Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E-Alkenes [Well-Defined Rh–Ga Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E-Alkenes]

Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian; Ferrandon, Magali S.; Webber, Thomas E.; Platero-Prats, Ana E.; Duan, Jiaxin; Garcia-Holley, Paula; Camaioni, Donald M.; Chapman, Karena W.; Delferro, Massimiliano; Farha, Omar K.; Fulton, John L.; Gagliardi, Laura; Lercher, Johannes A.; Penn, R. Lee; Stein, Andreas; Lu, Connie C.

doi:10.1021/jacs.8b08550

Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E-Alkenes [Well-Defined Rh–Ga Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E-Alkenes]

Journal Article · Tue Oct 23 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b08550· OSTI ID:1484223

Desai, Sai Puneet ^[1]; ^[1]; ^[2]; Ferrandon, Magali S. ^[3]; ^[1]; ^[4]; Duan, Jiaxin ^[1]; Garcia-Holley, Paula ^[5]; ^[2]; ^[6]; ^[3]; ^[5]; ^[2]; ^[1]; Lercher, Johannes A. ^[7]; ^[1]; ^[1]; ^[1]

Univ. of Minnesota, Minneapolis, MN (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. Autonoma de Madrid, Madrid (Spain); Argonne National Lab. (ANL), Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Stony Brook Univ., Stony Brook, NY (United States)
Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Technische Univ. Munchen, Garching (Germany)

Promoters are ubiquitous in industrial heterogeneous catalysts. The wider roles of promoters in accelerating catalysis and/or controlling selectivity are, however, not well understood. A model system has been developed where a heterobimetallic active site comprising an active metal (Rh) and a promoter ion (Ga) are preassembled and delivered onto a metal-organic framework (MOF) support, NU-1000. The Rh-Ga sites in NU-1000 selectively catalyze the hydrogenation of acyclic alkynes to E-alkenes. The overall stereoselectivity is complementary to the well-known Lindlar’s catalyst, which generates Zalkenes. In conclusion, the role of the Ga in promoting this unusual selectivity is evidenced by the lack of semihydrogenation selectivity when Ga is absent and only Rh is present in the active site.

View Accepted Manuscript (DOE)

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357; AC05-76RL01830

OSTI ID:: 1484223

Alternate ID(s):: OSTI ID: 1507435

Report Number(s):: PNNL-SA--137231; 148161

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 45 Vol. 140; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (64)

