The capricious nature of iodine catenation in I2 excess, perovskite-derived hybrid Pt(iv) compounds

Evans, Hayden A.; Andrews, Jessica L.; Fabini, Douglas H.; Preefer, Molleigh B.; Wu, Guang; Cheetham, Anthony K.; Wudl, Fred; Seshadri, Ram

doi:10.1039/C8CC07536K

The capricious nature of iodine catenation in I₂ excess, perovskite-derived hybrid Pt(iv) compounds

Journal Article · Tue Nov 27 00:00:00 EST 2018 · ChemComm

DOI:https://doi.org/10.1039/C8CC07536K· OSTI ID:1599725

^[1]; Andrews, Jessica L. ^[2]; ^[2]; Preefer, Molleigh B. ^[2]; Wu, Guang ^[2]; ^[3]; Wudl, Fred ^[2]; ^[2]

Univ. of California, Santa Barbara, CA (United States); UC Santa Barbara
Univ. of California, Santa Barbara, CA (United States)
Univ. of California, Santa Barbara, CA (United States); National Univ. of Singapore (Singapore)

Here, perovskite-derived hybrid platinum iodides with the general formula A₂Pt^IVI₆(A = formamidinium FA and guanidinium GUA) accommodate excess I₂to yield hydrogen-bond-stabilized compounds where the I₂forms catenates with I^-anions on the PtI₆octahedra.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, Santa Barbara, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: SC0012541

OSTI ID:: 1599725

Alternate ID(s):: OSTI ID: 1483443

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 5 Vol. 55; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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CCDC 1864903: Experimental Crystal Structure Determination Evans, Hayden A.; Andrews, Jessica L.; Fabini, Douglas H. https://doi.org/10.5517/ccdc.csd.cc20ll5d The current record is supplemented by this dataset	dataset	January 2018
CCDC 1864904: Experimental Crystal Structure Determination Evans, Hayden A.; Andrews, Jessica L.; Fabini, Douglas H. https://doi.org/10.5517/ccdc.csd.cc20ll6f The current record is supplemented by this dataset	dataset	January 2018
CCDC 1864905: Experimental Crystal Structure Determination Evans, Hayden A.; Andrews, Jessica L.; Fabini, Douglas H. https://doi.org/10.5517/ccdc.csd.cc20ll7g The current record is supplemented by this dataset	dataset	January 2018
CCDC 1864906: Experimental Crystal Structure Determination Evans, Hayden A.; Andrews, Jessica L.; Fabini, Douglas H. https://doi.org/10.5517/ccdc.csd.cc20ll8h The current record is supplemented by this dataset	dataset	January 2018
CCDC 1864907: Experimental Crystal Structure Determination Evans, Hayden A.; Andrews, Jessica L.; Fabini, Douglas H. https://doi.org/10.5517/ccdc.csd.cc20ll9j The current record is supplemented by this dataset	dataset	January 2018