2004
Free Metal Ion Depletion by Good's Buffers. IV. Bicine 1:1 and 2:1 Complexes with Mg(II), Ca(II), Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) Krishnamoorthy, C. R.; Nakon, R. Journal of Coordination Chemistry, Vol. 23, Issue 1-4 https://doi.org/10.1080/00958979109408254	journal	June 1991
Modelling the effect of particle shape on the phase stability of ZrO ₂ nanoparticles Barnard, Amanda S.; Yeredla, Rakesh R.; Xu, Huifang Nanotechnology, Vol. 17, Issue 12 https://doi.org/10.1088/0957-4484/17/12/038	journal	June 2006
Surface-Charge-Governed Ion Transport in Nanofluidic Channels Stein, Derek; Kruithof, Maarten; Dekker, Cees Physical Review Letters, Vol. 93, Issue 3 https://doi.org/10.1103/PhysRevLett.93.035901	journal	July 2004
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/S0909049500016964	journal	March 2001
Characterizing heavy-metal adsorption on oxides and oxyhydroxides Spark, K. M.; Johnson, B. B.; Wells, J. D. European Journal of Soil Science, Vol. 46, Issue 4 https://doi.org/10.1111/j.1365-2389.1995.tb01358.x	journal	December 1995
Nanominerals, Mineral Nanoparticles, and Earth Systems Hochella, M. F.; Lower, S. K.; Maurice, P. A. Science, Vol. 319, Issue 5870 https://doi.org/10.1126/science.1141134	journal	March 2008
Size-Driven Structural and Thermodynamic Complexity in Iron Oxides Navrotsky, A.; Mazeina, L.; Majzlan, J. Science, Vol. 319, Issue 5870 https://doi.org/10.1126/science.1148614	journal	March 2008
Free-metal ion depletion by "Good's" buffers Nakon, R.; Krishnamoorthy, C. Science, Vol. 221, Issue 4612 https://doi.org/10.1126/science.6879173	journal	August 1983
Nanogeochemistry: Geochemical reactions and mass transfers in nanopores Wang, Yifeng; Bryan, Charles; Xu, Huifang Geology, Vol. 31, Issue 5 https://doi.org/10.1130/0091-7613(2003)031<0387:NGRAMT>2.0.CO;2	journal	January 2003
Thermal behavior of metal nanoparticles in geologic materials Reich, Martin; Utsunomiya, Satoshi; Kesler, Stephen E. Geology, Vol. 34, Issue 12 https://doi.org/10.1130/G22829A.1	journal	January 2006
SIXPack a Graphical User Interface for XAS Analysis Using IFEFFIT Webb, S. M. Physica Scripta https://doi.org/10.1238/Physica.Topical.115a01011	journal	January 2005
Metastable nanosized diamond formation from a C-H-O fluid system Simakov, S. K. Journal of Materials Research, Vol. 25, Issue 12 https://doi.org/10.1557/jmr.2010.0303	journal	December 2010
The Nanopore Inner Sphere Enhancement Effect on Cation Adsorption: Sodium and Nickel Schulthess, C. P.; Taylor, R. W.; Ferreira, D. R. Soil Science Society of America Journal, Vol. 75, Issue 2 https://doi.org/10.2136/sssaj2010.0129nps	journal	January 2011
Surface area and porosity of primary silicate minerals Brantley, Susan L.; Mellott, Nathan P. American Mineralogist, Vol. 85, Issue 11-12 https://doi.org/10.2138/am-2000-11-1220	journal	November 2000
Continuous Cauchy wavelet transform analyses of EXAFS spectra: A qualitative approach Muñoz, Manuel; Argoul, Pierre; Farges, François American Mineralogist, Vol. 88, Issue 4 https://doi.org/10.2138/am-2003-0423	journal	April 2003
Nanopores in hematite ( -Fe2O3) nanocrystals observed by electron tomography Echigo, T.; Monsegue, N.; Aruguete, D. M. American Mineralogist, Vol. 98, Issue 1 https://doi.org/10.2138/am.2013.4120	journal	December 2012
Nanoparticles in the Environment Banfield, J. F.; Zhang, H. Reviews in Mineralogy and Geochemistry, Vol. 44, Issue 1 https://doi.org/10.2138/rmg.2001.44.01	journal	January 2001
Thermochemistry of Nanomaterials Navrotsky, A. Reviews in Mineralogy and Geochemistry, Vol. 44, Issue 1 https://doi.org/10.2138/rmg.2001.44.03	journal	January 2001
Geochemistry of laterites, stability of Al-goethite, Al-hematite, and Fe (super 3+) -kaolinite in bauxites and ferricretes; an approach to the mechanism of concretion formation Tardy, Y.; Nahon, D. American Journal of Science, Vol. 285, Issue 10 https://doi.org/10.2475/ajs.285.10.865	journal	December 1985

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Interfacial reactions of Cu( ii ) adsorption and hydrolysis driven by nano-scale confinement Knight, Andrew W.; Ilani-Kashkouli, Poorandokht; Harvey, Jacob A. Environmental Science: Nano, Vol. 7, Issue 1 https://doi.org/10.1039/c9en00855a	journal	January 2020

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