Promoters and Poisons Koel, Bruce E.; Kim, Johoo Handbook of Heterogeneous Catalysis: Online https://doi.org/10.1002/9783527610044.hetcat0087	book	March 2008
Intermetallic Ni _x M _y ( M = Ga and Sn) Nanocrystals: A Non-precious Metal Catalyst for Semi-Hydrogenation of Alkynes Liu, Yuxi; Liu, Xiangwen; Feng, Quanchen Advanced Materials, Vol. 28, Issue 23 https://doi.org/10.1002/adma.201600603	journal	April 2016
Iron Pincer Complex Catalyzed, Environmentally Benign, E -Selective Semi-Hydrogenation of Alkynes Srimani, Dipankar; Diskin-Posner, Yael; Ben-David, Yehoshoa Angewandte Chemie, Vol. 125, Issue 52 https://doi.org/10.1002/ange.201306629	journal	November 2013
Handbook Of Heterogeneous Catalysis. 2., completely revised and enlarged Edition. Vol. 1-8. Edited by G. Ertl, H. Knözinger, F. Schüth, and J. Weitkamp. Thomas, John Meurig Angewandte Chemie International Edition, Vol. 48, Issue 19 https://doi.org/10.1002/anie.200901598	journal	April 2009
Ceria in Hydrogenation Catalysis: High Selectivity in the Conversion of Alkynes to Olefins Vilé, Gianvito; Bridier, Blaise; Wichert, Jonas Angewandte Chemie International Edition, Vol. 51, Issue 34 https://doi.org/10.1002/anie.201203675	journal	July 2012
A Functional-Group-Tolerant Catalytic trans Hydrogenation of Alkynes Radkowski, Karin; Sundararaju, Basker; Fürstner, Alois Angewandte Chemie International Edition, Vol. 52, Issue 1 https://doi.org/10.1002/anie.201205946	journal	September 2012
Heterogeneous Catalysis: Understanding for Designing, and Designing for Applications Corma, Avelino Angewandte Chemie International Edition, Vol. 55, Issue 21 https://doi.org/10.1002/anie.201601231	journal	April 2016
Silver Nanoparticles for Olefin Production: New Insights into the Mechanistic Description of Propyne Hydrogenation Vilé, Gianvito; Baudouin, David; Remediakis, Ioannis N. ChemCatChem, Vol. 5, Issue 12 https://doi.org/10.1002/cctc.201300569	journal	September 2013
Ein neuer Katalysator für selektive Hydrierungen Lindlar, H. Helvetica Chimica Acta, Vol. 35, Issue 2 https://doi.org/10.1002/hlca.19520350205	journal	February 1952
cp2k: atomistic simulations of condensed matter systems Hutter, Jürg; Iannuzzi, Marcella; Schiffmann, Florian Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 4, Issue 1 https://doi.org/10.1002/wcms.1159	journal	June 2013
Selective hydrogenation of propyne over supported copper catalysts: influence of support Wehrli, J. T.; Thomas, D. J.; Wainwright, M. S. Applied Catalysis, Vol. 70, Issue 1 https://doi.org/10.1016/S0166-9834(00)84168-8	journal	January 1991
Electronic factors in catalysis: the volcano curve and the effect of promotion in catalytic ammonia synthesis Dahl, Søren; Logadottir, Ashildur; Jacobsen, Claus J. H. Applied Catalysis A: General, Vol. 222, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)00826-2	journal	December 2001
Hydrogenation of carbon–carbon multiple bonds: chemo-, regio- and stereo-selectivity Molnár, Árpád; Sárkány, Antal; Varga, Mónika Journal of Molecular Catalysis A: Chemical, Vol. 173, Issue 1-2 https://doi.org/10.1016/S1381-1169(01)00150-9	journal	September 2001
Palladium assisted copper/alumina catalysts for the selective hydrogenation of propyne, propadiene and propene mixed feeds McCue, Alan J.; Gibson, Andrew; Anderson, James A. Chemical Engineering Journal, Vol. 285 https://doi.org/10.1016/j.cej.2015.09.118	journal	February 2016
Activated takovite catalysts for partial hydrogenation of ethyne, propyne, and propadiene Abello, S.; Verboekend, D.; Bridier, B. Journal of Catalysis, Vol. 259, Issue 1 https://doi.org/10.1016/j.jcat.2008.07.012	journal	October 2008
Partial hydrogenation of propyne over copper-based catalysts and comparison with nickel-based analogues Bridier, Blaise; López, Núria; Pérez-Ramírez, Javier Journal of Catalysis, Vol. 269, Issue 1 https://doi.org/10.1016/j.jcat.2009.10.019	journal	January 2010
Promoters in heterogeneous catalysis: The role of Cl on ethylene epoxidation over Ag Rocha, Tulio C. R.; Hävecker, Michael; Knop-Gericke, Axel Journal of Catalysis, Vol. 312 https://doi.org/10.1016/j.jcat.2014.01.002	journal	April 2014
Promoted ceria catalysts for alkyne semi-hydrogenation Vilé, Gianvito; Dähler, Patrick; Vecchietti, Julia Journal of Catalysis, Vol. 324 https://doi.org/10.1016/j.jcat.2015.01.020	journal	April 2015
Palladium sulphide – A highly selective catalyst for the gas phase hydrogenation of alkynes to alkenes McCue, Alan J.; Guerrero-Ruiz, Antonio; Rodríguez-Ramos, Inmaculada Journal of Catalysis, Vol. 340 https://doi.org/10.1016/j.jcat.2016.05.002	journal	August 2016
Installing Heterobimetallic Cobalt–Aluminum Single Sites on a Metal Organic Framework Support Thompson, Anthony B.; Pahls, Dale R.; Bernales, Varinia Chemistry of Materials, Vol. 28, Issue 18 https://doi.org/10.1021/acs.chemmater.6b03244	journal	September 2016
Role of a Modulator in the Synthesis of Phase-Pure NU-1000 Webber, Thomas E.; Liu, Wei-Guang; Desai, Sai Puneet ACS Applied Materials & Interfaces, Vol. 9, Issue 45 https://doi.org/10.1021/acsami.7b11348	journal	November 2017
