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Title: Thermoelectric studies of Ir 1 - x Rh x Te 2 ( 0 x 0.3 )

Journal Article · · Physical Review B
ORCiD logo [1];  [2];  [3];  [1];  [1];  [1];  [1]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States); Renmin Univ. of China, Beijing (People's Republic of China)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. of Maryland, College Park, MD (United States)

Here, we report thermoelectric properties of Ir1–xRhxTe2 (0 ≤ x ≤ 0.3) alloy series where superconductivity at low temperatures emerges as the high-temperature structural transition (Ts) is suppressed. The isovalent ionic substitution of Rh into Ir has different effects on physical properties when compared to the anionic substitution of Se into Te, in which the structural transition is more stable with Se substitution. Rh substitution results in a slight reduction of lattice parameters and in an increase of number of carriers per unit cell. Weak-coupled BCS superconductivity in Ir0.8Rh0.2Te2 that emerges at low temperature (Tczero = 2.45K) is most likely driven by electron-phonon coupling rather than dimer fluctuations mediated pairing.

Research Organization:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0012704
OSTI ID:
1480974
Alternate ID(s):
OSTI ID: 1473994
Report Number(s):
BNL-209352-2018-JAAM; PRBMDO
Journal Information:
Physical Review B, Vol. 98, Issue 9; ISSN 2469-9950
Publisher:
American Physical Society (APS)Copyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 8 works
Citation information provided by
Web of Science

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