Supramolekulare Metallopolymere: Von linearen Materialien zu infiniten Netzwerken

Bentz, Kyle C.; Cohen, Seth M.

doi:10.1002/ange.201806912

Supramolekulare Metallopolymere: Von linearen Materialien zu infiniten Netzwerken

Journal Article · Wed Oct 24 00:00:00 EDT 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201806912· OSTI ID:1478676

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Department of Chemistry and Biochemistry University of California, San Diego La Jolla California 92093 USA

Abstract

Koordinationspolymere (coordination polymers, CPs) und supramolekulare Metallopolymere (supramolecular metallopolymers, SMPs) sind seit Jahrzehnten Gegenstand ausgiebiger Forschung. Spektakuläre Fortschritte in beiden Feldern haben neue Verbindungen hervorgebracht, die an der Grenze zwischen diesen beiden organisch‐anorganischen Gebieten liegen. An dieser Schnittstelle wurden Materialien entwickelt auf Basis unterschiedlicher Konzepte wie molekularem Flechten, supramolekularen Clustern und Hybriden aus Metall‐organischen Gerüstverbindungen und Polymeren. Dieser Kurzaufsatz gewährt einen Einblick in die intellektuelle Entstehung sowie die Verbindungen zwischen verschiedenen supramolekularen Konstrukten und den Stand der Wissenschaft bezüglich neuer Materialien an dieser Schnittstelle.

View Accepted Manuscript (Publisher)

Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-08ER46519

OSTI ID:: 1478676

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 46 Vol. 130; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (63)

