Rapid dissolution of surrogate nuclear debris using ammonium bifluoride fusion and indirect sonication dissolution methods

Hubley, Nicholas T.; Wegge, Dana L.; Weilert, Taylor M.; Leibman, Christopher P.; Rearick, Michael S.; Robertson, J. D.; Brockman, John D.

doi:10.1007/s10967-018-6127-3

Title: Rapid dissolution of surrogate nuclear debris using ammonium bifluoride fusion and indirect sonication dissolution methods

Journal Article · Sun Aug 19 00:00:00 EDT 2018 · Journal of Radioanalytical and Nuclear Chemistry

DOI:https://doi.org/10.1007/s10967-018-6127-3· OSTI ID:1479990

Hubley, Nicholas T. ^[1]; Wegge, Dana L. ^[1]; Weilert, Taylor M. ^[1]; Leibman, Christopher P. ^[2]; Rearick, Michael S. ^[2]; Robertson, J. D. ^[3];

^[3]

Univ. of Missouri, Columbia, MO (United States). Dept. of Chemistry
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Missouri, Columbia, MO (United States). Dept. of Chemistry. Research Reactor

Prompt analysis of elemental and isotopic information from post-detonation nuclear debris is critical for rapid attribution analysis. The capabilities of dissolution methods that use ammonium bifluoride (ABF, NH₄HF₂) and pressurized microwave digestion with HF acid are reported for NIST Surrogate Post-detonation Urban Debris (SPUD). Elemental concentration and isotope ratios were measured using inductively coupled plasma mass spectrometry. The SPUD material was also analyzed for U concentration using instrumental neutron activation analysis. Finally, the ABF dissolution method with a 10:1 ABF to sample ratio and the pressurized microwave digestion methods resulted in comparable results.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE; Defense Threat Reduction Agency (DTRA) (United States); Nuclear Regulatory Commission (NRC) (United States)

Grant/Contract Number:: AC52-06NA25396; HDTRA1-15-1-0016; NRC-HQ-84-15-G-0036

OSTI ID:: 1479990

Report Number(s):: LA-UR-18-23166

Journal Information:: Journal of Radioanalytical and Nuclear Chemistry, Vol. 318, Issue 1; ISSN 0236-5731

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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References (8)

Development of synthetic nuclear melt glass for forensic analysis Molgaard, Joshua J.; Auxier, John D.; Giminaro, Andrew V. Journal of Radioanalytical and Nuclear Chemistry, Vol. 304, Issue 3 https://doi.org/10.1007/s10967-015-3941-8	journal	January 2015
Total Rock Dissolution Using Ammonium Bifluoride (NH ₄ HF ₂ ) in Screw-Top Teflon Vials: A New Development in Open-Vessel Digestion Zhang, Wen; Hu, Zhaochu; Liu, Yongsheng Analytical Chemistry, Vol. 84, Issue 24 https://doi.org/10.1021/ac302327g	journal	November 2012
Development of ammonium bifluoride fusion method for rapid dissolution of trinitite samples and analysis by ICP-MS Hubley, Nickolas; Brown, John W. N.; Guthrie, James Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 3 https://doi.org/10.1007/s10967-015-4371-3	journal	August 2015
Evaluation of ammonium bifluoride fusion for rapid dissolution in post-detonation nuclear forensic analysis Hubley, Nicholas T.; Brockman, John D.; Robertson, J. David Radiochimica Acta, Vol. 105, Issue 8 https://doi.org/10.1515/ract-2016-2735	journal	January 2017
Sonication assisted dissolution of post-detonation nuclear debris using ammonium bifluoride Mason, Christian A.; Hubley, Nicholas T.; Robertson, J. David Radiochimica Acta, Vol. 105, Issue 12 https://doi.org/10.1515/ract-2017-2802	journal	November 2017
Precise Elemental and Isotopic Analyses in Silicate Samples Employing ICP-MS: Application of Hydrofluoric Acid Solution and Analytical Techniques Makishima, Akio; Tanaka, Ryoji; Nakamura, Eizo Analytical Sciences, Vol. 25, Issue 10 https://doi.org/10.2116/analsci.25.1181	journal	January 2009
Measurement of Uranium Isotope Ratios in Keratinous Materials: A Noninvasive Bioassay for Special Nuclear Material Brockman, John D.; Brown, John W. N.; Morrell, Jonathan S. Analytical Chemistry, Vol. 88, Issue 17 https://doi.org/10.1021/acs.analchem.6b02144	journal	August 2016
An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma-Mass Spectrometry Zhang, Wen; Qi, Liang; Hu, Zhaochu Geostandards and Geoanalytical Research, Vol. 40, Issue 2 https://doi.org/10.1111/j.1751-908X.2015.00356.x	journal	July 2015

Cited By (8)

Development of synthetic nuclear melt glass for forensic analysis Molgaard, Joshua J.; Auxier, John D.; Giminaro, Andrew V. Journal of Radioanalytical and Nuclear Chemistry, Vol. 304, Issue 3 https://doi.org/10.1007/s10967-015-3941-8	journal	January 2015
Development of ammonium bifluoride fusion method for rapid dissolution of trinitite samples and analysis by ICP-MS Hubley, Nickolas; Brown, John W. N.; Guthrie, James Journal of Radioanalytical and Nuclear Chemistry, Vol. 307, Issue 3 https://doi.org/10.1007/s10967-015-4371-3	journal	August 2015
Total Rock Dissolution Using Ammonium Bifluoride (NH ₄ HF ₂ ) in Screw-Top Teflon Vials: A New Development in Open-Vessel Digestion Zhang, Wen; Hu, Zhaochu; Liu, Yongsheng Analytical Chemistry, Vol. 84, Issue 24 https://doi.org/10.1021/ac302327g	journal	November 2012
Measurement of Uranium Isotope Ratios in Keratinous Materials: A Noninvasive Bioassay for Special Nuclear Material Brockman, John D.; Brown, John W. N.; Morrell, Jonathan S. Analytical Chemistry, Vol. 88, Issue 17 https://doi.org/10.1021/acs.analchem.6b02144	journal	August 2016
Application of inductively coupled plasma mass spectrometry for total metal determination in silicon-containing solid samples using the microwave-assisted nitric acid–hydrofluoric acid–hydrogen peroxide–boric acid digestion system Wu, Shaole; Zhao, Yu-Hui; Feng, Xinbang J. Anal. At. Spectrom., Vol. 11, Issue 4 https://doi.org/10.1039/ja9961100287	journal	January 1996
Evaluation of ammonium bifluoride fusion for rapid dissolution in post-detonation nuclear forensic analysis Hubley, Nicholas T.; Brockman, John D.; Robertson, J. David Radiochimica Acta, Vol. 105, Issue 8 https://doi.org/10.1515/ract-2016-2735	journal	January 2017
Sonication assisted dissolution of post-detonation nuclear debris using ammonium bifluoride Mason, Christian A.; Hubley, Nicholas T.; Robertson, J. David Radiochimica Acta, Vol. 105, Issue 12 https://doi.org/10.1515/ract-2017-2802	journal	November 2017
Precise Elemental and Isotopic Analyses in Silicate Samples Employing ICP-MS: Application of Hydrofluoric Acid Solution and Analytical Techniques Makishima, Akio; Tanaka, Ryoji; Nakamura, Eizo Analytical Sciences, Vol. 25, Issue 10 https://doi.org/10.2116/analsci.25.1181	journal	January 2009

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