Ag Alloyed Pd Single-Atom Catalysts for Efficient Selective Hydrogenation of Acetylene to Ethylene in Excess Ethylene Pei, Guang Xian; Liu, Xiao Yan; Wang, Aiqin ACS Catalysis, Vol. 5, Issue 6 https://doi.org/10.1021/acscatal.5b00700	journal	May 2015
PdZn Intermetallic Nanostructure with Pd–Zn–Pd Ensembles for Highly Active and Chemoselective Semi-Hydrogenation of Acetylene Zhou, Huiran; Yang, Xiaofeng; Li, Lin ACS Catalysis, Vol. 6, Issue 2 https://doi.org/10.1021/acscatal.5b01933	journal	January 2016
Selective Hydrogenation of Functionalized Alkynes to ( E )-Alkenes, Using Ordered Alloys as Catalysts Furukawa, Shinya; Komatsu, Takayuki ACS Catalysis, Vol. 6, Issue 3 https://doi.org/10.1021/acscatal.5b02953	journal	February 2016
Direct trans -Selective Ruthenium-Catalyzed Reduction of Alkynes in Two-Chamber Reactors and Continuous Flow Neumann, Karoline T.; Klimczyk, Sebastian; Burhardt, Mia N. ACS Catalysis, Vol. 6, Issue 7 https://doi.org/10.1021/acscatal.6b01045	journal	June 2016
Synthesis of BiRh Nanoplates with Superior Catalytic Performance in the Semihydrogenation of Acetylene Köhler, Daniel; Heise, Martin; Baranov, Alexey I. Chemistry of Materials, Vol. 24, Issue 9 https://doi.org/10.1021/cm300518j	journal	April 2012
Engineering Metal Organic Frameworks for Heterogeneous Catalysis Corma, A.; García, H.; Llabrés i Xamena, F. X. Chemical Reviews, Vol. 110, Issue 8, p. 4606-4655 https://doi.org/10.1021/cr9003924	journal	August 2010
Efficient Catalytic System for Synthesis of trans -Stilbene from Diphenylacetylene Using Rh-Based Intermetallic Compounds Furukawa, Shinya; Yokoyama, Akira; Komatsu, Takayuki ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs500947d	journal	September 2014
Coordinately unsaturated clusters. A novel catalytic reaction Burch, R. R.; Shusterman, A. J.; Muetterties, E. L. Journal of the American Chemical Society, Vol. 105, Issue 11 https://doi.org/10.1021/ja00349a030	journal	June 1983
Selective formation of trans olefins by a catalytic hydrogenation of alkynes mediated at two adjacent metal centers Burch, R. R.; Muetterties, E. L.; Teller, R. G. Journal of the American Chemical Society, Vol. 104, Issue 15 https://doi.org/10.1021/ja00379a040	journal	July 1982
Pd−Ga Intermetallic Compounds as Highly Selective Semihydrogenation Catalysts Armbrüster, Marc; Kovnir, Kirill; Behrens, Malte Journal of the American Chemical Society, Vol. 132, Issue 42 https://doi.org/10.1021/ja106568t	journal	October 2010
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
Kinetics and Thermodynamics of H ^– /H•/H ⁺ Transfer from a Rhodium(III) Hydride Hu, Yue; Norton, Jack R. Journal of the American Chemical Society, Vol. 136, Issue 16 https://doi.org/10.1021/ja412309j	journal	April 2014
Preparation of Macrocyclic Z -Enoates and ( E , Z )- or ( Z , E )-Dienoates through Catalytic Stereoselective Ring-Closing Metathesis Zhang, Hanmo; Yu, Elsie C.; Torker, Sebastian Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja510768c	journal	November 2014
Cooperative Effects in Ternary Cu−Ni−Fe Catalysts Lead to Enhanced Alkene Selectivity in Alkyne Hydrogenation Bridier, Blaise; Pérez-Ramírez, Javier Journal of the American Chemical Society, Vol. 132, Issue 12 https://doi.org/10.1021/ja9101997	journal	February 2010
Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation Cammarota, Ryan C.; Lu, Connie C. Journal of the American Chemical Society, Vol. 137, Issue 39 https://doi.org/10.1021/jacs.5b08313	journal	September 2015
E -Selective Semi-Hydrogenation of Alkynes by Heterobimetallic Catalysis Karunananda, Malkanthi K.; Mankad, Neal P. Journal of the American Chemical Society, Vol. 137, Issue 46 https://doi.org/10.1021/jacs.5b10357	journal	November 2015
Structural Transitions of the Metal-Oxide Nodes within Metal–Organic Frameworks: On the Local Structures of NU-1000 and UiO-66 Platero-Prats, Ana E.; Mavrandonakis, Andreas; Gallington, Leighanne C. Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.6b00069	journal	March 2016
Modular Attachment of Appended Boron Lewis Acids to a Ruthenium Pincer Catalyst: Metal–Ligand Cooperativity Enables Selective Alkyne Hydrogenation Tseng, Kuei-Nin T.; Kampf, Jeff W.; Szymczak, Nathaniel K. Journal of the American Chemical Society, Vol. 138, Issue 33 https://doi.org/10.1021/jacs.6b03972	journal	August 2016
Alkyne Semihydrogenation with a Well-Defined Nonclassical Co–H ₂ Catalyst: A H ₂ Spin on Isomerization and E -Selectivity Tokmic, Kenan; Fout, Alison R. Journal of the American Chemical Society, Vol. 138, Issue 41 https://doi.org/10.1021/jacs.6b08128	journal	October 2016
Regioselective Atomic Layer Deposition in Metal–Organic Frameworks Directed by Dispersion Interactions Gallington, Leighanne C.; Kim, In Soo; Liu, Wei-Guang Journal of the American Chemical Society, Vol. 138, Issue 41 https://doi.org/10.1021/jacs.6b08711	journal	October 2016