Metallo-Supramolecular Graft Copolymers: A Novel Approach Toward Polymer-Analogous Reactions Schubert, Ulrich S.; Hofmeier, Harald Macromolecular Rapid Communications, Vol. 23, Issue 9 https://doi.org/10.1002/1521-3927(20020601)23:9<561::AID-MARC561>3.0.CO;2-W	journal	June 2002
Retikuläre Chemie metall‐organischer Polyeder Tranchemontagne, David J.; Ni, Zheng; O'Keeffe, Michael Angewandte Chemie, Vol. 120, Issue 28 https://doi.org/10.1002/ange.200705008	journal	June 2008
Automatic Molecular Weaving Prototyped by Using Single-Stranded DNA Ciengshin, Tanashaya; Sha, Ruojie; Seeman, Nadrian C. Angewandte Chemie, Vol. 123, Issue 19 https://doi.org/10.1002/ange.201007685	journal	April 2011
Nano- and Microsized Cubic Gel Particles from Cyclodextrin Metal-Organic Frameworks Furukawa, Yuki; Ishiwata, Takumi; Sugikawa, Kouta Angewandte Chemie, Vol. 124, Issue 42 https://doi.org/10.1002/ange.201204919	journal	September 2012
Perspektiven der Chemie - Aspekte adaptiver Chemie und adaptiver Materialien Lehn, Jean-Marie Angewandte Chemie, Vol. 127, Issue 11 https://doi.org/10.1002/ange.201409399	journal	January 2015
Facile Self-Assembly of Metallo-Supramolecular Ring-in-Ring and Spiderweb Structures Using Multivalent Terpyridine Ligands Fu, Jun-Hao; Lee, Yin-Hsuan; He, Yun-Jui Angewandte Chemie, Vol. 127, Issue 21 https://doi.org/10.1002/ange.201501507	journal	April 2015
polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A. Angewandte Chemie, Vol. 127, Issue 21 https://doi.org/10.1002/ange.201502733	journal	April 2015
Light-Powered Self-Healable Metallosupramolecular Soft Actuators Borré, Etienne; Stumbé, Jean-François; Bellemin-Laponnaz, Stéphane Angewandte Chemie, Vol. 128, Issue 4 https://doi.org/10.1002/ange.201508241	journal	December 2015
Star PolyMOCs with Diverse Structures, Dynamics, and Functions by Three-Component Assembly Wang, Yufeng; Gu, Yuwei; Keeler, Eric G. Angewandte Chemie, Vol. 129, Issue 1 https://doi.org/10.1002/ange.201609261	journal	December 2016
Anisotropically Swelling Gels Attained through Axis-Dependent Crosslinking of MOF Crystals Ishiwata, Takumi; Kokado, Kenta; Sada, Kazuki Angewandte Chemie, Vol. 129, Issue 10 https://doi.org/10.1002/ange.201611338	journal	January 2017
Durch sichtbares Licht und Nahinfrarotstrahlung abbaubare supramolekulare Metallo-Gele Theis, Sabrina; Iturmendi, Aitziber; Gorsche, Christian Angewandte Chemie, Vol. 129, Issue 50 https://doi.org/10.1002/ange.201707321	journal	November 2017
Reticular Chemistry of Metal–Organic Polyhedra Tranchemontagne, David J.; Ni, Zheng; O'Keeffe, Michael Angewandte Chemie International Edition, Vol. 47, Issue 28, p. 5136-5147 https://doi.org/10.1002/anie.200705008	journal	June 2008
Automatic Molecular Weaving Prototyped by Using Single-Stranded DNA Ciengshin, Tanashaya; Sha, Ruojie; Seeman, Nadrian C. Angewandte Chemie International Edition, Vol. 50, Issue 19 https://doi.org/10.1002/anie.201007685	journal	April 2011
Nano- and Microsized Cubic Gel Particles from Cyclodextrin Metal-Organic Frameworks Furukawa, Yuki; Ishiwata, Takumi; Sugikawa, Kouta Angewandte Chemie International Edition, Vol. 51, Issue 42 https://doi.org/10.1002/anie.201204919	journal	September 2012
Perspectives in Chemistry-Aspects of Adaptive Chemistry and Materials Lehn, Jean-Marie Angewandte Chemie International Edition, Vol. 54, Issue 11 https://doi.org/10.1002/anie.201409399	journal	January 2015
Facile Self-Assembly of Metallo-Supramolecular Ring-in-Ring and Spiderweb Structures Using Multivalent Terpyridine Ligands Fu, Jun-Hao; Lee, Yin-Hsuan; He, Yun-Jui Angewandte Chemie International Edition, Vol. 54, Issue 21 https://doi.org/10.1002/anie.201501507	journal	April 2015
