A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO 2

Duyar, Melis S.; Tsai, Charlie; Snider, Jonathan L.; Singh, Joseph A.; Gallo, Alessandro; Yoo, Jong Suk; Medford, Andrew J.; Abild‐Pedersen, Frank; Studt, Felix; Kibsgaard, Jakob; Bent, Stacey F.; Nørskov, Jens K.; Jaramillo, Thomas F.

doi:10.1002/ange.201806583

Title: A Highly Active Molybdenum Phosphide Catalyst for Methanol Synthesis from CO and CO ₂

Journal Article · Thu Oct 18 00:00:00 EDT 2018 · Angewandte Chemie

DOI:https://doi.org/10.1002/ange.201806583· OSTI ID:1478125

^[1];

^[1]; Snider, Jonathan L. ^[1]; Singh, Joseph A. ^[1]; Gallo, Alessandro ^[1]; Yoo, Jong Suk ^[1]; Medford, Andrew J. ^[1];

^[1]; Studt, Felix ^[1];

^[1]; Bent, Stacey F. ^[1]; Nørskov, Jens K. ^[1];

^[1]

SUNCAT Center for Interface Science and Catalysis Stanford University Stanford CA 94305 USA, SLAC National Accelerator Laboratory Menlo Park CA 94025 USA

Abstract Methanol is a major fuel and chemical feedstock currently produced from syngas, a CO/CO ₂ /H ₂ mixture. Herein we identify formate binding strength as a key parameter limiting the activity and stability of known catalysts for methanol synthesis in the presence of CO ₂ . We present a molybdenum phosphide catalyst for CO and CO ₂ reduction to methanol, which through a weaker interaction with formate, can improve the activity and stability of methanol synthesis catalysts in a wide range of CO/CO ₂ /H ₂ feeds.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DEAC02-76SF00515

OSTI ID:: 1478125

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 130 Journal Issue: 46; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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