Neutron Scattering Investigations of Hydride Species in Heterogeneous Catalysis

Polo Garzon, Felipe; Luo, Si; Cheng, Yongqiang; Page, Katharine L.; Ramirez Cuesta, Anibal; Britt, Phillip F.; Wu, Zili

doi:10.1002/cssc.201801890

Title: Neutron Scattering Investigations of Hydride Species in Heterogeneous Catalysis

Journal Article · Mon Nov 05 00:00:00 EST 2018 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201801890· OSTI ID:1489564

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Abstract In heterogeneous catalysis, hydrides on the surface or in the bulk play a critical role as either active components or reaction intermediates in many hydrogen‐involving reactions, but characterization of the nature and structure of these hydride species remains challenging. Neutron scattering, which is extremely sensitive to light elements, such as hydrogen, has shown great potential in meeting this challenge. In this Minireview, recent advances in neutron studies of hydride species, mainly over the two most typical classes of catalysts—metals and oxides—are surveyed. Findings on catalysts outside these categories are raised if they are considered to be relevant for contextualization in the present Minireview. The adsorption, dissociation, spillover, and reactivity of hydrogen, especially hydride species over supported metal and oxide catalysts, have been successfully investigated, mostly by means of neutron vibrational spectroscopy. Insights from these neutron studies, which are otherwise not possible with other techniques, shed light on the interaction mechanism of hydrogen with solid surfaces and reaction mechanisms in which hydrogen is involved. Future research challenges on neutron scattering studies of hydrides, as well as catalysis in general, are also highlighted, and more operando‐type neutron studies need be conducted to advance the field.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1489564

Alternate ID(s):: OSTI ID: 1483335

Journal Information:: ChemSusChem, Vol. 12, Issue 1; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 24 works

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Combining X-ray Absorption and X-ray Diffraction Techniques for in Situ Studies of Chemical Transformations in Heterogeneous Catalysis: Advantages and Limitations

Journal Article · Fri Aug 05 00:00:00 EDT 2011 · The Journal of Physical Chemistry · OSTI ID:1489564

Frenkel, A I; Hanson, J; Wang, Q; +7 more

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
heterogeneous catalysis
hydrides
neutron scattering
supported catalysts
transition metals

Title: Neutron Scattering Investigations of Hydride Species in Heterogeneous Catalysis

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