polyMOFs: A Class of Interconvertible Polymer-Metal-Organic-Framework Hybrid Materials Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A. Angewandte Chemie International Edition, Vol. 54, Issue 21 https://doi.org/10.1002/anie.201502733	journal	April 2015
Light-Powered Self-Healable Metallosupramolecular Soft Actuators Borré, Etienne; Stumbé, Jean-François; Bellemin-Laponnaz, Stéphane Angewandte Chemie International Edition, Vol. 55, Issue 4 https://doi.org/10.1002/anie.201508241	journal	December 2015
Star PolyMOCs with Diverse Structures, Dynamics, and Functions by Three-Component Assembly Wang, Yufeng; Gu, Yuwei; Keeler, Eric G. Angewandte Chemie International Edition, Vol. 56, Issue 1 https://doi.org/10.1002/anie.201609261	journal	December 2016
Anisotropically Swelling Gels Attained through Axis-Dependent Crosslinking of MOF Crystals Ishiwata, Takumi; Kokado, Kenta; Sada, Kazuki Angewandte Chemie International Edition, Vol. 56, Issue 10 https://doi.org/10.1002/anie.201611338	journal	January 2017
Metallo-Supramolecular Gels that are Photocleavable with Visible and Near-Infrared Irradiation Theis, Sabrina; Iturmendi, Aitziber; Gorsche, Christian Angewandte Chemie International Edition, Vol. 56, Issue 50 https://doi.org/10.1002/anie.201707321	journal	November 2017
Amphiphilic Metallopolymers for Photoswitchable Supramolecular Hydrogels Borré, Etienne; Bellemin-Laponnaz, Stéphane; Mauro, Matteo Chemistry - A European Journal, Vol. 22, Issue 52 https://doi.org/10.1002/chem.201604321	journal	November 2016
Metal-Containing Polymers as Light-Emitting and Light-Responsive Materials and Beyond Mauro, Matteo; Bellemin-Laponnaz, Stéphane; Cebrián, Cristina Chemistry - A European Journal, Vol. 23, Issue 70 https://doi.org/10.1002/chem.201702936	journal	November 2017
Recent Trends in Metallopolymer Design: Redox-Controlled Surfaces, Porous Membranes, and Switchable Optical Materials Using Ferrocene-Containing Polymers Gallei, Markus; Rüttiger, Christian Chemistry - A European Journal, Vol. 24, Issue 40 https://doi.org/10.1002/chem.201800412	journal	May 2018
Zn ^II Bis terpyridine Metallopolymers: Improved Processability by the Introduction of Polymeric Side Chains Wild, Andreas; Teichler, Anke; von der Ehe, Christian Macromolecular Chemistry and Physics, Vol. 214, Issue 10 https://doi.org/10.1002/macp.201300003	journal	April 2013
Modulating metallopolymer mechanical properties by controlling metal ligand crosslinking Vidavsky, Yuval; Bae, Suwon; Silberstein, Meredith N. Journal of Polymer Science Part A: Polymer Chemistry, Vol. 56, Issue 11 https://doi.org/10.1002/pola.28994	journal	March 2018
Self-assembled metal–organic polyhedra: An overview of various applications Vardhan, Harsh; Yusubov, Mekhman; Verpoort, Francis Coordination Chemistry Reviews, Vol. 306 https://doi.org/10.1016/j.ccr.2015.05.016	journal	January 2016
Chemical Topology: Complex Molecular Knots, Links, and Entanglements Forgan, Ross S.; Sauvage, Jean-Pierre; Stoddart, J. Fraser Chemical Reviews, Vol. 111, Issue 9 https://doi.org/10.1021/cr200034u	journal	September 2011
Metal–Organic Frameworks for Separations Li, Jian-Rong; Sculley, Julian; Zhou, Hong-Cai Chemical Reviews, Vol. 112, Issue 2, p. 869-932 https://doi.org/10.1021/cr200190s	journal	September 2011
Metal–Organic Frameworks and Self-Assembled Supramolecular Coordination Complexes: Comparing and Contrasting the Design, Synthesis, and Functionality of Metal–Organic Materials Cook, Timothy R.; Zheng, Yao-Rong; Stang, Peter J. Chemical Reviews, Vol. 113, Issue 1 https://doi.org/10.1021/cr3002824	journal	November 2012
Supramolecular Polymers: Historical Development, Preparation, Characterization, and Functions Yang, Liulin; Tan, Xinxin; Wang, Zhiqiang Chemical Reviews, Vol. 115, Issue 15 https://doi.org/10.1021/cr500633b	journal	March 2015
