Tin–lead halide perovskites with improved thermal and air stability for efficient all-perovskite tandem solar cells

Leijtens, Tomas; Prasanna, Rohit; Bush, Kevin A.; Eperon, Giles E.; Raiford, James A.; Gold-Parker, Aryeh; Wolf, Eli J.; Swifter, Simon A.; Boyd, Caleb C.; Wang, Hsin-Ping; Toney, Michael F.; Bent, Stacey F.; McGehee, Michael D.

doi:10.1039/C8SE00314A

Tin–lead halide perovskites with improved thermal and air stability for efficient all-perovskite tandem solar cells

Journal Article · Sun Dec 31 23:00:00 EST 2017 · Sustainable Energy & Fuels

DOI:https://doi.org/10.1039/C8SE00314A· OSTI ID:1482895

^[1]; ^[1]; Bush, Kevin A. ^[2]; Eperon, Giles E. ^[3]; Raiford, James A. ^[4]; ^[5]; Wolf, Eli J. ^[2]; Swifter, Simon A. ^[2]; Boyd, Caleb C. ^[2]; Wang, Hsin-Ping ^[2]; ^[6]; Bent, Stacey F. ^[4]; McGehee, Michael D. ^[7]

Department of Materials Science; Stanford University; Stanford; USA; National Renewable Energy Laboratory
Department of Materials Science; Stanford University; Stanford; USA
Department of Chemistry; University of Washington; Seattle; USA; Cavendish Laboratory
Department of Chemical Engineering; Stanford University; Stanford; USA
Department of Chemistry; Stanford University; Stanford; USA; Stanford Synchrotron Radiation Lightsource
Stanford Synchrotron Radiation Lightsource; SLAC National Accelerator Laboratory; Menlo Park; USA
Department of Materials Science; Stanford University; Stanford; USA; Department of Chemical Engineering

We report the fabrication of monolithic all-perovskite tandem solar cells with a stabilized power conversion efficiency of 19.1% and demonstrate improved thermal, atmospheric, and operational stability of the tin–lead perovskite (FA_0.75Cs_0.25Sn_0.5Pb_0.5I₃) used as the low gap absorber.

Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 1482895

Report Number(s):: NREL/JA-5K00-72820

Journal Information:: Sustainable Energy & Fuels, Journal Name: Sustainable Energy & Fuels Journal Issue: 11 Vol. 2; ISSN SEFUA7; ISSN 2398-4902

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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On understanding bandgap bowing and optoelectronic quality in Pb–Sn alloy hybrid perovskites Rajagopal, Adharsh; Stoddard, Ryan J.; Hillhouse, Hugh W. Journal of Materials Chemistry A, Vol. 7, Issue 27 https://doi.org/10.1039/c9ta05308e	journal	January 2019
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Vacuum‐Assisted Growth of Low‐Bandgap Thin Films (FA$_{0.8}$MA$_{0.2}$Sn$_{0.5}$Pb$_{0.5}$I$_{3}$) for All‐Perovskite Tandem Solar Cells Abdollahi Nejand, Bahram; Hossain, Ihteaz M.; Jakoby, Marius Karlsruhe https://doi.org/10.5445/ir/1000104357	text	January 2020
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Mechanochemical Synthesis of Sn(II) and Sn(IV) Iodide Perovskites and Study of Their Structural, Chemical, Thermal, Optical, and Electrical Properties El Ajjouri, Yousra; Locardi, Federico; Gélvez-Rueda, María C. Energy Technology, Vol. 8, Issue 4 https://doi.org/10.1002/ente.201900788	journal	April 2020
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