Effects of one-step alkaline and two-step alkaline/dilute acid and alkaline/steam explosion pretreatments on the structure of isolated pine lignin

Das, Parthapratim; Stoffel, Romina B.; Area, Maria C.; Ragauskas, Arthur J.

doi:10.1016/j.biombioe.2018.11.029

Title: Effects of one-step alkaline and two-step alkaline/dilute acid and alkaline/steam explosion pretreatments on the structure of isolated pine lignin

Journal Article · Thu Dec 06 00:00:00 EST 2018 · Biomass and Bioenergy

DOI:https://doi.org/10.1016/j.biombioe.2018.11.029· OSTI ID:1489098

Das, Parthapratim ^[1];

^[2]; Area, Maria C. ^[3];

^[1]

Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Tennessee, Knoxville, TN (United States); Pulp and Paper Program- Institute of Materials of Misiones (National University of Misiones - National Council of Scientific and Technical Research), Misiones (Argentina)
Pulp and Paper Program- Institute of Materials of Misiones (National University of Misiones - National Council of Scientific and Technical Research), Misiones (Argentina)

Biological valorization of biomass most often depends on the efficient reduction of plant cell wall recalcitrance and conversion of lignin – the most recalcitrant constituent – to fuels, chemicals and/or value-added substances. Lignin conversion to fuels and value-added chemicals requires a sound understanding of the structure of lignin before and after different pretreatments. In the current work, an effort has been made to compare the structural differences in isolated pine lignin after one- (alkaline) and two-step (alkaline/dilute acid and alkaline/steam explosion) pretreatments. Our results indicate removal of the low molecular weight fraction of lignin after an initial alkaline pretreatment. A subsequent dilute acid pretreatment resulted in the loss of lignin inter-unit linkages such as β-O-4’ aryl ethers. Furthermore, with a steam explosion pretreatment, lignin exhibited a competing condensation process leading to increased condensed lignin structures.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1489098

Journal Information:: Biomass and Bioenergy, Vol. 120, Issue C; ISSN 0961-9534

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 27 works

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59 BASIC BIOLOGICAL SCIENCES
Pine
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Title: Effects of one-step alkaline and two-step alkaline/dilute acid and alkaline/steam explosion pretreatments on the structure of isolated pine lignin

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