Photophysics and Redox Behavior of Chiral Transition Metal Polymers Barron, Jason A.; Glazier, Samantha; Bernhard, Stefan Inorganic Chemistry, Vol. 42, Issue 5 https://doi.org/10.1021/ic020691v	journal	March 2003
Enantiomerically Pure Chiral Coordination Polymers: Synthesis, Spectroscopy, and Electrochemistry in Solution and on Surfaces Bernhard, Stefan; Takada, Kazutake; Díaz, Diego J. Journal of the American Chemical Society, Vol. 123, Issue 42 https://doi.org/10.1021/ja011020j	journal	October 2001
Multistimuli, Multiresponsive Metallo-Supramolecular Polymers Beck, J. Benjamin; Rowan, Stuart J. Journal of the American Chemical Society, Vol. 125, Issue 46 https://doi.org/10.1021/ja038521k	journal	November 2003
Understanding the Mechanism of Gelation and Stimuli-Responsive Nature of a Class of Metallo-Supramolecular Gels Weng, Wengui; Beck, J. Benjamin; Jamieson, Alex M. Journal of the American Chemical Society, Vol. 128, Issue 35 https://doi.org/10.1021/ja063408q	journal	September 2006
Thermo-, Photo-, and Chemo-Responsive Shape-Memory Properties from Photo-Cross-Linked Metallo-Supramolecular Polymers Kumpfer, Justin R.; Rowan, Stuart J. Journal of the American Chemical Society, Vol. 133, Issue 32 https://doi.org/10.1021/ja205332w	journal	August 2011
Aqueous Self-Assembly of an Electroluminescent Double-Helical Metallopolymer de Hatten, Xavier; Asil, Demet; Friend, Richard H. Journal of the American Chemical Society, Vol. 134, Issue 46 https://doi.org/10.1021/ja308055s	journal	November 2012
Transformation of Metal–Organic Framework to Polymer Gel by Cross-Linking the Organic Ligands Preorganized in Metal–Organic Framework Ishiwata, Takumi; Furukawa, Yuki; Sugikawa, Kouta Journal of the American Chemical Society, Vol. 135, Issue 14 https://doi.org/10.1021/ja3125614	journal	March 2013
Mechanochemistry with Metallosupramolecular Polymers Balkenende, Diederik W. R.; Coulibaly, Souleymane; Balog, Sandor Journal of the American Chemical Society, Vol. 136, Issue 29 https://doi.org/10.1021/ja5051633	journal	July 2014
Differentially Addressable Cavities within Metal–Organic Cage-Cross-Linked Polymeric Hydrogels Foster, Jonathan A.; Parker, Richard M.; Belenguer, Ana M. Journal of the American Chemical Society, Vol. 137, Issue 30 https://doi.org/10.1021/jacs.5b05507	journal	July 2015
Covalent Chemistry beyond Molecules Jiang, Juncong; Zhao, Yingbo; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.5b10666	journal	February 2016
Polymer–Metal–Organic Frameworks (polyMOFs) as Water Tolerant Materials for Selective Carbon Dioxide Separations Zhang, Zhenjie; Nguyen, Ha Thi Hoang; Miller, Stephen A. Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b11034	journal	January 2016
Metal/Ligand-Induced Formation of Metallo-Supramolecular Polymers Beck, J. Benjamin; Ineman, Jennifer M.; Rowan, Stuart J. Macromolecules, Vol. 38, Issue 12 https://doi.org/10.1021/ma050369e	journal	June 2005
Optically healable supramolecular polymers Burnworth, Mark; Tang, Liming; Kumpfer, Justin R. Nature, Vol. 472, Issue 7343, p. 334-337 https://doi.org/10.1038/nature09963	journal	April 2011
Highly branched and loop-rich gels via formation of metal–organic cages linked by polymers Zhukhovitskiy, Aleksandr V.; Zhong, Mingjiang; Keeler, Eric G. Nature Chemistry, Vol. 8, Issue 1 https://doi.org/10.1038/nchem.2390	journal	November 2015
Molecular weaving via surface-templated epitaxy of crystalline coordination networks. Wang, Zhengbang; Błaszczyk, Alfred; Fuhr, Olaf Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14442	journal	February 2017
