Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R.; Park, Joong Sun; Lee, Eungje

Title: Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Patent · Tue Sep 04 00:00:00 EDT 2018

OSTI ID:1476897

Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R.; Park, Joong Sun; Lee, Eungje

An electrode material comprising a composite lithium metal oxide, which in an initial state has the formula: y[xLi₂MO₃.(1-x)LiM'O₂].(1-y)Li_1+dMn_2-z-dM"_-zO₄; wherein 0.ltoreq.x.ltoreq.1; 0.75.ltoreq.y<1; 01+dMn_2-z-dM"_zO₄ component comprises a spinel structure, each of the Li₂MO₃ and the LiM'O₂ components comprise layered structures, and at least one of M, M', and M" comprises Co. Cells and batteries comprising the electrode material also are described.

View Patent

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC02-06CH11357

Assignee:: UCHICAGO ARGONNE, LLC (Chicago, IL)

Patent Number(s):: 10,069,143

Application Number:: 14/733,512

OSTI ID:: 1476897

Resource Relation:: Patent File Date: 2015 Jun 08

Country of Publication:: United States

Language:: English

References (88)

Advances in Stabilizing ‘Layered-Layered’ xLi₂MnO₃·(1-x)LiMO₂(M=Mn, Ni, Co) Electrodes with a Spinel Component Long, Brandon R.; Croy, Jason R.; Park, Joong Sun Journal of The Electrochemical Society, Vol. 161, Issue 14, p. A2160-A2167 https://doi.org/10.1149/2.0681414jes	journal	January 2014
Surface Protected Lithium-Metal-Oxide Electrodes Thackeray, Michael M.; Kang, Sun-Ho https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100190058 US Patent Application 12/694422; 20100190058	patent-application	July 2010
Structural complexity of layered-spinel composite electrodes for Li-ion batteries Cabana, Jordi; Johnson, Christopher S.; Yang, Xiao-Qing Journal of Materials Research, Vol. 25, Issue 8, p. 1601-1616 https://doi.org/10.1557/JMR.2010.0206	journal	August 2010
High-Performance ZrO₂-Coated LiNiO₂ Cathode Material Cho, Jaephil; Kim, Tae-Joon; Kim, Yong Jeong Electrochemical and Solid-State Letters, Vol. 4, Issue 10, p. A159-A161 https://doi.org/10.1149/1.1398556	journal	January 2001
Positive active material for a rechargeable lithium battery, method for preparing the same and battery containing the same Cho, Jae-Phil; Park, Byung Woo; Kim, Yong Jeong https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6916580 US Patent Document 6,916,580	patent	July 2005
Positive electrode active material for lithium battery, method for producing the same, and lithium battery containing the same Amine, Khalil; Yasuda, Hideo; Fujita, Yuko https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5981106 US Patent Document 5,981,106	patent	November 1999
Cathode active material and lithium battery using the same Park, Kyu-sung https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7935270 US Patent Document 7,935,270	patent	May 2011
Positive active material for rechargeable lithium battery and method of preparing same Kweon, Ho-Jin; Suh, Joon-Won https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7138209 US Patent Document 7,138,209	patent	November 2006
Controlled Nanoparticle Metal Phosphates (Metal = Al , Fe, Ce, and Sr) Coatings on LiCoO₂ Cathode Materials Kim, Jisuk; Noh, Mijung; Cho, Jaephil Journal of The Electrochemical Society, Vol. 152, Issue 6, p. A1142-A1148 https://doi.org/10.1149/1.1896526	journal	January 2005
Manganese oxide composite electrodes for lithium batteries Johnson, Christopher S.; Kang, Sun-Ho; Thackeray, Michael M. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7790308 US Patent Document 7,790,308	patent	September 2010
Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells Gummow, R. J.; de Kock, A.; Thackeray, M. M. Solid State Ionics, Vol. 69, Issue 1, p. 59-67 https://doi.org/10.1016/0167-2738(94)90450-2	journal	April 1994
Methods for producing lithium metal oxide particles Kumar, Sujeet; Reitz, Hariklia Dris; Horne, Craig R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6482374 US Patent Document 6,482,374	patent	November 2002
Positive plate active material and nonaqyeous electrolyte secondary cell using same Hosoya, Yosuke; Yamamoto, Yoshikatsu; Sato, Takashi https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20040076882 US Patent Application 10/468900; 20040076882	patent-application	April 2004
Lithium-cobalt-nickel-oxide cathode materials prepared at 400°C for rechargeable lithium batteries Gummow, R. J.; Thackeray, M. M. Solid State Ionics, Vol. 53-56, p. 681-687 https://doi.org/10.1016/0167-2738(92)90447-W	journal	July 1992
Surface Modification of High Capacity Layered Li [ Li_0.2Mn_0.54Ni_0.13Co_0.13 ] O₂ Cathodes by AlPO₄ Wu, Y.; Vadivel Murugan, A.; Manthiram, A. Journal of The Electrochemical Society, Vol. 155, Issue 9, p. A635-A641 https://doi.org/10.1149/1.2948350	journal	January 2008
Microwave-Assisted Synthesis of High-Voltage Nanostructured LiMn_1.5Ni_0.5O₄ Spinel: Tuning the Mn³⁺ Content and Electrochemical Performance Jafta, Charl J.; Mathe, Mkhulu K.; Manyala, Ncholu ACS Applied Materials & Interfaces, Vol. 5, Issue 15, p. 7592-7598 https://doi.org/10.1021/am401894t	journal	July 2013
Effect of a ZrO₂ Coating on the Structure and Electrochemistry of Li_xCoO₂ When Cycled to 4.5 V Chen, Zhaohui; Dahn, J. R. Electrochemical and Solid-State Letters, Vol. 5, Issue 10, p. A213-A216 https://doi.org/10.1149/1.1503202	journal	January 2002
Positive active material for rechargeable lithium batteries and method of preparing same Kweon, Ho-Jin; Suh, Jun-Won; Jung, Won-Il https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6984469 US Patent Document 6,984,469	patent	January 2006
Lithium transition metal oxide Thackeray, Michael M.; Gummow, Rosalind J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5160712 US Patent Document 5,160,712	patent	November 1992
Synthesis and Characterization of Carbon-Coated Lithium Transition Metal Phosphates LiMPO₄ (M = Fe , Mn, Co, Ni) Prepared via a Nonaqueous Sol-Gel Route Yang, Jingsi; Xu, Jun John Journal of The Electrochemical Society, Vol. 153, Issue 4, p. A716-A723 https://doi.org/10.1149/1.2168410	journal	January 2006
Electrochemical evaluation of mixed oxide electrode for Li-ion secondary batteries: Li_1.1Mn_1.9O₄ and LiNi_0.8Co_0.15Al_0.05O₂ Myung, Seung-Taek; Cho, Myung Hun; Hong, Hyeon Taik Journal of Power Sources, Vol. 146, Issue 1-2, p. 222-225 https://doi.org/10.1016/j.jpowsour.2005.03.031	journal	August 2005
Layered Li(Li_0.2Ni_0.15+0.5zCo_0.10Mn_0.55−0.5z)O_2−zF_z cathode materials for Li-ion secondary batteries Kang, S.-H.; Amine, K. Journal of Power Sources, Vol. 146, Issue 1-2, p. 654-657 https://doi.org/10.1016/j.jpowsour.2005.03.152	journal	August 2005
Process of preparing a surface-treated positive active material for a lithium secondary battery Suh, Jun-Won; Kweon, Ho-Jin https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7445871 US Patent Document 7,445,871	patent	November 2008
Surface/chemically modified oxide cathodes for lithium-ion batteries Manthiram, Arumugam; Kanman, Arunachala Nadar Mada https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030108790 US Patent Application 10/010858; 20030108790	patent-application	June 2003
Assembled Battery and Battery System Sugiyama, Shigeyuki; Aoki, Mamoru https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100207577 US Patent Application 12/676493; 20100207577	patent-application	August 2010
