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Lattice dynamics of ultrathin FeSe films on SrTiO3

Journal Article · · Physical Review B
 [1];  [1];  [2];  [3];  [2];  [1];  [1];  [1];  [1];  [1];  [4];  [4];  [4];  [5];  [5];  [1];  [6]
  1. Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics; Univ. of Chinese Academy of Sciences, Beijing (China). School of Physical Sciences
  2. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences. Computational Sciences and Engineering Division
  4. Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics
  5. Louisiana State Univ., Baton Rouge, LA (United States). Dept. of Physics and Astronomy
  6. Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics; Univ. of Chinese Academy of Sciences, Beijing (China). School of Physical Sciences; Collaborative Innovation Center of Quantum Matter, Beijing (China)
Charge transfer and electron-phonon coupling (EPC) are proposed to be two important constituents associated with enhanced superconductivity in the single unit cell FeSe films on oxide surfaces. Using high-resolution electron energy loss spectroscopy combined with first-principles calculations, we have explored here the lattice dynamics of ultrathin FeSe films grown on $${\mathrm{SrTiO}}_{3}$$. We show that, despite the significant effect from the substrate on the electronic structure and superconductivity of the system, the FeSe phonons in the films are unaffected. The energy dispersion and linewidth associated with the Fe- and Se-derived vibrational modes are thickness and temperature independent. Theoretical calculations indicate the crucial role of antiferromagnetic correlation in FeSe to reproduce the experimental phonon dispersion. Importantly, the only detectable change due to the growth of FeSe films is the broadening of the Fuchs-Kliewer (F-K) phonons associated with the lattice vibrations of $${\mathrm{SrTiO}}_{3}$$(001) substrate. Finally, if EPC plays any role in the enhancement of film superconductivity, it must be the interfacial coupling between the electrons in FeSe film and the F-K phonons from substrate rather than the phonons of FeSe.
Research Organization:
Chinese Academy of Sciences (CAS), Beijing (China); Louisiana State Univ., Baton Rouge, LA (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Chinese Academy of Sciences, Beijing (China); Univ. of Tennessee, Knoxville, TN (United States)
Sponsoring Organization:
National Key R&D Program of China; National Natural Science Foundation of China (NSFC); National Science Foundation (NSF) (United States); USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Youth Innovation Promotion Association of Chinese Academy of Sciences (CAS)
Grant/Contract Number:
AC02-05CH11231; AC05-00OR22725
OSTI ID:
1484097
Alternate ID(s):
OSTI ID: 1416071
Journal Information:
Physical Review B, Journal Name: Physical Review B Journal Issue: 3 Vol. 97; ISSN 2469-9950
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English

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Cited By (4)

Molecular Beam Epitaxy and Electronic Structure of Atomically Thin Oxyselenide Films journal August 2019
Unconventional pairing in single FeSe layers journal July 2019
Electron Phonon Coupling versus Photoelectron Energy Loss at the Origin of Replica Bands in Photoemission of FeSe on SrTiO 3 journal June 2018
Enhanced Superconducting State in FeSe / SrTiO 3 by a Dynamic Interfacial Polaron Mechanism journal February 2019

Figures / Tables (11)


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