Rigid Oligomer from Lignin in Designing of Tough, Self-Healing Elastomers

Cui, Mengmeng; Nguyen, Ngoc A.; Bonnesen, Peter V.; Uhrig, David; Keum, Jong K.; Naskar, Amit K.

doi:10.1021/acsmacrolett.8b00600

Title: Rigid Oligomer from Lignin in Designing of Tough, Self-Healing Elastomers

Journal Article · Tue Oct 16 00:00:00 EDT 2018 · ACS Macro Letters

DOI:https://doi.org/10.1021/acsmacrolett.8b00600· OSTI ID:1483177

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Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Here, converting lignin into well-defined compounds is often challenged by structural complexation and inorganic contamination induced by the pulping process. In this report, instead of breaking down lignin into small molecules, we extracted a uniform and rigid oligomer from the lignin waste stream. The multifunctional polyphenol oligomer containing carboxylic acid, alcohol, and phenol groups is highly reactive and brings stiffness into the material matrix. Tough and self-healing elastomers are economically prepared from this oligomer by a reaction with epoxy-terminated polyethylene glycol, without needing any solvent. Specifically, the polyaromatic backbone’s rigidity enhances the elastomer’s toughness, and the multiple polar substituents form a network of hydrogen bonding that heals the elastomer. Many other applications, including adhesives, hydrogels, coating, and metal scavengers, are envisioned based on this oligomer’s unique properties.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1483177

Journal Information:: ACS Macro Letters, Vol. 7, Issue 11; ISSN 2161-1653

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 37 works

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