Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability

Chen, Dong; Zhang, Pengfei; Fang, Qianrong; Wan, Shun; Li, Hui; Yang, Shize; Huang, Caili; Dai, Sheng

doi:10.1039/c8qi00471d

Title: Coordination-supported organic polymers: mesoporous inorganic–organic materials with preferred stability

Journal Article · Tue Jun 05 00:00:00 EDT 2018 · Inorganic Chemistry Frontiers (Online)

DOI:https://doi.org/10.1039/c8qi00471d· OSTI ID:1479716

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Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering
Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Jilin Univ., Changchun (China). State Key Lab. of Inorganic Synthesis and Preparative Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

Here, a simple and versatile strategy, borrowing ideas from the chemistry of MOFs and COFs, is developed for the synthesis of coordination-supported organic polymers (COPs) via coordination between Al³⁺ and 5-amino-8-hydroxyquinoline together with organic imine- or imide-based polycondensation. The COPs with high surface areas (up to 1123 m² g^-1) and abundant mesopores (2.5 nm or 14 nm) possess good crystalline and porous structure after being soaked in boiling water.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Shanghai Jiao Tong Univ. (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Shanghai Pujiang Program (China); Young Thousand Talented Program (China); National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC05-00OR22725; 17PJ1403500; 21776174

OSTI ID:: 1479716

Alternate ID(s):: OSTI ID: 1441042

Journal Information:: Inorganic Chemistry Frontiers (Online), Vol. 5, Issue 8; ISSN 2052-1553

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 7 works

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