Lithium metal oxide electrodes for lithium cells and batteries Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6677082 US Patent Document 6,677,082	patent	January 2004
Anomalous capacity and cycling stability of xLi₂MnO₃·(1−x)LiMO₂ electrodes (M=Mn, Ni, Co) in lithium batteries at 50°C Johnson, Christopher S.; Li, Naichao; Lefief, Christina Electrochemistry Communications, Vol. 9, Issue 4, p. 787-795 https://doi.org/10.1016/j.elecom.2006.11.006	journal	April 2007
AlF₃-Coating to Improve High Voltage Cycling Performance of Li[Ni_1∕3]Co_1∕3]Mn_1∕3]O₂ Cathode Materials for Lithium Secondary Batteries Sun, Y.-K.; Cho, S.-W.; Lee, S.-W. Journal of The Electrochemical Society, Vol. 154, Issue 3, p. A168-A172 https://doi.org/10.1149/1.2422890	journal	January 2007
Thin Film Battery Comprising Stacked Battery Cells and Methods Kraznov, Victor; Nieh, Kai-Wei https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090136839 US Patent Application 11/946819; 20090136839	patent-application	May 2009
High-energy and high-power Li-rich nickel manganese oxide electrode materials Kim, Donghan; Kang, Sun-Ho; Balasubramanian, Mahalingam Electrochemistry Communications, Vol. 12, Issue 11, p. 1618-1621 https://doi.org/10.1016/j.elecom.2010.09.009	journal	November 2010
Structural and Electrochemical Characterization of Composite Layered-Spinel Electrodes Containing Ni and Mn for Li-Ion Batteries Cabana, Jordi; Kang, Sun-Ho; Johnson, Christopher S. Journal of The Electrochemical Society, Vol. 156, Issue 9 https://doi.org/10.1149/1.3151963	journal	January 2009
Lithium metal oxide electrodes for lithium batteries Thackeray, Michael M.; Kim, Jeom-Soo; Johnson, Christopher S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7314682 US Patent Document 7,314,682	patent	January 2008
Improvement of High-Voltage Cycling Behavior of Surface-Modified Li[Ni[sub 1∕3]Co[sub 1∕3]Mn[sub 1∕3]]O[sub 2] Cathodes by Fluorine Substitution for Li-Ion Batteries Kim, G.-H.; Kim, J.-H.; Myung, S.-T. Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1707-A1713 https://doi.org/10.1149/1.1952747	journal	July 2005
The significance of the Li₂MnO₃ component in ‘composite’ xLi₂MnO₃·(1−x)LiMn_0.5Ni_0.5O₂ electrodes Johnson, C. S.; Kim, J-S.; Lefief, C. Electrochemistry Communications, Vol. 6, Issue 10, p. 1085-1091 https://doi.org/10.1016/j.elecom.2004.08.002	journal	October 2004
Electrochemical cell Thackeray, Michael M.; Gummow, Rosalind J. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5316877 US Patent Document 5,316,877	patent	May 1994
Li₂MnO₃-stabilized LiMO₂ (M = Mn, Ni, Co) electrodes for lithium-ion batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. Journal of Materials Chemistry, Vol. 17, Issue 30, p. 3112-3125 https://doi.org/10.1039/b702425h	journal	January 2007
Characterization of LT ‐ Li_xCo_1 − yNi_y O ₂ Electrodes for Rechargeable Lithium Cells Gummow, R. J.; Thackeray, M. M. Journal of The Electrochemical Society, Vol. 140, Issue 12, p. 3365-3368 https://doi.org/10.1149/1.2221096	journal	January 1993
Manganese oxide composite electrodes for lithium batteries Thackeray, Michael M.; Kang, Sun-Ho; Johnson, Christopher S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8080340 US Patent Document 8,080,340	patent	December 2011
Positive active material for rechargeable lithium battery and method of preparing same Cho, Jae-Phil; Kim, Chan; Yoo, Sang-Im https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6555269 US Patent Document 6,555,269	patent	April 2003
