An Interconnected Channel-Like Framework as Host for Lithium Metal Composite Anodes

Wang, Hansen; Lin, Dingchang; Xie, Jin; Liu, Yayuan; Chen, Hao; Li, Yanbin; Xu, Jinwei; Zhou, Guangmin; Zhang, Zewen; Pei, Allen; Zhu, Yangying; Liu, Kai; Wang, Kecheng; Cui, Yi

doi:10.1002/aenm.201802720

Title: An Interconnected Channel-Like Framework as Host for Lithium Metal Composite Anodes

Journal Article · Wed Jan 02 00:00:00 EST 2019 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201802720· OSTI ID:1506957

^[1]; Lin, Dingchang ^[1]; Xie, Jin ^[1]; Liu, Yayuan ^[1]; Chen, Hao ^[1]; Li, Yanbin ^[1]; Xu, Jinwei ^[1]; Zhou, Guangmin ^[1]; Zhang, Zewen ^[1]; Pei, Allen ^[1]; Zhu, Yangying ^[1]; Liu, Kai ^[1]; Wang, Kecheng ^[1];

^[2]

Stanford Univ., Stanford, CA (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Abstract Lithium (Li) metal anodes have long been counted on to meet the increasing demand for high energy, high‐power rechargeable battery systems but they have been plagued by uncontrollable plating, unstable solid electrolyte interphase (SEI) formation, and the resulting low Coulombic efficiency. These problems are even aggravated under commercial levels of current density and areal capacity testing conditions. In this work, the channel‐like structure of a carbonized eggplant (EP) as a stable “host” for Li metal melt infusion, is utilized. With further interphase modification of lithium fluoride (LiF), the as‐formed EP–LiF composite anode maintains ≈90% Li metal theoretical capacity and can successfully suppress dendrite growth and volume fluctuation during cycling. EP–LiF offers much improved symmetric cell and full‐cell cycling performance with lower and more stable overpotential under various areal capacity and elevated rate capability. Furthermore, carbonized EP serves as a light‐weight high‐performance current collector, achieving an average Coulombic efficiency ≈99.1% in ether‐based electrolytes with 2.2 mAh cm ⁻² cycling areal capacity. The natural structure of carbonized EP will inspire further artificial designs of electrode frameworks for both Li anode and sulfur cathodes, enabling promising candidates for next‐generation high‐energy density batteries.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1506957

Alternate ID(s):: OSTI ID: 1489295

Journal Information:: Advanced Energy Materials, Vol. 9, Issue 7; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 83 works

Citation information provided by
Web of Science

References (52)

Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries Fan, Xiulin; Chen, Long; Ji, Xiao Chem, Vol. 4, Issue 1 https://doi.org/10.1016/j.chempr.2017.10.017	journal	January 2018
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth Li, Weiyang; Yao, Hongbin; Yan, Kai Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8436	journal	June 2015
Crumpled Graphene Balls Stabilized Dendrite-free Lithium Metal Anodes Liu, Shan; Wang, Aoxuan; Li, Qianqian Joule, Vol. 2, Issue 1 https://doi.org/10.1016/j.joule.2017.11.004	journal	January 2018
Coralloid Carbon Fiber-Based Composite Lithium Anode for Robust Lithium Metal Batteries Zhang, Rui; Chen, Xiang; Shen, Xin Joule, Vol. 2, Issue 4 https://doi.org/10.1016/j.joule.2018.02.001	journal	April 2018
Eggplant-derived microporous carbon sheets: towards mass production of efficient bifunctional oxygen electrocatalysts at low cost for rechargeable Zn–air batteries Li, Bing; Geng, Dongsheng; Lee, Xinjing Shannon Chemical Communications, Vol. 51, Issue 42 https://doi.org/10.1039/C5CC01999K	journal	January 2015
Surface Condition Changes in Lithium Metal Deposited in Nonaqueous Electrolyte Containing HF by Dissolution-Deposition Cycles Shiraishi, Soshi Journal of The Electrochemical Society, Vol. 146, Issue 5 https://doi.org/10.1149/1.1391818	journal	January 1999
Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix Lin, Dingchang; Zhao, Jie; Sun, Jie Proceedings of the National Academy of Sciences, Vol. 114, Issue 18 https://doi.org/10.1073/pnas.1619489114	journal	April 2017
A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia Angewandte Chemie International Edition, Vol. 57, Issue 6 https://doi.org/10.1002/anie.201710806	journal	January 2018
Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode Liu, Yayuan; Lin, Dingchang; Liang, Zheng Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10992	journal	March 2016
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504526	journal	December 2015
A sheet-like porous carbon for high-rate supercapacitors produced by the carbonization of an eggplant Li, Zhengjie; Lv, Wei; Zhang, Chen Carbon, Vol. 92 https://doi.org/10.1016/j.carbon.2015.02.054	journal	October 2015
A reversible dendrite-free high-areal-capacity lithium metal electrode Wang, Hui; Matsui, Masaki; Kuwata, Hiroko Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15106	journal	April 2017
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Composite lithium metal anode by melt infusion of lithium into a 3D conducting scaffold with lithiophilic coating Liang, Zheng; Lin, Dingchang; Zhao, Jie Proceedings of the National Academy of Sciences, Vol. 113, Issue 11 https://doi.org/10.1073/pnas.1518188113	journal	February 2016
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b02166	journal	May 2015
Implantable Solid Electrolyte Interphase in Lithium-Metal Batteries Cheng, Xin-Bing; Yan, Chong; Chen, Xiang Chem, Vol. 2, Issue 2 https://doi.org/10.1016/j.chempr.2017.01.003	journal	February 2017
Lithium Fluoride Additives for Stable Cycling of Lithium Batteries at High Current Densities Choudhury, Snehashis; Archer, Lynden A. Advanced Electronic Materials, Vol. 2, Issue 2 https://doi.org/10.1002/aelm.201500246	journal	January 2016
All-solid-state high performance asymmetric supercapacitors based on novel MnS nanocrystal and activated carbon materials Chen, Teng; Tang, Yongfu; Qiao, Yuqing Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23289	journal	March 2016
Artificial Protection Film on Lithium Metal Anode toward Long-Cycle-Life Lithium-Oxygen Batteries Liu, Qing-Chao; Xu, Ji-Jing; Yuan, Shuang Advanced Materials, Vol. 27, Issue 35 https://doi.org/10.1002/adma.201501490	journal	August 2015
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries Fan, Xiulin; Chen, Long; Borodin, Oleg Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0183-2	journal	July 2018
Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes Zhang, Xue-Qiang; Chen, Xiang; Cheng, Xin-Bing Angewandte Chemie International Edition, Vol. 57, Issue 19 https://doi.org/10.1002/anie.201801513	journal	March 2018
Graphite-Encapsulated Li-Metal Hybrid Anodes for High-Capacity Li Batteries Sun, Yongming; Zheng, Guangyuan; Seh, Zhi Wei Chem, Vol. 1, Issue 2 https://doi.org/10.1016/j.chempr.2016.07.009	journal	August 2016
Moisture loss kinetics and microstructural changes in eggplant (Solanum melongena L.) during conventional and ultrasonically assisted convective drying Puig, A.; Perez-Munuera, I.; Carcel, J. A. Food and Bioproducts Processing, Vol. 90, Issue 4 https://doi.org/10.1016/j.fbp.2012.07.001	journal	October 2012
Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon Lin, Dingchang; Liu, Yayuan; Chen, Wei Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01020	journal	May 2017
The path towards sustainable energy Chu, Steven; Cui, Yi; Liu, Nian Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4834	journal	December 2016