Isolated Single-Atom Pd Sites in Intermetallic Nanostructures: High Catalytic Selectivity for Semihydrogenation of Alkynes Feng, Quanchen; Zhao, Shu; Wang, Yu Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b01471	journal	May 2017
Systematic Identification of Promoters for Methane Oxidation Catalysts Using Size- and Composition-Controlled Pd-Based Bimetallic Nanocrystals Willis, Joshua J.; Goodman, Emmett D.; Wu, Liheng Journal of the American Chemical Society, Vol. 139, Issue 34 https://doi.org/10.1021/jacs.7b06260	journal	August 2017
Fine-Tuning the Activity of Metal–Organic Framework-Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane Li, Zhanyong; Peters, Aaron W.; Platero-Prats, Ana E. Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b09365	journal	October 2017
Half-Sandwich Ruthenium Carbene Complexes Link trans -Hydrogenation and gem -Hydrogenation of Internal Alkynes Guthertz, Alexandre; Leutzsch, Markus; Wolf, Lawrence M. Journal of the American Chemical Society, Vol. 140, Issue 8 https://doi.org/10.1021/jacs.8b00665	journal	February 2018
Organometallic reactions of rhodium octaethylporphyrin species in pyridine. Heterolytic cleavage of [(OEP)Rh]2 and metalloanion activation of carbon monoxide Wayland, Bradford B.; Balkus, Kenneth J.; Farnos, Maria D. Organometallics, Vol. 8, Issue 4 https://doi.org/10.1021/om00106a014	journal	April 1989
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A. Nature Chemistry, Vol. 6, Issue 7 https://doi.org/10.1038/nchem.1956	journal	May 2014
Chemoselective single-site Earth-abundant metal catalysts at metal–organic framework nodes Manna, Kuntal; Ji, Pengfei; Lin, Zekai Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12610	journal	August 2016
Al13Fe4 as a low-cost alternative for palladium in heterogeneous hydrogenation Armbrüster, M.; Kovnir, K.; Friedrich, M. Nature Materials, Vol. 11, Issue 8 https://doi.org/10.1038/nmat3347	journal	June 2012
Single-site catalyst promoters accelerate metal-catalyzed nitroarene hydrogenation Wang, Liang; Guan, Erjia; Zhang, Jian Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03810-y	journal	April 2018
Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation Albani, Davide; Shahrokhi, Masoud; Chen, Zupeng Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05052-4	journal	July 2018
The role of reticular chemistry in the design of CO2 reduction catalysts Diercks, Christian S.; Liu, Yuzhong; Cordova, Kyle E. Nature Materials, Vol. 17, Issue 4 https://doi.org/10.1038/s41563-018-0033-5	journal	February 2018
Heterogeneous single-atom catalysis Wang, Aiqin; Li, Jun; Zhang, Tao Nature Reviews Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/s41570-018-0010-1	journal	May 2018
Postsynthetic modification of metal–organic frameworks—a progress report Tanabe, Kristine K.; Cohen, Seth M. Chem. Soc. Rev., Vol. 40, Issue 2 https://doi.org/10.1039/C0CS00031K	journal	January 2011
Promoters in the hydrogenation of alkynes in mixtures: insights from density functional theory López, Núria; Vargas-Fuentes, Crisa Chem. Commun., Vol. 48, Issue 10 https://doi.org/10.1039/C1CC14922A	journal	January 2012
Assembly of dicobalt and cobalt–aluminum oxide clusters on metal–organic framework and nanocast silica supports Desai, Sai Puneet; Malonzo, Camille D.; Webber, Thomas Faraday Discussions, Vol. 201 https://doi.org/10.1039/C7FD00055C	journal	January 2017
Addressing the characterisation challenge to understand catalysis in MOFs: the case of nanoscale Cu supported in NU-1000 Platero-Prats, Ana E.; Li, Zhanyong; Gallington, Leighanne C. Faraday Discussions, Vol. 201 https://doi.org/10.1039/C7FD00110J	journal	January 2017
Metal–organic framework materials as catalysts Lee, JeongYong; Farha, Omar K.; Roberts, John Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459 https://doi.org/10.1039/b807080f	journal	January 2009
Enantioselective catalysis with homochiral metal–organic frameworks Ma, Liqing; Abney, Carter; Lin, Wenbin Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256 https://doi.org/10.1039/b807083k	journal	January 2009
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Separable dual-space Gaussian pseudopotentials Goedecker, S.; Teter, M.; Hutter, J. Physical Review B, Vol. 54, Issue 3 https://doi.org/10.1103/PhysRevB.54.1703	journal	July 1996
Generalized Gradient Approximation Made Simple [Phys. Rev. Lett. 77, 3865 (1996)] Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 78, Issue 7 https://doi.org/10.1103/PhysRevLett.78.1396	journal	February 1997
Solvent-Free Oxidation of Primary Alcohols to Aldehydes Using Au-Pd/TiO ₂ Catalysts Enache, Dan I.; Edwards, Jennifer K.; Landon, Philip Science, Vol. 311, Issue 5759 https://doi.org/10.1126/science.1120560	journal	January 2006
Identification of Non-Precious Metal Alloy Catalysts for Selective Hydrogenation of Acetylene Studt, F.; Abild-Pedersen, F.; Bligaard, T. Science, Vol. 320, Issue 5881 https://doi.org/10.1126/science.1156660	journal	June 2008

