Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research

Ataee‐Esfahani, Hamed; Chen, De‐Jun; Tong, YuYe J.

doi:10.1002/batt.201800068

Dual‐IR Window/Electrode Operando Attenuated Total Reflection‐IR Absorption Spectroscopy for Battery Research

Journal Article · Mon Nov 19 23:00:00 EST 2018 · Batteries & Supercaps

DOI:https://doi.org/10.1002/batt.201800068· OSTI ID:1482847

Ataee‐Esfahani, Hamed ^[1]; Chen, De‐Jun ^[1]; Tong, YuYe J. ^[1]

Department of Chemistry Georgetown University 37^th &, O St, NW Washington DC 20057 United States

Abstract

We report a novel dual‐IR window/electrode operando infrared (IR) spectroscopy method for battery research. In addition to keeping all the features of the in‐situ/operando IR spectroscopic methodologies for batteries reported in the literature so far, the dual‐IR window/electrode configuration reported herein offers a unique advantage of accessing both, anode and cathode processes quasi‐simultaneously by rotating the dual‐window/electrode IR battery cell 180° step‐wise in the same operando real‐battery‐like cell. The proof‐of‐concept studies demonstrated clearly its investigative advantages in gaining broader insights into the chemistry of batteries during charging/discharging and beyond.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

OSTI ID:: 1482847

Journal Information:: Batteries & Supercaps, Journal Name: Batteries & Supercaps Journal Issue: 1 Vol. 2; ISSN 2566-6223

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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