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism Ding, Fei; Xu, Wu; Graff, Gordon L. Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456 https://doi.org/10.1021/ja312241y	journal	March 2013
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 3, Article No. 16010 https://doi.org/10.1038/nenergy.2016.10	journal	February 2016
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605531	journal	December 2016
Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Opportunities and challenges for a sustainable energy future Chu, Steven; Majumdar, Arun Nature, Vol. 488, Issue 7411, p. 294-303 https://doi.org/10.1038/nature11475	journal	August 2012
Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF ₃ framework Wang, Hansen; Lin, Dingchang; Liu, Yayuan Science Advances, Vol. 3, Issue 9 https://doi.org/10.1126/sciadv.1701301	journal	September 2017
A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries Suo, Liumin; Hu, Yong-Sheng; Li, Hong Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2513	journal	February 2013
Design of Complex Nanomaterials for Energy Storage: Past Success and Future Opportunity Liu, Yayuan; Zhou, Guangmin; Liu, Kai Accounts of Chemical Research, Vol. 50, Issue 12 https://doi.org/10.1021/acs.accounts.7b00450	journal	December 2017
Regulating Li deposition by constructing LiF-rich host for dendrite-free lithium metal anode Yuan, Yanxia; Wu, Feng; Bai, Ying Energy Storage Materials, Vol. 16 https://doi.org/10.1016/j.ensm.2018.06.022	journal	January 2019
An In Vivo Formed Solid Electrolyte Surface Layer Enables Stable Plating of Li Metal Pang, Quan; Liang, Xiao; Shyamsunder, Abhinandan Joule, Vol. 1, Issue 4 https://doi.org/10.1016/j.joule.2017.11.009	journal	December 2017
High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating Zheng, Guangyuan; Wang, Chao; Pei, Allen ACS Energy Letters, Vol. 1, Issue 6 https://doi.org/10.1021/acsenergylett.6b00456	journal	November 2016
Preparation of eggplant-derived macroporous carbon tubes and composites of EDMCT/Co(OH)(CO ₃ ) _0.5 nano-cone-arrays for high-performance supercapacitors Qu, Yicheng; Zan, Guangtao; Wang, Jiaxian Journal of Materials Chemistry A, Vol. 4, Issue 11 https://doi.org/10.1039/C5TA09948J	journal	January 2016
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability Zhao, Jie; Liao, Lei; Shi, Feifei Journal of the American Chemical Society, Vol. 139, Issue 33 https://doi.org/10.1021/jacs.7b05251	journal	August 2017
Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer Liu, Kai; Pei, Allen; Lee, Hye Ryoung Journal of the American Chemical Society, Vol. 139, Issue 13 https://doi.org/10.1021/jacs.6b13314	journal	March 2017
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries Suo, Liumin; Xue, Weijiang; Gobet, Mallory Proceedings of the National Academy of Sciences, Vol. 115, Issue 6 https://doi.org/10.1073/pnas.1712895115	journal	January 2018
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes Lin, Dingchang; Liu, Yayuan; Liang, Zheng Nature Nanotechnology, Vol. 11, Issue 7 https://doi.org/10.1038/nnano.2016.32	journal	March 2016
Incorporating Ionic Paths into 3D Conducting Scaffolds for High Volumetric and Areal Capacity, High Rate Lithium-Metal Anodes Zhang, Chanyuan; Liu, Shan; Li, Guojie Advanced Materials, Vol. 30, Issue 33 https://doi.org/10.1002/adma.201801328	journal	July 2018
Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes Liu, Wei; Li, Weiyang; Zhuo, Denys ACS Central Science, Vol. 3, Issue 2 https://doi.org/10.1021/acscentsci.6b00389	journal	January 2017
Interconnected hollow carbon nanospheres for stable lithium metal anodes Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng Nature Nanotechnology, Vol. 9, Issue 8 https://doi.org/10.1038/nnano.2014.152	journal	July 2014
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4041	journal	August 2014
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Artificial Protection Film on Lithium Metal Anode toward Long-Cycle-Life Lithium-Oxygen Batteries Liu, Qing-Chao; Xu, Ji-Jing; Yuan, Shuang Advanced Materials, Vol. 27, Issue 40 https://doi.org/10.1002/adma.201504429	journal	October 2015
A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia Angewandte Chemie, Vol. 130, Issue 6 https://doi.org/10.1002/ange.201710806	journal	January 2018
Decoupling the origins of irreversible coulombic efficiency in anode-free lithium metal batteries Huang, Chen-Jui; Thirumalraj, Balamurugan; Tao, Hsien-Chu Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21683-6	journal	March 2021
Highly Stable Lithium Metal Batteries Enabled by Regulating the Solvation of Lithium Ions in Nonaqueous Electrolytes Zhang, Xue-Qiang; Chen, Xiang; Cheng, Xin-Bing Angewandte Chemie, Vol. 130, Issue 19 https://doi.org/10.1002/ange.201801513	journal	March 2018
Stable Lithium Electrodeposition in Liquid and Nanoporous Solid Electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden arXiv https://doi.org/10.48550/arxiv.1404.6177	text	January 2014

