Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Organosulfates in aerosols downwind of an urban region in central Amazon

Journal Article · · Environmental Science: Processes & Impacts
DOI:https://doi.org/10.1039/C8EM00413G· OSTI ID:1479155
 [1];  [1];  [2];  [3];  [2];  [4];  [5];  [6];  [7];  [7];  [7];  [7];  [7];  [6];  [3];  [2]
  1. Aarhus University, Dept. of Chemistry, 8000 Aarhus C, Denmark
  2. University of California, Berkeley, Dept. of Environmental Science, Policy, and Management, Berkeley, USA
  3. Harvard University, School of Engineering and Applied Sciences, Cambridge, USA
  4. University of California, Berkeley, Dept. of Civil and Environmental Engineering, Berkeley, USA
  5. University of Sao Paulo, Institute of Physics, Sao Paulo, Brazil
  6. Pacific Northwest National Laboratory, Environmental Molecular Sciences Laboratory, Richland, USA
  7. University of Colorado, Boulder, Dept. of Chemistry & Cooperative Institute for Research in Environmental Sciences (CIRES), Boulder, USA

Aerosols in the central Amazon downwind of a city contain considerable concentrations of organic sulfate derived from isoprene, correlating with inorganic aerosol sulfate.

Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0016559
OSTI ID:
1479155
Alternate ID(s):
OSTI ID: 1633049
Journal Information:
Environmental Science: Processes & Impacts, Journal Name: Environmental Science: Processes & Impacts Journal Issue: 11 Vol. 20; ISSN 2050-7887; ISSN ESPICZ
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (78)

