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Title: X-ray Raman optical activity of chiral molecules

Journal Article · · Chemical Science
DOI:https://doi.org/10.1039/C8SC04120B· OSTI ID:1481432
ORCiD logo [1]; ORCiD logo [2];  [3]
  1. Ecole Polytechnique Fédérale de Lausanne, Laboratoire de Spectroscopie Ultrarapide, Faculté des Sciences de Base, ISIC-BSP, CH-1015 Lausanne
  2. PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, USA
  3. Department of Chemistry, University of California, Irvine, USA, Department of Physics and Astronomy
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Resonant and off-resonant Raman Optical Activity signals in the X-ray regime (XROA) are predicted. XROA is a chiral-sensitive variant of the spontaneous Resonant Inelastic Scattering (RIXS) signal. Thanks to the highly localized nature of core excitations, these signals provide a direct probe of local chirality with high sensitivity to the molecular structure. We derive sum-over-states expressions for frequency domain XROA signals and apply them to tyrosine at the nitrogen and oxygen K-edges. Time-resolved extensions of ROA made possible by using additional pulses are briefly outlined.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
FG02-04ER15571; AC02-76SF00515; CHE-1663822
OSTI ID:
1481432
Alternate ID(s):
OSTI ID: 1503547
Journal Information:
Chemical Science, Journal Name: Chemical Science Vol. 10 Journal Issue: 3; ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 15 works
Citation information provided by
Web of Science

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