Interdiffusion at Room Temperature in Cu-Ni(Fe) Nanolaminates

Jankowski, Alan

doi:10.3390/coatings8060225

Interdiffusion at Room Temperature in Cu-Ni(Fe) Nanolaminates

Journal Article · Wed Jun 20 00:00:00 EDT 2018 · Coatings

DOI:https://doi.org/10.3390/coatings8060225· OSTI ID:1477876

Jankowski, Alan ^[1]

Sandia National Lab. (SNL-CA), Livermore, CA (United States). Materials Sciences—Energy Nanomaterials

The decomposition of a one-dimensional composition wave in Cu-Ni(Fe) nanolaminate structures is quantified using X-ray diffraction to assess kinetics of the interdiffusion process for samples aged at room temperature for 30 years. Definitive evidence for growth to the composition modulation within the chemical spinodal is found through measurement of a negative interdiffusivity for each of sixteen different nanolaminate samples over a composition wavelength range of 2.1–10.6 nm. A diffusivity value D of 1.77 × 10^-24 cm²·s^-1 is determined for the Cu-Ni(Fe) alloy system, perhaps the first such measurement at a ratio of melt temperature to test temperature that is greater than 5. The anomalously high diffusivity value with respect to bulk diffusion is attributed to the nanolaminate structure that features paths for short-circuit diffusion through interlayer grain boundaries.

View Accepted Manuscript (DOE)

Research Organization:: Sandia National Lab. (SNL-CA), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003525

OSTI ID:: 1477876

Report Number(s):: SAND--2017-10068J; 657116

Journal Information:: Coatings, Journal Name: Coatings Journal Issue: 6 Vol. 8; ISSN 2079-6412

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

References (43)

