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Synthesis of Geometrically Well-Defined Covalent Acene Dimers for Mechanistic Exploration of Singlet Fission

Journal Article · · Journal of Organic Chemistry

We report the first synthesis of norbornyl-bridged acene dimers (2 and 3) with well-defined and controlled spatial relationships between the acene chromophore subunits. We employ a modular 2-D strategy wherein the central module, common to all our compounds, is a norbornyl moiety. The acenes are attached to this module using the Diels–Alder reaction, which also forms one of the acene rings. Manipulation of the Diels–Alder adducts provides the desired geometrically defined bis-acenes. As a result, the modular nature of this synthesis affords flexibility and allows for the preparation of a variety of acene dimers, including functionalized tetracene dimers.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division
Grant/Contract Number:
FG02-07ER15890; AC02-05CH11231
OSTI ID:
1480248
Journal Information:
Journal of Organic Chemistry, Journal Name: Journal of Organic Chemistry Journal Issue: 9 Vol. 82; ISSN 0022-3263
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

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Cited By (4)

Davydov splitting and singlet fission in excitonically coupled pentacene dimers journal January 2019
Pentacene Dimers as a Critical Tool for the Investigation of Intramolecular Singlet Fission journal March 2018
Weakly coupled triplet pair states probed by quantum beating in delayed fluorescence in tetracene crystals journal October 2019
Davydov splitting and singlet fission in excitonically coupled pentacene dimers null January 2019

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