Dimethyl sulfide in the Amazon rain forest: DMS in the Amazon journal January 2015
Acceleration of O + from the cusp to the plasma sheet : O+ acceleration: cusp to plasma sheet journal February 2015
Characterization of organosulfates from the photooxidation of isoprene and unsaturated fatty acids in ambient aerosol using liquid chromatography/(−) electrospray ionization mass spectrometry journal January 2008
Chemical and microphysical characterization of ambient aerosols with the aerodyne aerosol mass spectrometer journal January 2007
Mass spectrometric characterization of organosulfates related to secondary organic aerosol from isoprene: Organosulfates from isoprene journal March 2013
cis-pinic acid, a possible precursor for organic aerosol formation from ozonolysis of α-pinene journal May 1998
The mass budgets of carbonyl sulfide, dimethyl sulfide, carbon disulfide and hydrogen sulfide journal January 2000
Organosulfates and oxidation products from biogenic hydrocarbons in fine aerosols from a forest in North West Europe during spring journal September 2011
Chemical characterization of secondary organic aerosol constituents from isoprene ozonolysis in the presence of acidic aerosol journal April 2016
Denuder/filter sampling of organic acids and organosulfates at urban and boreal forest sites: Gas/particle distribution and possible sampling artifacts journal April 2016
Multiphase reactivity of gaseous hydroperoxide oligomers produced from isoprene ozonolysis in the presence of acidified aerosols journal March 2017
Composition and sources of carbonaceous aerosols in Northern Europe during winter journal January 2018
Field-Deployable, High-Resolution, Time-of-Flight Aerosol Mass Spectrometer journal December 2006
Evidence for an Unrecognized Secondary Anthropogenic Source of Organosulfates and Sulfonates: Gas-Phase Oxidation of Polycyclic Aromatic Hydrocarbons in the Presence of Sulfate Aerosol journal May 2015
Recent Discoveries and Future Challenges in Atmospheric Organic Chemistry journal February 2016
Effect of Organic Coatings, Humidity and Aerosol Acidity on Multiphase Chemistry of Isoprene Epoxydiols journal May 2016
Ambient Gas-Particle Partitioning of Tracers for Biogenic Oxidation journal September 2016
Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides journal September 2016
Effect of the Aerosol-Phase State on Secondary Organic Aerosol Formation from the Reactive Uptake of Isoprene-Derived Epoxydiols (IEPOX) journal February 2018
The Molecular Identification of Organic Compounds in the Atmosphere: State of the Art and Challenges journal February 2015
Evidence for Organosulfates in Secondary Organic Aerosol journal January 2007
Hydroxycarboxylic Acid-Derived Organosulfates: Synthesis, Stability, and Quantification in Ambient Aerosol journal August 2011
Isoprene Epoxydiols as Precursors to Secondary Organic Aerosol Formation: Acid-Catalyzed Reactive Uptake Studies with Authentic Compounds journal November 2011
Contribution of Organosulfur Compounds to Organic Aerosol Mass journal July 2012
Organosulfates as Tracers for Secondary Organic Aerosol (SOA) Formation from 2-Methyl-3-Buten-2-ol (MBO) in the Atmosphere journal August 2012
Observational Insights into Aerosol Formation from Isoprene journal September 2013
Characterization of Polar Organosulfates in Secondary Organic Aerosol from the Green Leaf Volatile 3- Z -Hexenal journal October 2014
Reactive Uptake of an Isoprene-Derived Epoxydiol to Submicron Aerosol Particles journal September 2014
Terpenylic Acid and Related Compounds from the Oxidation of α-Pinene: Implications for New Particle Formation and Growth above Forests journal September 2009
To What Extent Can Biogenic SOA be Controlled? journal May 2010
Carboxylic Acids in Secondary Aerosols from Oxidation of Cyclic Monoterpenes by Ozone journal March 2000
Chemical Composition of Secondary Organic Aerosol Formed from the Photooxidation of Isoprene journal August 2006
Organosulfate Formation in Biogenic Secondary Organic Aerosol journal September 2008
3-methyl-1,2,3-butanetricarboxylic acid: An atmospheric tracer for terpene secondary organic aerosol journal January 2007
Sources and properties of Amazonian aerosol particles journal January 2010
Mass spectral characterization of submicron biogenic organic particles in the Amazon Basin journal January 2009
Development and evaluation of a photooxidation mechanism for isoprene journal January 1992
A global model of natural volatile organic compound emissions journal January 1995
The cycle of biogenic sulfur compounds over the Amazon Basin: 1. Dry season journal January 1988
The atmospheric sulfur cycle over the Amazon Basin: 2. Wet season journal January 1990
Airborne observations reveal elevational gradient in tropical forest isoprene emissions journal May 2017
Sulfate radical-initiated formation of isoprene-derived organosulfates in atmospheric aerosols journal January 2013
Biogenic carbon and anthropogenic pollutants combine to form a cooling haze over the southeastern United States journal May 2009
Reactive intermediates revealed in secondary organic aerosol formation from isoprene journal December 2009
Response of an aerosol mass spectrometer to organonitrates and organosulfates and implications for atmospheric chemistry journal March 2010
