Molecular Weaving of Covalent Organic Frameworks for Adaptive Guest Inclusion

Liu, Yuzhong; Ma, Yanhang; Yang, Jingjing; Diercks, Christian S.; Tamura, Nobumichi; Jin, Fangying; Yaghi, Omar M.

doi:10.1021/jacs.8b08949

Title: Molecular Weaving of Covalent Organic Frameworks for Adaptive Guest Inclusion

Journal Article · Mon Oct 01 00:00:00 EDT 2018 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.8b08949· OSTI ID:1477401

^[1]; Ma, Yanhang ^[2];

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^[1]; Tamura, Nobumichi ^[1]; Jin, Fangying ^[1];

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Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Shanghai Tech Univ. (China)

The synthesis of new isoreticular non-interpenetrated woven covalent organic frameworks (COFs) was achieved by linking aldehyde-functionalized copper(I) bisphenanthroline complexes with benzidine linkers in the presence of a bulky anion, diphenylphosphinate (PO₂Ph₂-) to give metalated COF-506-Cu and, upon removal of copper(I), the demetalated COF-506. The structures ofthese COFs were determined by a combination of powder X-ray diffraction and electron microscopy techniques. Guest-accessibility to the pores of the two frameworks was examined by vapor and dye inclusion studies and compared to the already reported doubly-interpenetrated COF-505-Cu. Remarkably, COF-506 was found to take up guest molecules that exceed the size of the COF-506-Cu pores, thus giving credence to the notion of a novel mode of motional dynamics in solids we term 'adaptive inclusion'.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1477401

Journal Information:: Journal of the American Chemical Society, Vol. 140, Issue 47; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 63 works

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Construction of Covalent‐Organic Frameworks (COFs) from Amorphous Covalent Organic Polymers via Linkage Replacement Zhai, Yufeng; Liu, Guiyan; Jin, Fenchun Angewandte Chemie, Vol. 131, Issue 49 https://doi.org/10.1002/ange.201911231	journal	October 2019
Structural Basis of CO2 Adsorption in a Flexible Metal-Organic Framework Material Allen, Andrew; Wong-Ng, Winnie; Cockayne, Eric Nanomaterials, Vol. 9, Issue 3 https://doi.org/10.3390/nano9030354	journal	March 2019
Divergent Chemistry Paths for 3D and 1D Metallo‐Covalent Organic Frameworks (COFs) Xu, Hai‐Sen; Luo, Yi; See, Pei Zhen Angewandte Chemie International Edition, Vol. 59, Issue 28 https://doi.org/10.1002/anie.202002724	journal	April 2020
Construction of Covalent‐Organic Frameworks (COFs) from Amorphous Covalent Organic Polymers via Linkage Replacement Zhai, Yufeng; Liu, Guiyan; Jin, Fenchun Angewandte Chemie International Edition, Vol. 58, Issue 49 https://doi.org/10.1002/anie.201911231	journal	December 2019
Divergent Chemistry Paths for 3D and 1D Metallo‐Covalent Organic Frameworks (COFs) Xu, Hai‐Sen; Luo, Yi; See, Pei Zhen Angewandte Chemie, Vol. 132, Issue 28 https://doi.org/10.1002/ange.202002724	journal	April 2020

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