Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman

Mcgrane, Shawn David; Aslam, Tariq Dennis; Pierce, Timothy Henry; Hare, Steven John; Byers, Mark Ellis

doi:10.1063/1.5016287

Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman

Journal Article · Wed Jan 24 00:00:00 EST 2018 · Journal of Applied Physics

DOI:https://doi.org/10.1063/1.5016287· OSTI ID:1481130

^[1]; ^[1]; Pierce, Timothy Henry ^[1]; Hare, Steven John ^[1]; Byers, Mark Ellis ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Raman spectra and velocimetry of shocked PBX 9502 (plastic bonded explosive composed of 95% triaminotrinitrobenzene (TATB) and 5% 3M Company Kel F-800 polymer binder) are reported with the Stokes/anti-Stokes ratio used to determine temperature after the shock reflects from a lithium fluoride window. Final pressures up to 14.5 GPa were tested, but the pressure induced absorption of TATB caused the Raman signal to decrease exponentially with pressure. The reflected shock temperature could be determined to 7 GPa, with an average increase of 14.9 K/GPa. Suggestions to adapt the technique to permit thermometry at higher temperatures are discussed, as are comparisons to a recently proposed equation of state for PBX 9502.

View Accepted Manuscript (DOE)

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1481130

Alternate ID(s):: OSTI ID: 1417941

Report Number(s):: LA-UR--17-30515

Journal Information:: Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 4 Vol. 123; ISSN 0021-8979

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited By (2)

Shock temperature dependent rate law for plastic bonded explosives Aslam, Tariq D. Journal of Applied Physics, Vol. 123, Issue 14 https://doi.org/10.1063/1.5020172	journal	April 2018
Dynamic absorption in optical pyrometry of hot spots in plastic-bonded triaminotrinitrobenzene Bassett, Will P.; Johnson, Belinda P.; Dlott, Dana D. Applied Physics Letters, Vol. 114, Issue 19 https://doi.org/10.1063/1.5092984	journal	May 2019

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Explosives
PBX 9502
Raman
shock
temperature

Temperature of shocked plastic bonded explosive PBX 9502 measured with spontaneous Stokes/anti-Stokes Raman

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References (24)

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