Nanoscale volume diffusion: Diffusion in thin films, multilayers and nanoobjects (hollow nanoparticles) Erdélyi, Zoltán; Beke, Dezső L. Journal of Materials Science, Vol. 46, Issue 20 https://doi.org/10.1007/s10853-011-5720-4	journal	October 2011
A solid-solution model for inhomogeneous systems Hillert, M. Acta Metallurgica, Vol. 9, Issue 6 https://doi.org/10.1016/0001-6160(61)90155-9	journal	June 1961
Nonlinear diffusion Tsakalakos, T. Scripta Metallurgica, Vol. 20, Issue 4 https://doi.org/10.1016/0036-9748(86)90238-3	journal	April 1986
Concentration wave approach in structural and thermodynamic characterization of ceramic crystals Khachaturyan, A. G.; Pokrovskii, B. I. Progress in Materials Science, Vol. 29, Issue 1-2 https://doi.org/10.1016/0079-6425(85)90008-8	journal	January 1985
Experimental evidence for anomalous grain boundary diffusion of Fe in Cu and Cu-Fe alloys Prokoshkina, Daria; Esin, Vladimir A.; Divinski, Sergiy V. Acta Materialia, Vol. 133 https://doi.org/10.1016/j.actamat.2017.05.024	journal	July 2017
Observation of Giant Diffusivity Along Dislocation Cores Legros, M.; Dehm, G.; Arzt, E. Science, Vol. 319, Issue 5870 https://doi.org/10.1126/science.1151771	journal	March 2008
Strain Energy Effects in the Spinodal Decomposition of Cu-Ni(Fe) Nanolaminate Coatings Jankowski, Alan Coatings, Vol. 5, Issue 3 https://doi.org/10.3390/coatings5030246	journal	June 2015
On measurements of self-diffusion rates along dislocations in F.C.C. Metals Balluffi, R. W. physica status solidi (b), Vol. 42, Issue 1 https://doi.org/10.1002/pssb.19700420102	journal	January 1970
Phase stability by the artificial concentration wave method Jankowski, A. F.; Tsakalakos, T. Metallurgical Transactions A, Vol. 20, Issue 3 https://doi.org/10.1007/BF02653914	journal	March 1989
Melting Point Depression and Fast Diffusion in Nanostructured Brazing Fillers Confined Between Barrier Nanolayers Kaptay, G.; Janczak-Rusch, J.; Jeurgens, L. P. H. Journal of Materials Engineering and Performance, Vol. 25, Issue 8 https://doi.org/10.1007/s11665-016-2123-3	journal	May 2016
On spinodal decomposition Cahn, John W. Acta Metallurgica, Vol. 9, Issue 9 https://doi.org/10.1016/0001-6160(61)90182-1	journal	September 1961
On spinodal decomposition in cubic crystals Cahn, John W. Acta Metallurgica, Vol. 10, Issue 3 https://doi.org/10.1016/0001-6160(62)90114-1	journal	March 1962
Coherent fluctuations and nucleation in isotropic solids Cahn, John W. Acta Metallurgica, Vol. 10, Issue 10 https://doi.org/10.1016/0001-6160(62)90140-2	journal	October 1962
A model for diffusion on cubic lattices and its application to the early stages of ordering Cook, H. E.; De Fontaine, D.; Hilliard, J. e. Acta Metallurgica, Vol. 17, Issue 6 https://doi.org/10.1016/0001-6160(69)90083-2	journal	June 1969
On the elastic free energy of solid solutions—I. Microscopic theory Cook, H. E.; de Fontaine, D. Acta Metallurgica, Vol. 17, Issue 7 https://doi.org/10.1016/0001-6160(69)90112-6	journal	July 1969
Structure and properties of spinodally decomposed Cu-Ni-Fe alloys Butler, E. P.; Thomas, G. Acta Metallurgica, Vol. 18, Issue 3 https://doi.org/10.1016/0001-6160(70)90150-1	journal	March 1970
Diffusion induced grain boundary migration and recrystallization in the CuNi system den Broeder, F. J. A.; Nakahara, S. Scripta Metallurgica, Vol. 17, Issue 3 https://doi.org/10.1016/0036-9748(83)90181-3	journal	March 1983
Composition-modulated films: New materials for studying stability and critical phenomena in solid solutions Tsakalakos, T. Thin Solid Films, Vol. 86, Issue 1 https://doi.org/10.1016/0040-6090(81)90161-9	journal	November 1981
Grain size dependence on layer thickness in composition modulated thin films Jankowski, A. F.; Shewbridge, J. F. Materials Letters, Vol. 4, Issue 5-7 https://doi.org/10.1016/0167-577X(86)90032-7	journal	July 1986
Investigation of the interplay of nickel dissolution and copper segregation in Ni/Cu() system Erdélyi, Z.; Girardeaux, Ch.; Tôkei, Zs. Surface Science, Vol. 496, Issue 1-2 https://doi.org/10.1016/S0039-6028(01)01571-0	journal	January 2002
Grain boundary diffusion and segregation of Ni in Cu Divinski, Sergiy; Ribbe, Jens; Schmitz, Guido Acta Materialia, Vol. 55, Issue 10 https://doi.org/10.1016/j.actamat.2007.01.032	journal	June 2007
Interfacial diffusion in Cu with a gradient nanostructured surface layer Wang, Z. B.; Lu, K.; Wilde, G. Acta Materialia, Vol. 58, Issue 7 https://doi.org/10.1016/j.actamat.2009.12.024	journal	April 2010
Grain boundary width, energy and self-diffusion in nickel: Effect of material purity Prokoshkina, D.; Esin, V. A.; Wilde, G. Acta Materialia, Vol. 61, Issue 14 https://doi.org/10.1016/j.actamat.2013.05.010	journal	August 2013