Cited By (7)

Anion Pairs Template a Trigonal Prism with Disilver Vertices Carpenter, John P.; McTernan, Charlie T.; Ronson, Tanya K. Journal of the American Chemical Society, Vol. 141, Issue 29 https://doi.org/10.1021/jacs.9b05432	journal	July 2019
Fast and Selective Semihydrogenation of Alkynes by Palladium Nanoparticles Sandwiched in Metal–Organic Frameworks Choe, Kwanghak; Zheng, Fengbin; Wang, Hui Angewandte Chemie, Vol. 132, Issue 9 https://doi.org/10.1002/ange.201913453	journal	January 2020
Fast and Selective Semihydrogenation of Alkynes by Palladium Nanoparticles Sandwiched in Metal–Organic Frameworks Choe, Kwanghak; Zheng, Fengbin; Wang, Hui Angewandte Chemie International Edition, Vol. 59, Issue 9 https://doi.org/10.1002/anie.201913453	journal	January 2020
Catalyst as colour indicator for endpoint detection to enable selective alkyne trans-hydrogenation with ethanol Wang, Yulei; Huang, Zhidao; Huang, Zheng Nature Catalysis, Vol. 2, Issue 6 https://doi.org/10.1038/s41929-019-0299-2	journal	June 2019
Heterobimetallic scandium–group 10 metal complexes with LM → Sc (LM = Ni, Pd, Pt) dative bonds Cui, Peng; Xiong, Chunyan; Du, Jun Dalton Transactions, Vol. 49, Issue 1 https://doi.org/10.1039/c9dt04369a	journal	January 2020
Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids Simon, Ilka; Hornung, Julius; Barthel, Juri RWTH Aachen University https://doi.org/10.18154/rwth-2019-08213	text	January 2019
Synthesis of nickel/gallium nanoalloys using a dual-source approach in 1-alkyl-3-methylimidazole ionic liquids Simon, Ilka; Hornung, Julius; Barthel, Juri Beilstein Journal of Nanotechnology, Vol. 10 https://doi.org/10.3762/bjnano.10.171	journal	January 2019

