Selective Charging Behavior in an Ionic Mixture Electrolyte-Supercapacitor System for Higher Energy and Power

Wang, Xuehang; Mehandzhiyski, Aleksandar Yordanov; Arstad, Bjørnar; Van Aken, Katherine L.; Mathis, Tyler S.; Gallegos, Alejandro; Tian, Ziqi; Ren, Dingding; Sheridan, Edel; Grimes, Brian Arthur; Jiang, De-en; Wu, Jianzhong; Gogotsi, Yury; Chen, De

doi:10.1021/jacs.7b10693

Title: Selective Charging Behavior in an Ionic Mixture Electrolyte-Supercapacitor System for Higher Energy and Power

Journal Article · Wed Nov 29 00:00:00 EST 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b10693· OSTI ID:1489029

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^[3]; Van Aken, Katherine L. ^[4]; Mathis, Tyler S. ^[4]; Gallegos, Alejandro ^[5];

^[5]; Ren, Dingding ^[2]; Sheridan, Edel ^[6]; Grimes, Brian Arthur ^[2];

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Norwegian Univ. of Science and Technology, Trondheim (Norway); Drexel Univ., Philadelphia, PA (United States)
Norwegian Univ. of Science and Technology, Trondheim (Norway)
SINTEF Materials and Chemistry, Oslo (Norway)
Drexel Univ., Philadelphia, PA (United States)
Univ. of California, Riverside, CA (United States)
SINTEF Materials and Chemistry, Trondheim (Norway)

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: ERKCC61; AC05-00OR22725

OSTI ID:: 1489029

Alternate ID(s):: OSTI ID: 1470145; OSTI ID: 1494890

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 51; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 76 works

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References (38)

Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
True Performance Metrics in Electrochemical Energy Storage Gogotsi, Y.; Simon, P. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1213003	journal	November 2011
Efficient storage mechanisms for building better supercapacitors Salanne, M.; Rotenberg, B.; Naoi, K. Nature Energy, Vol. 1, Issue 6 https://doi.org/10.1038/nenergy.2016.70	journal	May 2016
Formulation of Ionic-Liquid Electrolyte To Expand the Voltage Window of Supercapacitors Van Aken, Katherine L.; Beidaghi, Majid; Gogotsi, Yury Angewandte Chemie International Edition, Vol. 54, Issue 16 https://doi.org/10.1002/anie.201412257	journal	March 2015
Ionic-liquid materials for the electrochemical challenges of the future Armand, Michel; Endres, Frank; MacFarlane, Douglas R. Nature Materials, Vol. 8, Issue 8, p. 621-629 https://doi.org/10.1038/nmat2448	journal	July 2009
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Chmiola, J. Science, Vol. 313, Issue 5794 https://doi.org/10.1126/science.1132195	journal	September 2006
Relation between the Ion Size and Pore Size for an Electric Double-Layer Capacitor Largeot, Celine; Portet, Cristelle; Chmiola, John Journal of the American Chemical Society, Vol. 130, Issue 9 https://doi.org/10.1021/ja7106178	journal	March 2008
Geometrically confined favourable ion packing for high gravimetric capacitance in carbon–ionic liquid supercapacitors Wang, Xuehang; Zhou, Haitao; Sheridan, Edel Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02702K	journal	January 2016
Carbons and Electrolytes for Advanced Supercapacitors Béguin, François; Presser, Volker; Balducci, Andrea Advanced Materials, Vol. 26, Issue 14, p. 2219-2251 https://doi.org/10.1002/adma.201304137	journal	February 2014
Solvent effect on the ion adsorption from ionic liquid electrolyte into sub-nanometer carbon pores Lin, R.; Huang, P.; Ségalini, J. Electrochimica Acta, Vol. 54, Issue 27 https://doi.org/10.1016/j.electacta.2009.07.015	journal	November 2009
Ion Dynamics in Porous Carbon Electrodes in Supercapacitors Using in Situ Infrared Spectroelectrochemistry Richey, Francis W.; Dyatkin, Boris; Gogotsi, Yury Journal of the American Chemical Society, Vol. 135, Issue 34 https://doi.org/10.1021/ja406120e	journal	August 2013
On the Dynamics of Charging in Nanoporous Carbon-Based Supercapacitors Péan, Clarisse; Merlet, Céline; Rotenberg, Benjamin ACS Nano, Vol. 8, Issue 2 https://doi.org/10.1021/nn4058243	journal	January 2014
Direct observation of ion dynamics in supercapacitor electrodes using in situ diffusion NMR spectroscopy Forse, Alexander C.; Griffin, John M.; Merlet, Céline Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2016.216	journal	February 2017
Confinement, Desolvation, And Electrosorption Effects on the Diffusion of Ions in Nanoporous Carbon Electrodes Pean, Clarisse; Daffos, Barbara; Rotenberg, Benjamin Journal of the American Chemical Society, Vol. 137, Issue 39 https://doi.org/10.1021/jacs.5b07416	journal	September 2015
Boosted Supercapacitive Energy with High Rate Capability of aCarbon Framework with Hierarchical Pore Structure in an Ionic Liquid Wang, Xuehang; Zhou, Haitao; Lou, Fengliu ChemSusChem, Vol. 9, Issue 21 https://doi.org/10.1002/cssc.201600779	journal	October 2016
Double-Layer in Ionic Liquids: Paradigm Change? Kornyshev, Alexei A. The Journal of Physical Chemistry B, Vol. 111, Issue 20 https://doi.org/10.1021/jp067857o	journal	May 2007
Steric effects in adsorption of ions from mixed electrolytes into microporous carbon Segalini, Julie; Iwama, Etsuro; Taberna, Pierre-Louis Electrochemistry Communications, Vol. 15, Issue 1 https://doi.org/10.1016/j.elecom.2011.11.023	journal	February 2012
On the molecular origin of supercapacitance in nanoporous carbon electrodes Merlet, Céline; Rotenberg, Benjamin; Madden, Paul A. Nature Materials, Vol. 11, Issue 4 https://doi.org/10.1038/nmat3260	journal	March 2012
Electrochemical Quartz Crystal Microbalance (EQCM) Study of Ion Dynamics in Nanoporous Carbons Tsai, Wan-Yu; Taberna, Pierre-Louis; Simon, Patrice Journal of the American Chemical Society, Vol. 136, Issue 24 https://doi.org/10.1021/ja503449w	journal	June 2014
NMR Study of Ion Dynamics and Charge Storage in Ionic Liquid Supercapacitors Forse, Alexander C.; Griffin, John M.; Merlet, Céline Journal of the American Chemical Society, Vol. 137, Issue 22 https://doi.org/10.1021/jacs.5b03958	journal	May 2015
Highly confined ions store charge more efficiently in supercapacitors Merlet, C.; Péan, C.; Rotenberg, B. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3701	journal	October 2013
Desolvation of Ions in Subnanometer Pores and Its Effect on Capacitance and Double-Layer Theory Chmiola, John; Largeot, Celine; Taberna, Pierre-Louis Angewandte Chemie, Vol. 120, Issue 18 https://doi.org/10.1002/ange.200704894	journal	April 2008
Importance of Ion Packing on the Dynamics of Ionic Liquids during Micropore Charging He, Yadong; Qiao, Rui; Vatamanu, Jenel The Journal of Physical Chemistry Letters, Vol. 7, Issue 1 https://doi.org/10.1021/acs.jpclett.5b02378	journal	December 2015
Can ionophobic nanopores enhance the energy storage capacity of electric-double-layer capacitors containing nonaqueous electrolytes? Lian, Cheng; Liu, Honglai; Henderson, Douglas Journal of Physics: Condensed Matter, Vol. 28, Issue 41 https://doi.org/10.1088/0953-8984/28/41/414005	journal	August 2016
New Perspectives on the Charging Mechanisms of Supercapacitors Forse, Alexander C.; Merlet, Céline; Griffin, John M. Journal of the American Chemical Society, Vol. 138, Issue 18 https://doi.org/10.1021/jacs.6b02115	journal	April 2016
Rapid and Accurate Estimation of Densities of Room-Temperature Ionic Liquids and Salts Ye, Chengfeng; Shreeve, Jean'ne M. The Journal of Physical Chemistry A, Vol. 111, Issue 8 https://doi.org/10.1021/jp066202k	journal	March 2007
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Welton, Thomas Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084 https://doi.org/10.1021/cr980032t	journal	August 1999
Solvent-free ionic liquids as in situ probes for assessing the effect of ion size on the performance of electrical double layer capacitors Ania, C. O.; Pernak, J.; Stefaniak, F. Carbon, Vol. 44, Issue 14 https://doi.org/10.1016/j.carbon.2006.07.026	journal	November 2006
Capacitive Energy Storage from −50 to 100 °C Using an Ionic Liquid Electrolyte Lin, Rongying; Taberna, Pierre-Louis; Fantini, Sébastien The Journal of Physical Chemistry Letters, Vol. 2, Issue 19 https://doi.org/10.1021/jz201065t	journal	September 2011
Outstanding performance of activated graphene based supercapacitors in ionic liquid electrolyte from −50 to 80°C Tsai, Wan-Yu; Lin, Rongying; Murali, Shanthi Nano Energy, Vol. 2, Issue 3 https://doi.org/10.1016/j.nanoen.2012.11.006	journal	May 2013
Cation−π Interactions in Simple Aromatics: Electrostatics Provide a Predictive Tool Mecozzi, Sandro; West, Anthony P.; Dougherty, Dennis A. Journal of the American Chemical Society, Vol. 118, Issue 9 https://doi.org/10.1021/ja9539608	journal	January 1996
Competitive pi interactions and hydrogen bonding within imidazolium ionic liquids Matthews, Richard P.; Welton, Tom; Hunt, Patricia A. Physical Chemistry Chemical Physics, Vol. 16, Issue 7 https://doi.org/10.1039/c3cp54672a	journal	January 2014
A Computational Study of Cation−π Interactions vs Salt Bridges in Aqueous Media: Implications for Protein Engineering Gallivan, Justin P.; Dougherty, Dennis A. Journal of the American Chemical Society, Vol. 122, Issue 5 https://doi.org/10.1021/ja991755c	journal	January 2000
Exploring electrolyte organization in supercapacitor electrodes with solid-state NMR Deschamps, Michaël; Gilbert, Edouard; Azais, Philippe Nature Materials, Vol. 12, Issue 4 https://doi.org/10.1038/nmat3567	journal	February 2013
In situ NMR and electrochemical quartz crystal microbalance techniques reveal the structure of the electrical double layer in supercapacitors Griffin, John M.; Forse, Alexander C.; Tsai, Wan-Yu Nature Materials, Vol. 14, Issue 8 https://doi.org/10.1038/nmat4318	journal	June 2015
Real-Time NMR Studies of Electrochemical Double-Layer Capacitors Wang, Hao; Köster, Thomas K. -J.; Trease, Nicole M. Journal of the American Chemical Society, Vol. 133, Issue 48 https://doi.org/10.1021/ja2072115	journal	December 2011
Predictive thermodynamics for condensed phases Glasser, Leslie; Jenkins, H. Donald Brooke Chemical Society Reviews, Vol. 34, Issue 10 https://doi.org/10.1039/b501741f	journal	January 2005
Why Are Ionic Liquids Liquid? A Simple Explanation Based on Lattice and Solvation Energies Krossing, Ingo; Slattery, John M.; Daguenet, Corinne Journal of the American Chemical Society, Vol. 128, Issue 41 https://doi.org/10.1021/ja0619612	journal	October 2006