Nanolaminated FeCoB/FeCo and FeCoB/NiFe soft magnetic thin films with tailored magnetic properties deposited by magnetron sputtering Hida, Rachid; Falub, Claudiu V.; Perraudeau, Sandrine Journal of Magnetism and Magnetic Materials, Vol. 453 https://doi.org/10.1016/j.jmmm.2018.01.022	journal	May 2018
The thermal stability of nanocrystalline Au–Cu alloys Jankowski, Alan F.; Saw, Cheng K.; Hayes, Jeffrey P. Thin Solid Films, Vol. 515, Issue 3 https://doi.org/10.1016/j.tsf.2006.07.167	journal	November 2006
Synthesis and Properties of 2D Carbon—Graphdiyne Jia, Zhiyu; Li, Yongjun; Zuo, Zicheng Accounts of Chemical Research, Vol. 50, Issue 10 https://doi.org/10.1021/acs.accounts.7b00205	journal	September 2017
Dislocation-pipe diffusion in nitride superlattices observed in direct atomic resolution Garbrecht, Magnus; Saha, Bivas; Schroeder, Jeremy L. Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/srep46092	journal	April 2017
Influence of dislocations on diffusion kinetics in solids with particular reference to the alkali halides Harrison, L. G. Transactions of the Faraday Society, Vol. 57 https://doi.org/10.1039/tf9615701191	journal	January 1961
Free Energy of a Nonuniform System. I. Interfacial Free Energy Cahn, John W.; Hilliard, John E. The Journal of Chemical Physics, Vol. 28, Issue 2 https://doi.org/10.1063/1.1744102	journal	February 1958
Interdiffusion in composition‐modulated copper‐gold thin films Paulson, Wayne M.; Hilliard, John E. Journal of Applied Physics, Vol. 48, Issue 6 https://doi.org/10.1063/1.324027	journal	June 1977
Effect of long‐range interaction on diffusion in copper‐nickel composition‐modulated alloys Tsakalakos, T.; Hilliard, J. E. Journal of Applied Physics, Vol. 55, Issue 8 https://doi.org/10.1063/1.333328	journal	April 1984
Grain boundary and triple junction diffusion in nanocrystalline copper Wegner, M.; Leuthold, J.; Peterlechner, M. Journal of Applied Physics, Vol. 116, Issue 9 https://doi.org/10.1063/1.4893960	journal	September 2014
Alloy decomposition in Cu-Ni-Fe. I. Equilibrium states and kinetics of homophase fluctuations Poerschke, R.; Wagner, W.; Wollenberger, H. Journal of Physics F: Metal Physics, Vol. 16, Issue 4 https://doi.org/10.1088/0305-4608/16/4/007	journal	April 1986
Alloy decomposition in Cu-Ni-Fe. III. Influence of electron irradiation on decomposition kinetics and morphology Wagner, W.; Poerschke, R.; Wollenberger, H. Journal of Physics F: Metal Physics, Vol. 17, Issue 10 https://doi.org/10.1088/0305-4608/17/10/010	journal	October 1987
Nonlinear relaxation dynamics in decomposing alloys: One-dimensional Cahn-Hilliard model Fraerman, A. A.; Mel'nikov, A. S.; Nefedov, I. M. Physical Review B, Vol. 55, Issue 10 https://doi.org/10.1103/PhysRevB.55.6316	journal	March 1997
Observation and Origin of Extraordinary Atomic Mobility at Metal-Semiconductor Interfaces at Low Temperatures Wang, Zumin; Jeurgens, Lars P. H.; Sigle, Wilfried Physical Review Letters, Vol. 115, Issue 1 https://doi.org/10.1103/PhysRevLett.115.016102	journal	July 2015
Bone-like crack resistance in hierarchical metastable nanolaminate steels Koyama, Motomichi; Zhang, Zhao; Wang, Meimei Science, Vol. 355, Issue 6329 https://doi.org/10.1126/science.aal2766	journal	March 2017
Mössbauer study of the process of the room-temperature aging of the alloy Cu79Ni14Fe7 Pyataev, A. V.; Manapov, R. A. The Physics of Metals and Metallography, Vol. 111, Issue 1 https://doi.org/10.1134/S0031918X11010108	journal	January 2011
Applications of Spinodal Alloys Ditchek, B.; Schwartz, L. H. Annual Review of Materials Science, Vol. 9, Issue 1 https://doi.org/10.1146/annurev.ms.09.080179.001251	journal	August 1979
Two-Dimensional (2D) Nanomaterials towards Electrochemical Nanoarchitectonics in Energy-Related Applications Khan, Ali Hossain; Ghosh, Srabanti; Pradhan, Bapi Bulletin of the Chemical Society of Japan, Vol. 90, Issue 6 https://doi.org/10.1246/bcsj.20170043	journal	June 2017
Coarsening of Extremely Small Particles in the Cu-Ni-Fe System Gust, W.; Wachtel, E.; FrüHauf, B. MRS Proceedings, Vol. 21 https://doi.org/10.1557/PROC-21-461	journal	January 1982
Diffusion of Ni⁶³ and Cr⁵¹ in Nickel-Chromium Alloys (On the Relation between High-Temperature Creep and Diffusion in Nickel Base Solid Solutions. I) [Ni-Cr合金中のNi⁶³およびCr⁵¹の拡散] Monma, Kaizo; Suto, Hajime; Oikawa, Hiroshi Journal of the Japan Institute of Metals, Vol. 28, Issue 4 https://doi.org/10.2320/jinstmet1952.28.4_188	journal	January 1964
Grain Boundary Diffusion of Fe in High-Purity Copper Ribbe, Jens; Schmitz, Guido; Divinski, Sergiy V. Defect and Diffusion Forum, Vol. 289-292 https://doi.org/10.4028/www.scientific.net/DDF.289-292.211	journal	April 2009

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36 MATERIALS SCIENCE
Cu-Ni(Fe)
interdiffusion
nanolaminate
spinodal

Interdiffusion at Room Temperature in Cu-Ni(Fe) Nanolaminates

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