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Ultrastrong nanocrystalline steel with exceptional thermal stability and radiation tolerance

Journal Article · · Nature Communications
Nanocrystalline (NC) metals are stronger and more radiation-tolerant than their coarse-grained (CG) counterparts, but they often suffer from poor thermal stability, i.e., nanograins coarsen significantly when heated to 0.3 to 0.5 of their melting temperature (Tm). Here we report an NC austenitic stainless steel (NC-SS) containing 1 at% lanthanum with an average grain size of 45 nm and an ultrahigh yield strength of ~ 2.5 GPa that exhibits exceptional thermal stability up to 1000 oC (0.75 Tm). In-situ irradiation to 40 dpa at 450 oC and ex-situ irradiation to 108 dpa at 600 oC produce neither significant grain growth nor void swelling, in contrast to significant void swelling of CG-SS at similar doses. This thermal stability is due to segregation of elemental lanthanum and (La, O, Si)-rich nanoprecipitates at grain boundaries. Microstructure dependent cluster dynamics show grain boundary sinks effectively reduce steady-state vacancy concentrations to suppress void swelling upon irradiation.
Research Organization:
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC05-76RL01830
OSTI ID:
1489222
Report Number(s):
PNNL-SA--139907
Journal Information:
Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 9; ISSN 2041-1723
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United States
Language:
English

References (61)

Design of Radiation Tolerant Materials Via Interface Engineering journal September 2013
Stabilization of nanocrystalline grain sizes by solute additions journal December 2008
The radiation damage tolerance of ultra-high strength nanolayered composites journal September 2007
Irradiation-tolerant nanostructured ferritic alloys: Transforming helium from a liability to an asset journal September 2010
The impact of swelling on fusion reactor first wall lifetime journal May 1984
Theory and experimental background on dimensional changes in irradiated alloys journal October 1994
An in-situ tem study of the thermal stability of nanocrystalline NiP journal December 1991
Alloy effects in nanostructures journal January 1993
Grain growth and chemical ordering in (Fe,Mn)3Si journal March 1995
Effect of grain boundary character on sink efficiency journal October 2012
Unusual size-dependent strengthening mechanisms in helium ion-irradiated immiscible coherent Cu/Co nanolayers journal February 2015
Stainless steel in construction: A review of research, applications, challenges and opportunities journal November 2008
Micro-engineered first wall tungsten armor for high average power laser fusion energy systems journal December 2005
Radiation damage in helium ion irradiated nanocrystalline Fe journal June 2012
Ideal sinks are not always ideal: Radiation damage accumulation in nanocomposites journal July 2015
Methodology for determining void swelling at very high damage under ion irradiation journal August 2016
Radiation damage tolerant nanomaterials journal November 2013
Microstructural observation and tensile properties of ODS-304 austenitic steel journal January 2013
High-temperature grain size stabilization of nanocrystalline Fe–Cr alloys with Hf additions journal September 2014
Influence of injected interstitials on the void swelling in two structural variants of 304L stainless steel induced by self-ion irradiation at 500 °C journal October 2017
Defect-interface interactions journal October 2015
Radiation damage in nanostructured materials journal July 2018
Comparison of swelling and irradiation creep behavior of fcc-austenitic and bcc-ferritic/martensitic alloys at high neutron exposure journal January 2000
Grain coarsening inhibited by solute segregation journal January 2002
Structural materials for fission & fusion energy journal November 2009
In Situ Study of Defect Migration Kinetics and Self-Healing of Twin Boundaries in Heavy Ion Irradiated Nanotwinned Metals journal April 2015
Voids in Irradiated Stainless Steel journal November 1967
Ultrastrong steel via minimal lattice misfit and high-density nanoprecipitation journal April 2017
Effect of grain size on void formation during high-energy electron irradiation of austenitic stainless steel journal January 1974
An experimental investigation of extrapolation methods in the derivation of accurate unit-cell dimensions of crystals journal May 1945
Interface Structure and Radiation Damage Resistance in Cu-Nb Multilayer Nanocomposites journal April 2008
Design of Stable Nanocrystalline Alloys journal August 2012
High dislocation density–induced large ductility in deformed and partitioned steels journal August 2017
Enhanced thermal stability of nanograined metals below a critical grain size journal May 2018
Phase-Field Models for Microstructure Evolution journal August 2002
Alloy thermodynamics in nanostructures journal January 1994
Solute-Derived Thermal Stabilization of Nano-sized Grains in Melt-Spun Aluminum journal June 2016
Void-swelling in irons and ferritic steels journal November 1979
Microstructure and strength of nanocrystalline copper alloy prepared by mechanical alloying journal August 1991
Grain growth in nanocrystalline TiO2 and its relation to vickers hardness and fracture toughness journal December 1990
An in-situ tem study of the thermal stability of nanocrystalline NiP journal December 1991
Alloy effects in nanostructures journal January 1993
Defect and void evolution in oxide dispersion strengthened ferritic steels under 3.2 MeV Fe+ ion irradiation with simultaneous helium injection journal August 2000
Comparison of swelling and irradiation creep behavior of fcc-austenitic and bcc-ferritic/martensitic alloys at high neutron exposure journal January 2000
Grain coarsening inhibited by solute segregation journal January 2002
Structural materials for fission & fusion energy journal November 2009
Materials challenges in nuclear energy journal February 2013
The stabilization of nanocrystalline copper by zirconium journal January 2013
Grain-size stabilization in nanocrystalline FeZr alloys journal September 2008
A review: applications of the phase field method in predicting microstructure and property evolution of irradiated nuclear materials journal April 2017
Superior radiation-resistant nanoengineered austenitic 304L stainless steel for applications in extreme radiation environments journal January 2015
The Deformation and Ageing of Mild Steel: III Discussion of Results journal September 1951
Formation mechanism and the role of nanoparticles in Fe-Cr ODS steels developed for radiation tolerance journal November 2010
Probing grain boundary sink strength at the nanoscale: Energetics and length scales of vacancy and interstitial absorption by grain boundaries in α -Fe journal February 2012
Interface Structure and Radiation Damage Resistance in Cu-Nb Multilayer Nanocomposites journal April 2008
Efficient Annealing of Radiation Damage Near Grain Boundaries via Interstitial Emission journal March 2010
Recent Developments in Irradiation-Resistant Steels journal August 2008
Advanced oxide dispersion strengthened and nanostructured ferritic alloys journal October 2013
Void swelling and irradiation creep in light water reactor (LWR) environments book January 2010
Alloy thermodynamics in nanostructures journal January 1994
Correlation between Milling Parameters, Structural and Mechanical Properties of Nanostructured Austenitic Y2O3 Strengthened Steels journal November 2012

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