Single crystal growth and magnetic properties of the mixed valent Yb containing Zintl phase, Yb14MgSb11
- Univ. of California, Davis, CA (United States)
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
Here, large crystals of Yb14MgSb11 were grown through a Sn flux method. Magnetic susceptibility measurements yield an effective magnetic moment of 3.4(1) μB, revealing the presence of both divalent and trivalent Yb in Yb14MgSb11. Previously assumed to only contain Yb2+ as in Yb14MnSb11, the mixed valency demonstrates that Yb14MgSb11 is a Zintl phase.
- Research Organization:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- Grant GBMF4411; SC0014664; AC02-07CH11358
- OSTI ID:
- 1481869
- Alternate ID(s):
- OSTI ID: 1480150
- Report Number(s):
- IS-J-9796; CHCOFS
- Journal Information:
- ChemComm, Vol. 54, Issue 92; ISSN 1359-7345
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 15 works
Citation information provided by
Web of Science
Web of Science
Synthesis, crystal structure and physical properties of the solid solutions Ca 14– x RE x CdSb 11 ( RE = La–Nd, Sm, Gd–Yb, x ≈ 0.85 ± 0.15)
|
journal | June 2019 |
Hydride assisted synthesis of the high temperature thermoelectric phase: Yb 14 MgSb 11
|
journal | October 2019 |
Seebeck and Figure of Merit Enhancement by Rare Earth Doping in Yb14-xRExZnSb11 (x = 0.5)
|
journal | March 2019 |
Similar Records
Intermediate Yb valence in the Zintl phases Yb14MSb11(M=Zn,Mn,Mg): XANES, magnetism, and heat capacity
Structure and ferromagnetism of the rare-earth Zintl compounds: Yb{sub 14}MnSb{sub 11} and Yb{sub 14}MnBi{sub 11}
Finding the order in complexity: The electronic structure of 14-1-11 zintl compounds
Journal Article
·
Wed Nov 11 00:00:00 EST 2020
· Physical Review Materials
·
OSTI ID:1481869
+5 more
Structure and ferromagnetism of the rare-earth Zintl compounds: Yb{sub 14}MnSb{sub 11} and Yb{sub 14}MnBi{sub 11}
Journal Article
·
Sun Nov 01 00:00:00 EST 1998
· Chemistry of Materials
·
OSTI ID:1481869
+1 more
Finding the order in complexity: The electronic structure of 14-1-11 zintl compounds
Journal Article
·
Mon Nov 22 00:00:00 EST 2021
· Applied Physics Letters
·
OSTI ID:1481869
+3 more