Cited By (7)

In Situ Preparation of Thin and Rigid COF Film on Li Anode as Artificial Solid Electrolyte Interphase Layer Resisting Li Dendrite Puncture Chen, Dongdong; Huang, Sheng; Zhong, Lei Advanced Functional Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adfm.201907717	journal	December 2019
Plating/Stripping Behavior of Actual Lithium Metal Anode Liu, He; Cheng, Xin‐Bing; Xu, Rui Advanced Energy Materials, Vol. 9, Issue 44 https://doi.org/10.1002/aenm.201902254	journal	October 2019
Large‐Scale Modification of Commercial Copper Foil with Lithiophilic Metal Layer for Li Metal Battery Cui, Shiqiang; Zhai, Pengbo; Yang, Weiwei Small, Vol. 16, Issue 5 https://doi.org/10.1002/smll.201905620	journal	January 2020
In situ fluorinated solid electrolyte interphase towards long-life lithium metal anodes Xu, Shan-Min; Duan, Hui; Shi, Ji-Lei Nano Research, Vol. 13, Issue 2 https://doi.org/10.1007/s12274-020-2625-z	journal	January 2020
Lithium Metal Anode Materials Design: Interphase and Host Wang, Hansen; Liu, Yayuan; Li, Yuzhang Electrochemical Energy Reviews, Vol. 2, Issue 4 https://doi.org/10.1007/s41918-019-00054-2	journal	October 2019
Shape-stabilized phase-change materials supported by eggplant-derived porous carbon for efficient solar-to-thermal energy conversion and storage Li, Yaqiong; Huang, Xiubing; Li, Yang Sustainable Energy & Fuels, Vol. 4, Issue 4 https://doi.org/10.1039/c9se01272a	journal	January 2020
An engineered self-supported electrocatalytic cathode and dendrite-free composite anode based on 3D double-carbon hosts for advanced Li–SeS ₂ batteries Wang, Mei; Guo, Yi; Wang, Boya Journal of Materials Chemistry A, Vol. 8, Issue 6 https://doi.org/10.1039/c9ta11124g	journal	January 2020

Similar Records

Wrinkled Graphene Cages as Hosts for High-Capacity Li Metal Anodes Shown by Cryogenic Electron Microscopy

Journal Article · Thu Jan 24 00:00:00 EST 2019 · Nano Letters · OSTI ID:1506957

Wang, Hansen; Li, Yuzhang; Li, Yanbin; +16 more

Enhanced Stability of Li Metal Anodes by Synergetic Control of Nucleation and the Solid Electrolyte Interphase

Journal Article · Mon Sep 30 00:00:00 EDT 2019 · Advanced Energy Materials · OSTI ID:1506957

Peng, Zhe; Song, Junhua; Huai, Liyuan; +15 more

A Highly Reversible, Dendrite‐Free Lithium Metal Anode Enabled by a Lithium‐Fluoride‐Enriched Interphase

Journal Article · Fri Feb 14 00:00:00 EST 2020 · Advanced Materials · OSTI ID:1506957

Cui, Chunyu; Yang, Chongyin; Eidson, Nico; +7 more

Related Subjects

25 ENERGY STORAGE
Coulombic efficiency
host
lithium metal anodes
SEI

Title: An Interconnected Channel-Like Framework as Host for Lithium Metal Composite Anodes

Citation Formats

References (52)

Cited By (7)

Similar Records

Related Subjects