Investigation of a Spin Transition in a LaCoO3 Single Crystal by the Method of X-Ray Magnetic Circular Dichroism at the Cobalt K- and L2,3-Edges

Sikolenko, Vadim V.; Troyanchuk, I. O.; Karpinsky, D. V.; Rogalev, A.; Wilhelm, F.; Rosenberg, R.; Prabhakaran, D.; Efimova, E. A.; Efimov, V. V.; Tiutiunnikov, S. I.; Bobrikov, I. A.

doi:10.1134/S1063783418020270

Title: Investigation of a Spin Transition in a LaCoO₃ Single Crystal by the Method of X-Ray Magnetic Circular Dichroism at the Cobalt K- and L_2,3-Edges

Journal Article · Thu Mar 01 00:00:00 EST 2018 · Physics of the Solid State

DOI:https://doi.org/10.1134/S1063783418020270· OSTI ID:1477189

Sikolenko, Vadim V. ^[1]; Troyanchuk, I. O. ^[2]; Karpinsky, D. V. ^[2]; Rogalev, A. ^[3]; Wilhelm, F. ^[3]; Rosenberg, R. ^[4]; Prabhakaran, D. ^[5]; Efimova, E. A. ^[6]; Efimov, V. V. ^[6]; Tiutiunnikov, S. I. ^[6]; Bobrikov, I. A. ^[6]

Joint Institute for Nuclear Research, Moscow oblast (Russia); Immanuel Kant Baltic Federal Univ., Kaliningrad (Russia)
National Academy of Sciences of Belarus, Minsk (Belarus)
European Synchrotron Radiation Facility (ESRF), Grenoble Cedex (France)
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Univ. of Oxford, Oxford (United Kingdom)
Joint Institute for Nuclear Research, Moscow oblast (Russia)

Here, the spin transitions of cobalt ions in LaCoO₃ single crystals have been studied by the method of X-ray magnetic circular dichroism (XMCD) at the K- and L_2,3-edges of Co³⁺ ions. The orbital momentum of cobalt ions obtained for the K-edge at the 3d level in the region of the spin transition in the temperature range from 25 to 120 K increases by a factor of approximately 1.6, whereas the slope of the magnetization curve value in the same temperature range and magnetic field increases by a factor of more than 10. XMCD experiments at the cobalt L_2,3)-edges demonstrate gradual growth of the ratio of the orbital momentum to the spin one L/S from 0.48 to 0.53 in the temperature range from 60 K to 120 K.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: Russian Foundation for Basic Research; Joint Institute for Nuclear Research (JINR); USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1477189

Journal Information:: Physics of the Solid State, Vol. 60, Issue 2; ISSN 1063-7834

Publisher:: Springer NatureCopyright Statement

Country of Publication:: United States

Language:: English

References (23)