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A universal strategy to obtain highly redox-active porous carbons for efficient energy storage Song, Ziyang; Miao, Ling; Li, Liangchun Journal of Materials Chemistry A, Vol. 8, Issue 7 https://doi.org/10.1039/c9ta13520k	journal	January 2020
Density functional calculations of efficient H ₂ separation from impurity gases (H ₂ , N ₂ , H ₂ O, CO, Cl ₂ , and CH ₄ ) via bilayer g-C ₃ N ₄ membrane Guo, Yuan; Tang, Chunmei; Wang, Xinbo Chinese Physics B, Vol. 28, Issue 4 https://doi.org/10.1088/1674-1056/28/4/048102	journal	April 2019
Side-chain effects on the capacitive behaviour of ionic liquids in microporous electrodes Gallegos, Alejandro; Lian, Cheng; Dyatkin, Boris Molecular Physics, Vol. 117, Issue 23-24 https://doi.org/10.1080/00268976.2019.1650210	journal	August 2019
Ionic liquid electrolytes in electric double layer capacitors Yin, Li; Li, Shu; Liu, Xiaohong Science China Materials, Vol. 62, Issue 11 https://doi.org/10.1007/s40843-019-9458-3	journal	July 2019
Co ²⁺ induced phase transformation from δ- to α-MnO ₂ and their hierarchical α-MnO ₂ @δ-MnO ₂ nanostructures for efficient asymmetric supercapacitors Guo, Yu; Li, Lei; Song, Li Journal of Materials Chemistry A, Vol. 7, Issue 20 https://doi.org/10.1039/c9ta01918a	journal	January 2019
Highly accessible hierarchical porous carbon from a bi-functional ionic liquid bulky gel: high-performance electrochemical double layer capacitors Yan, Yang; Hao, Xiao-Feng; Gao, Li-guo Journal of Materials Chemistry A, Vol. 7, Issue 44 https://doi.org/10.1039/c9ta07820g	journal	January 2019
Rational Design of Carbon‐Rich Materials for Energy Storage and Conversion Kong, Debin; Gao, Yang; Xiao, Zhichang Advanced Materials, Vol. 31, Issue 45 https://doi.org/10.1002/adma.201804973	journal	October 2018
A first-principles roadmap and limits to design efficient supercapacitor electrode materials Ali, Basant A.; Allam, Nageh K. Physical Chemistry Chemical Physics, Vol. 21, Issue 32 https://doi.org/10.1039/c9cp02614b	journal	January 2019
Using inorganic dynamic porogens for preparing high-surface-area capacitive carbons with tailored micropores Dong, Xiao-Ling; Li, Wen-Cui; Jiang, Biao Journal of Materials Chemistry A, Vol. 7, Issue 2 https://doi.org/10.1039/c8ta10411e	journal	January 2019
Side-chain effects on the capacitive behaviour of ionic liquids in microporous electrodes Gallegos, Alejandro; Lian, Cheng; Dyatkin, Boris Taylor & Francis https://doi.org/10.6084/m9.figshare.9250184.v1	text	January 2019

Figures / Tables (3)

Figure 1(p. 3)

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Figure 3(p. 5)

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energy storage (including batteries and capacitors)
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