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Unimolecular decomposition kinetics of the stabilised Criegee intermediates CH 2 OO and CD 2 OO

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI:https://doi.org/10.1039/C8CP05332D· OSTI ID:1477897
 [1];  [2];  [1];  [1];  [1];  [1];  [2];  [2]
  1. School of Chemistry, University of Leeds, Leeds, UK
  2. Combustion Research Facility, Sandia National Laboratories, Livermore, USA
+ Show Author Affiliations

Decomposition kinetics of stabilised CH 2 OO and CD 2 OO Criegee intermediates have been investigated as a function of temperature (450–650 K) and pressure (2–350 Torr) using flash photolysis coupled with time-resolved cavity-enhanced broadband UV absorption spectroscopy.

Research Organization:
Sandia National Laboratories (SNL-CA), Livermore, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1477897
Alternate ID(s):
OSTI ID: 1471779
OSTI ID: 1474125
Report Number(s):
SAND--2018-8055J
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 38 Vol. 20; ISSN 1463-9076; ISSN PPCPFQ
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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