Extraordinary Corrosion Protection from Polymer–Clay Nanobrick Wall Thin Films

Journal Article · Mon Jun 18 00:00:00 EDT 2018 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.8b05865· OSTI ID:1476931

Schindelholz, Eric John  ^[1]; Spoerke, Erik David  ^[1]; Nguyen, Hai -Duy ^[1]; Grunlan, Jaime C.  ^[2]; Qin, Shuang ^[2]; Bufford, Daniel C. ^[1]

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1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
2. Texas A & M Univ., College Station, TX (United States)

Metals across all industries demand anticorrosion surface treatments and drive a continual need for high-performing and low-cost coatings. Here we demonstrate polymer–clay nanocomposite thin films as a new class of transparent conformal barrier coatings for protection in corrosive atmospheres. Films assembled via layer-by-layer deposition, as thin as 90 nm, are shown to reduce copper corrosion rates by >1000× in an aggressive H₂S atmosphere. Furthermore, these multilayer nanobrick wall coatings hold promise as high-performing anticorrosion treatment alternatives to costlier, more toxic, and less scalable thin films, such as graphene, hexavalent chromium, or atomic-layer-deposited metal oxides.

• Research Organization: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
• Sponsoring Organization: USDOE National Nuclear Security Administration (NNSA)
• Grant/Contract Number: AC04-94AL85000
• OSTI ID: 1476931
• Report Number(s): SAND-2018-6529J; 664535
• Journal Information: ACS Applied Materials and Interfaces, Vol. 10, Issue 26; ISSN 1944-8244
• Publisher: American Chemical Society (ACS)
• Country of Publication: United States
• Language: English

Related Subjects

36 MATERIALS SCIENCE
anticorrosion barrier
coating
copper
corrosion resistant
inhibitor (or inhibition)
layer-by-layer assembly
nanocomposite
oxidation