Temperature- and pressure-induced spin-state transitions in ${LaCoO}_{3}$ Vankó, György; Rueff, Jean-Pascal; Mattila, Aleksi Physical Review B, Vol. 73, Issue 2 https://doi.org/10.1103/PhysRevB.73.024424	journal	January 2006
Reversible strain effect on the magnetization of ${LaCoO}_{3}$ films Herklotz, A.; Rata, A. D.; Schultz, L. Physical Review B, Vol. 79, Issue 9 https://doi.org/10.1103/PhysRevB.79.092409	journal	March 2009
Local electronic structure and magnetic properties of $La {Mn}_{0.5} {Co}_{0.5} O_{3}$ studied by x-ray absorption and magnetic circular dichroism spectroscopy Burnus, T.; Hu, Z.; Hsieh, H. H. Physical Review B, Vol. 77, Issue 12 https://doi.org/10.1103/PhysRevB.77.125124	journal	March 2008
The ferromagnetic and antiferromagnetic phases in anion deficient La _0.5 ₋ _x Pr _x Ba _0.5 CoO ₃ ₋ _δ cobaltites Troyanchuk, I. O.; Karpinsky, D. V.; Bushinsky, M. V. Journal of Applied Physics, Vol. 112, Issue 1 https://doi.org/10.1063/1.4733953	journal	July 2012
Tuning the magnetic properties of $La Co O_{3}$ thin films by epitaxial strain Fuchs, D.; Arac, E.; Pinta, C. Physical Review B, Vol. 77, Issue 1 https://doi.org/10.1103/PhysRevB.77.014434	journal	January 2008
Evidence for the excited triplet of ${Co}^{3 +}$ in ${LaCoO}_{3}$ Noguchi, S.; Kawamata, S.; Okuda, K. Physical Review B, Vol. 66, Issue 9 https://doi.org/10.1103/PhysRevB.66.094404	journal	September 2002
Possible surface antiferromagnetism and no evidence for intergranular tunneling magnetoresistance in La _0.5 Sr _0.5 CoO _3–δ cobaltites Troyanchuk, I. O.; Bushinsky, M. V.; Lobanovsky, L. S. Journal of Applied Physics, Vol. 114, Issue 21 https://doi.org/10.1063/1.4838155	journal	December 2013
An interpretation of the magnetic properties of the perovskite-type mixed crystals La1−xSrxCoO3−λ Goodenough, John B. Journal of Physics and Chemistry of Solids, Vol. 6, Issue 2-3 https://doi.org/10.1016/0022-3697(58)90107-0	journal	August 1958
Direct Measurement of the Low-Temperature Spin-State Transition in ${LaCoO}_{3}$ Klie, R. F.; Zheng, J. C.; Zhu, Y. Physical Review Letters, Vol. 99, Issue 4 https://doi.org/10.1103/PhysRevLett.99.047203	journal	July 2007
Spin State Transition in ${LaCoO}_{3}$ Studied Using Soft X-ray Absorption Spectroscopy and Magnetic Circular Dichroism Haverkort, M. W.; Hu, Z.; Cezar, J. C. Physical Review Letters, Vol. 97, Issue 17 https://doi.org/10.1103/PhysRevLett.97.176405	journal	October 2006
Evidence for a low-spin to intermediate-spin state transition in ${LaCoO}_{3}$ Zobel, C.; Kriener, M.; Bruns, D. Physical Review B, Vol. 66, Issue 2 https://doi.org/10.1103/PhysRevB.66.020402	journal	June 2002
Effect of Coulomb Interaction on the X-Ray Magnetic Circular Dichroism Spin Sum Rule in 3 d Transition Elements Teramura, Yoshiki; Tanaka, Arata; Jo, Takeo Journal of the Physical Society of Japan, Vol. 65, Issue 4 https://doi.org/10.1143/JPSJ.65.1053	journal	April 1996
Evidence for orbital ordering in ${LaCoO}_{3}$ Maris, G.; Ren, Y.; Volotchaev, V. Physical Review B, Vol. 67, Issue 22 https://doi.org/10.1103/PhysRevB.67.224423	journal	June 2003
Ferromagnetism in $La Co O_{3}$ Yan, J. -Q.; Zhou, J. -S.; Goodenough, J. B. Physical Review B, Vol. 70, Issue 1 https://doi.org/10.1103/PhysRevB.70.014402	journal	July 2004
First-Order Localized-Electron $⇆$ Collective-Electron Transition in LaCo $O_{3}$ Raccah, P. M.; Goodenough, J. B. Physical Review, Vol. 155, Issue 3 https://doi.org/10.1103/PhysRev.155.932	journal	March 1967
Spin transition in LaCoO ₃ investigated by resonant soft X-ray emission spectroscopy Magnuson, M.; Butorin, S. M.; Såthe, C. Europhysics Letters (EPL), Vol. 68, Issue 2 https://doi.org/10.1209/epl/i2004-10183-8	journal	October 2004
Spin-State Transition in ${LaCoO}_{3}$ : Direct Neutron Spectroscopic Evidence of Excited Magnetic States Podlesnyak, A.; Streule, S.; Mesot, J. Physical Review Letters, Vol. 97, Issue 24 https://doi.org/10.1103/PhysRevLett.97.247208	journal	December 2006
X-ray circular dichroism as a probe of orbital magnetization Thole, B. T.; Carra, P.; Sette, F. Physical Review Letters, Vol. 68, Issue 12 https://doi.org/10.1103/PhysRevLett.68.1943	journal	March 1992
Pressure induced antiferromagnet-ferromagnet transition in La0.5Ba0.5CoO2.8 cobaltite Troyanchuk, I. O.; Bushinsky, M. V.; Sikolenko, V. The European Physical Journal B, Vol. 86, Issue 10 https://doi.org/10.1140/epjb/e2013-40617-x	journal	October 2013
Structural phenomena associated with the spin-state transition in ${LaCoO}_{3}$ Radaelli, P. G.; Cheong, S. -W. Physical Review B, Vol. 66, Issue 9 https://doi.org/10.1103/PhysRevB.66.094408	journal	September 2002
Intermediate-spin state and properties of ${LaCoO}_{3}$ Korotin, M. A.; Ezhov, S. Yu.; Solovyev, I. V. Physical Review B, Vol. 54, Issue 8 https://doi.org/10.1103/PhysRevB.54.5309	journal	August 1996
Two Spin-State Transitions in LaCoO ₃ Asai, Kichizo; Yoneda, Atsuro; Yokokura, Osamu Journal of the Physical Society of Japan, Vol. 67, Issue 1 https://doi.org/10.1143/JPSJ.67.290	journal	January 1998
Bulk single crystal growth and magnetic studies of La1−xSrxCoO3+δ Prabhakaran, D.; Boothroyd, A. T.; Wondre, F. R. Journal of Crystal Growth, Vol. 275, Issue 1-2 https://doi.org/10.1016/j.jcrysgro.2004.11.120	journal	February 2005

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Title: Investigation of a Spin Transition in a LaCoO3 Single Crystal by the Method of X-Ray Magnetic Circular Dichroism at the Cobalt K- and L2,3-Edges

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Title: Investigation of a Spin Transition in a LaCoO₃ Single Crystal by the Method of X-Ray Magnetic Circular Dichroism at the Cobalt K- and L_2,3-Edges