Figures / Tables (5)

Similar Records

Installing heterobimetallic cobalt–aluminum single sites on a metal organic framework support

Journal Article · Sun Aug 21 20:00:00 EDT 2016 · Chemistry of Materials · OSTI ID:1356824

Construction of Au–Pd alloy shells for enhanced catalytic performance toward alkyne semihydrogenation reactions

Journal Article · Sat Dec 31 23:00:00 EST 2016 · Materials Horizons · OSTI ID:1535142

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

CCDC 1842577: Experimental Crystal Structure Determination: QIQBAW : (μ-N,N',N''-[nitrilotri(ethane-2,1-diyl)]tri(pyridin-2-aminido))-(phenolato)-gallium-rhodium benzene solvate Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian https://doi.org/10.5517/ccdc.csd.cc1zvbz4 The current record is supplemented by this dataset	dataset	May 2018
CCDC 1842578: Experimental Crystal Structure Determination: QIQBEA : (ethene)-(phenolato)-(N2-(pyridin-2-yl)-N1,N1-bis{2-[(pyridin-2-yl)amino]ethyl}ethane-1,2-diamine)-rhodium Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian https://doi.org/10.5517/ccdc.csd.cc1zvc06 The current record is supplemented by this dataset	dataset	May 2018
CCDC 1842579: Experimental Crystal Structure Determination: QIQBIE : (μ-N,N',N''-[nitrilotri(ethane-2,1-diyl)]tri(pyridin-2-aminido))-chloro-gallium-rhodium dichloromethane solvate Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian https://doi.org/10.5517/ccdc.csd.cc1zvc17 The current record is supplemented by this dataset	dataset	May 2018
CCDC 1842580: Experimental Crystal Structure Determination: QIQBOK : (μ-N,N',N''-[nitrilotri(ethane-2,1-diyl)]tri(pyridin-2-aminido))-methyl-gallium-rhodium acetonitrile solvate Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian https://doi.org/10.5517/ccdc.csd.cc1zvc28 The current record is supplemented by this dataset	dataset	May 2018
CCDC 1842581: Experimental Crystal Structure Determination: QIQBUQ : (diphenylacetylene)-(phenolato)-(N2-(pyridin-2-yl)-N1,N1-bis{2-[(pyridin-2-yl)amino]ethyl}ethane-1,2-diamine)-rhodium Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian https://doi.org/10.5517/ccdc.csd.cc1zvc39 The current record is supplemented by this dataset	dataset	May 2018

Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E-Alkenes [Well-Defined Rh–Ga Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E-Alkenes]

Citation Formats

References (64)

Cited By (7)

Linked Research (5)

Figures / Tables (5)

Similar Records

Related Subjects