Photoswitching topology in polymer networks with metal–organic cages as crosslinks Gu, Yuwei; Alt, Eric A.; Wang, Heng Nature, Vol. 560, Issue 7716 https://doi.org/10.1038/s41586-018-0339-0	journal	July 2018
Metal–ligand induced supramolecular polymerization: A route to responsive materials Rowan, Stuart J.; Beck, J. Benjamin Faraday Discuss., Vol. 128 https://doi.org/10.1039/B403135K	journal	January 2005
2,2′:6′,2″-Terpyridines: From chemical obscurity to common supramolecular motifs Constable, Edwin C. Chem. Soc. Rev., Vol. 36, Issue 2 https://doi.org/10.1039/B601166G	journal	January 2007
Multi-responsive coordination polymers utilising metal-stabilised, dynamic covalent imine bonds García, Fátima; Pelss, Janis; Zuilhof, Han Chemical Communications, Vol. 52, Issue 58 https://doi.org/10.1039/C6CC00500D	journal	January 2016
Hierarchical structure and porosity in UiO-66 polyMOFs Ayala, Sergio; Zhang, Zhenjie; Cohen, Seth M. Chemical Communications, Vol. 53, Issue 21 https://doi.org/10.1039/C6CC10225E	journal	January 2017
Synthesis and characterization of metallo-supramolecular polymers Winter, Andreas; Schubert, Ulrich S. Chemical Society Reviews, Vol. 45, Issue 19 https://doi.org/10.1039/C6CS00182C	journal	January 2016
Control of the light-response in supramolecular metallopolymeric gels by tuning the coordination metal Borré, Etienne; Stumbé, Jean-François; Bellemin-Laponnaz, Stéphane Chemical Communications, Vol. 53, Issue 59 https://doi.org/10.1039/C7CC03516K	journal	January 2017
Isoreticular expansion of polyMOFs achieves high surface area materials Schukraft, Giulia E. M.; Ayala, Sergio; Dick, Benjamin L. Chemical Communications, Vol. 53, Issue 77 https://doi.org/10.1039/C7CC04222A	journal	January 2017
Box-like gel capsules from heterostructures based on a core–shell MOF as a template of crystal crosslinking Ishiwata, Takumi; Michibata, Ayano; Kokado, Kenta Chemical Communications, Vol. 54, Issue 12 https://doi.org/10.1039/C7CC07158B	journal	January 2018
Block co-polyMOFs: assembly of polymer–polyMOF hybrids via iterative exponential growth and “click” chemistry MacLeod, M. J.; Johnson, J. A. Polymer Chemistry, Vol. 8, Issue 31 https://doi.org/10.1039/C7PY00922D	journal	January 2017
Synthesis and optical properties of metallo-supramolecular polymers Iyer, Parameswar K.; Beck, J. Benjamin; Weder, Christoph Chemical Communications, Issue 3 https://doi.org/10.1039/b410734a	journal	January 2005
MOF@MOF: microporous core–shell architectures Koh, Kyoungmoo; Wong-Foy, Antek G.; Matzger, Adam J. Chemical Communications, Issue 41 https://doi.org/10.1039/b904526k	journal	January 2009
Stimuli-responsive supramolecular polymeric materials Yan, Xuzhou; Wang, Feng; Zheng, Bo Chemical Society Reviews, Vol. 41, Issue 18 https://doi.org/10.1039/c2cs35091b	journal	January 2012
Self-healing metallopolymers based on cadmium bis(terpyridine) complex containing polymer networks Bode, S.; Bose, R. K.; Matthes, S. Polymer Chemistry, Vol. 4, Issue 18 https://doi.org/10.1039/c3py00288h	journal	January 2013
First synthesis of soluble, well defined coordination polymers from kinetically unstable copper(I) complexes Velten, Ulf; Rehahn, Matthias Chemical Communications, Issue 23 https://doi.org/10.1039/cc9960002639	journal	January 1996
Weaving of organic threads into a crystalline covalent organic framework Liu, Y.; Ma, Y.; Zhao, Y. Science, Vol. 351, Issue 6271 https://doi.org/10.1126/science.aad4011	journal	January 2016
Poly[ n ]catenanes: Synthesis of molecular interlocked chains Wu, Qiong; Rauscher, Phillip M.; Lang, Xiaolong Science, Vol. 358, Issue 6369 https://doi.org/10.1126/science.aap7675	journal	November 2017

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