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Design of Laboratory System to Recover Tritium from Zirconium Recycle and Plan to Test System

Technical Report ·
DOI:https://doi.org/10.2172/1479736· OSTI ID:1479736
 [1];  [1];  [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

The objective of the tritium separations task is to develop a viable process to separate tritium from the zirconium recycle off-gas stream. In support of this long-term objective, the goal of the present work is to design a test system and prepare a test plan for an alternate tritium capture method suitable for, and compatible with, recycle of the reactive gas (i.e., chlorine) in the zirconium recycle process. The zirconium recycle process is under development to recover zirconium from the Zircaloy® cladding component of used nuclear fuel. Small quantities of all isotopes of hydrogen (all H) are trapped in the Zircaloy as zirconium hydride. Processing releases and converts this hydrogen to hydrogen chloride, including tritium-substitu ted hydrogen chloride, 3HCl (a.k.a., TCl). This compound of tritium must be removed from the zirconium recycle process off-gas and sequestered to satisfy regulations governing emissions of tritium.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC05-00OR22725
OSTI ID:
1479736
Report Number(s):
ORNL/SPR-2018/984; NTRD-MRWFD-2018-000208
Country of Publication:
United States
Language:
English

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