The mechanisms, dynamics, and implications of self-sealing and CO2 resistance in wellbore cements

Guthrie, George Drake Jr.; Pawar, Rajesh J.; Carey, James William; Karra, Satish; Harp, Dylan Robert; Viswanathan, Hari S.

doi:10.1016/j.ijggc.2018.04.006

The mechanisms, dynamics, and implications of self-sealing and CO₂ resistance in wellbore cements

Journal Article · Thu Jun 14 00:00:00 EDT 2018 · International Journal of Greenhouse Gas Control

DOI:https://doi.org/10.1016/j.ijggc.2018.04.006· OSTI ID:1483500

Guthrie, George Drake Jr. ^[1]; ^[1]; ^[1]; ^[1]; ^[1]; ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Here, this study analyzes the dynamics and mechanisms of the interactions of carbonated brine with hydrated-Portland-cement; in particular, the study focuses on self-sealing, a process whereby hydrated-Portland cement reacts with carbonated brine to for silica and calcium carbonate in sufficient quantities to seal the flow pathway. The analysis is based on a comprehensive set of reactive-transport simulations that explore the complex coupled dynamics between the fluid flow and mineral reactions that underlie self-sealing, and it relies heavily on the synthesis of the extensive body of work on wellbore integrity that has been conducted over the past decade. The analysis explores a large chemical and mineralogical diversity and a wide range in physical conditions and flow regimes, attempting to assess the robustness of the analysis. Self-sealing conditions arise over a wide range in cement properties and reservoir conditions. Although some properties and conditions promote a stronger self-sealing response, self-sealing occurs for a wide range of Ca:Si ratios in cement and for various reservoir fluid compositions. Self-sealing conditions move along a wellbore proportional to the flux of the leaking carbonated brine, and the reaction zone spreads out proportional to the fluid velocity, where volumetric flux and velocity are related by porosity (flux = velocity * porosity). However, self-sealing conditions can be maintained in a specific section of a wellbore by controlling the pressure drive and/or effective wellbore permeability, which in turn can limit the flux and velocity of any leaking fluid. Finally, the phases produced by hydrating Portland cement represent a carbonic cement that will react with a carbonated brine to produce end products (calcium carbonate and silica) that can maintain integrity in the presence of carbonic acid. Lastly, the attributes that make hydrated Portland cement phases a carbonic cement are required for self-sealing.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Fossil Energy (FE); USDOE Office of Fossil Energy (FE). Clean Coal (FE-20)

Grant/Contract Number:: 89233218CNA000001; AC52-06NA25396

OSTI ID:: 1483500

Alternate ID(s):: OSTI ID: 1601502

Report Number(s):: LA-UR--17-29117

Journal Information:: International Journal of Greenhouse Gas Control, Journal Name: International Journal of Greenhouse Gas Control Journal Issue: C Vol. 75; ISSN 1750-5836

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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