Epoxide as a precursor to secondary organic aerosol formation from isoprene photooxidation in the presence of nitrogen oxides journal April 2013
Effects of anthropogenic emissions on aerosol formation from isoprene and monoterpenes in the southeastern United States journal December 2014
Isoprene photochemistry over the Amazon rainforest journal May 2016
Formation of Secondary Organic Aerosols Through Photooxidation of Isoprene journal February 2004
Unexpected Epoxide Formation in the Gas-Phase Photooxidation of Isoprene journal August 2009
NOAA’s HYSPLIT Atmospheric Transport and Dispersion Modeling System journal December 2015
The Green Ocean Amazon Experiment (GoAmazon2014/5) Observes Pollution Affecting Gases, Aerosols, Clouds, and Rainfall over the Rain Forest journal May 2017
Evidence for a significant proportion of Secondary Organic Aerosol from isoprene above a maritime tropical forest journal January 2011
Aerosol mass spectrometer constraint on the global secondary organic aerosol budget journal January 2011
A review of the anthropogenic influence on biogenic secondary organic aerosol journal January 2011
Formation of 3-methyl-1,2,3-butanetricarboxylic acid via gas phase oxidation of pinonic acid – a mass spectrometric study of SOA aging journal January 2012
Particle partitioning potential of organic compounds is highest in the Eastern US and driven by anthropogenic water journal January 2013
Organosulfates and organic acids in Arctic aerosols: speciation, annual variation and concentration levels journal January 2014
Understanding the anthropogenic influence on formation of biogenic secondary organic aerosols in Denmark via analysis of organosulfates and related oxidation products journal January 2014
Characterization of a real-time tracer for isoprene epoxydiols-derived secondary organic aerosol (IEPOX-SOA) from aerosol mass spectrometer measurements journal January 2015
Submicron particle mass concentrations and sources in the Amazonian wet season (AMAZE-08) journal January 2015
Fine-particle water and pH in the southeastern United States journal January 2015
Examining the effects of anthropogenic emissions on isoprene-derived secondary organic aerosol formation during the 2013 Southern Oxidant and Aerosol Study (SOAS) at the Look Rock, Tennessee ground site journal January 2015
Chemical characterization of organosulfates in secondary organic aerosol derived from the photooxidation of alkanes journal January 2016
Cloud condensation nuclei activity, droplet growth kinetics, and hygroscopicity of biogenic and anthropogenic secondary organic aerosol (SOA) journal January 2016
Molecular composition of organic aerosols in central Amazonia: an ultra-high-resolution mass spectrometry study journal January 2016
Long-term observations of cloud condensation nuclei in the Amazon rain forest – Part 1: Aerosol size distribution, hygroscopicity, and new model parametrizations for CCN prediction journal January 2016
Particle water and pH in the eastern Mediterranean: source variability and implications for nutrient availability journal January 2016
Introduction: Observations and Modeling of the Green Ocean Amazon (GoAmazon2014/5) journal January 2016
CCN activity and organic hygroscopicity of aerosols downwind of an urban region in central Amazonia: seasonal and diel variations and impact of anthropogenic emissions journal January 2017
Qualitative and quantitative analysis of atmospheric organosulfates in Centreville, Alabama journal January 2017
Influence of urban pollution on the production of organic particulate matter from isoprene epoxydiols in central Amazonia journal January 2017
Contributions of mobile, stationary and biogenic sources to air pollution in the Amazon rainforest: a numerical study with the WRF-Chem model journal January 2017
Trends in erythemal doses at the Polish Polar Station, Hornsund, Svalbard based on the homogenized measurements (1996–2016) and reconstructed data (1983–1995) journal January 2018
Novel pathway of SO 2 oxidation in the atmosphere: reactions with monoterpene ozonolysis intermediates and secondary organic aerosol journal January 2018
Physical properties of the sub-micrometer aerosol over the Amazon rain forest during the wet-to-dry season transition - comparison of modeled and measured CCN concentrations journal January 2004
A review of Secondary Organic Aerosol (SOA) formation from isoprene journal January 2009
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions journal January 2012

Similar Records

Organosulfates in aerosols downwind of an urban region in central Amazon
Journal Article · Thu Nov 01 00:00:00 EDT 2018 · Environmental Science: Processes & Impacts · OSTI ID:1633049

Natural and Anthropogenically Influenced Isoprene Oxidation in Southeastern United States and Central Amazon
Journal Article · Wed Apr 08 20:00:00 EDT 2020 · Environmental Science and Technology · OSTI ID:1674999

CCN activity and organic hygroscopicity of aerosols downwind of an urban region in central Amazonia: seasonal and diel variations and impact of anthropogenic emissions
Journal Article · Wed Oct 04 20:00:00 EDT 2017 · Atmospheric Chemistry and Physics (Online) · OSTI ID:1459766

Related Subjects