Copolyesters developed from bio‐based 2,5‐furandicarboxylic acid: Synthesis, sequence distribution, mechanical, and barrier properties of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s

Jia, Zhen; Wang, Jinggang; Sun, Liyuan; Liu, Fei; Zhu, Jin; Liu, Xiaoqing

doi:10.1002/app.47291

Copolyesters developed from bio‐based 2,5‐furandicarboxylic acid: Synthesis, sequence distribution, mechanical, and barrier properties of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s

Journal Article · Sun Nov 25 00:00:00 EST 2018 · Journal of Applied Polymer Science

DOI:https://doi.org/10.1002/app.47291· OSTI ID:1483321

Jia, Zhen ^[1]; Wang, Jinggang ^[1]; Sun, Liyuan ^[2]; Liu, Fei ^[1]; Zhu, Jin ^[1]; ^[1]

Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo Zhejiang 315201 People's Republic of China, Key Laboratory of Bio‐based Polymeric Materials Ningbo Zhejiang 315201 People's Republic of China
Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo Zhejiang 315201 People's Republic of China, Key Laboratory of Bio‐based Polymeric Materials Ningbo Zhejiang 315201 People's Republic of China, University of Chinese Academy of Sciences Huairou Beijing 100049 People's Republic of China

ABSTRACT

A series of poly(propylene‐ co ‐1,4‐cyclohexanedimethylene 2,5‐furandicarboxylate)s (PPCFs) with different compositions were synthesized from bio‐based aromatic monomer 2,5‐furandicarboxylic acid and 1,3‐propanediol (PDO), along with 1,4‐cyclohexanedimethylene (CHDM). The chemical structure, composition, and sequence distribution of PPCFs were determined by nuclear magnetic resonance ( ¹ H NMR and ¹³ C NMR). Results showed that the compositions of copolyesters depended on the feed molar ratio of PDO and CHDM, and all the obtained PPCFs copolyesters had triad component in a random sequential structure. With the addition of CHDM, the gas barrier properties of poly(propylene 2,5‐furandicarboxylate) (PPF) deteriorated. However, when the content of CHDM reached 79%, PPCF79 still showed the CO ₂ and O ₂ barrier improvement factor of 4.5 and 3.25, respectively, which were better than those of poly(ethylene naphthalate), a well‐known polymer with barrier property. Besides, PPCF79 showed good performance on tensile modulus, tensile strength, elongation at break, and the crystallization enthalpy was improved from 3.2 J g ⁻¹ for PPF to 30.7 J g ⁻¹ for PPCF79. It has the potential to serve as a promising bio‐based polymer with excellent comprehensive performance. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136 , 47291.

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Sponsoring Organization:: USDOE

OSTI ID:: 1483321

Journal Information:: Journal of Applied Polymer Science, Journal Name: Journal of Applied Polymer Science Journal Issue: 13 Vol. 136; ISSN 0021-8995

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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