Electrode Structures and Surfaces For Li Batteries Thackeray, Michael M.; Kim, Donghan; Croy, Jason https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20130078518 US Patent Application 13/680959; 20130078518	patent-application	March 2013
Lithium metal oxide electrodes for lithium cells and batteries Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7468223 US Patent Document 7,468,223	patent	December 2008
Designing High-Capacity, Lithium-Ion Cathodes Using X-ray Absorption Spectroscopy Croy, Jason R.; Balasubramanian, Mahalingam; Kim, Donghan Chemistry of Materials, Vol. 23, Issue 24, p. 5415-5424 https://doi.org/10.1021/cm2026703	journal	December 2011
Identification of LiNi_0.5Mn_1.5O₄ spinel in layered manganese enriched electrode materials Belharouak, Ilias; Koenig, Gary M.; Ma, Jiwei Electrochemistry Communications, Vol. 13, Issue 3, p. 232-236 https://doi.org/10.1016/j.elecom.2010.12.021	journal	March 2011
Spinel versus layered structures for lithium cobalt oxide synthesised at 400°C Gummow, R. J.; Liles, D. C.; Thackeray, M. M. Materials Research Bulletin, Vol. 28, Issue 3, p. 235-246 https://doi.org/10.1016/0025-5408(93)90157-9	journal	March 1993
What Are Batteries, Fuel Cells, and Supercapacitors? Winter, Martin; Brodd, Ralph J. Chemical Reviews, Vol. 104, Issue 10, p. 4245-4270 https://doi.org/10.1021/cr020730k	journal	October 2004
Non-aqueous electrolyte secondary battery Shirakata, Hironori; Kitao, Hideki; Akita, Hiroyuki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20060216605 US Patent Application 11/378638; 20060216605	patent-application	September 2006
Novel LiCoO₂ Cathode Material with Al₂O₃ Coating for a Li Ion Cell Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo Chemistry of Materials, Vol. 12, Issue 12, p. 3788-3791 https://doi.org/10.1021/cm000511k	journal	December 2000
Electrochemical and Structural Properties of xLi₂M‘O₃ ·(1− x )LiMn_0.5Ni_0.5O₂ Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3) Kim, Jeom-Soo; Johnson, Christopher S.; Vaughey, John T. Chemistry of Materials, Vol. 16, Issue 10, p. 1996-2006 https://doi.org/10.1021/cm0306461	journal	May 2004
The Electrochemical Stability of Spinel Electrodes Coated with ZrO₂, Al₂O₃, and SiO₂ from Colloidal Suspensions Kim, J.-S.; Johnson, C. S.; Vaughey, J. T. Journal of The Electrochemical Society, Vol. 151, Issue 10, p. A1755-A1761 https://doi.org/10.1149/1.1793713	journal	January 2004
Optimization of Insertion Compounds Such as LiMn₂O₄ for Li-Ion Batteries Amatucci, G.; Tarascon, J.-M. Journal of The Electrochemical Society, Vol. 149, Issue 12, p. K31-K46 https://doi.org/10.1149/1.1516778	journal	November 2002
A New Three‐Volt Spinel Li_1 + xMn_1.5Ni_0.5 O ₄ for Secondary Lithium Batteries Amine, K.; Tukamoto, H.; Yasuda, H. Journal of The Electrochemical Society, Vol. 143, Issue 5, p. 1607-1613 https://doi.org/10.1149/1.1836686	journal	January 1996
Lithium metal oxide electrodes for lithium batteries Thackeray, Michael M.; Kim, Jeom-Soo; Johnson, Christopher S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050026040 US Patent Application 10/825931; 20050026040	patent-application	February 2005
Positive-electrode active material for non-aqueous electrolyte secondary cell and process for preparing the same Oesten, Ruediger; Suzuki, Ryuta; Nitta, Katsuhisa https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20050153206 US Patent Application 10/510334; 20050153206	patent-application	July 2005
Cathode active material and lithium battery using the same Park, Kyu-sung https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7927506 US Patent Document 7,927,506	patent	April 2011
Lithium Metal Oxide Electrodes for Lithium Batteries Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20150180031 US Patent Application 14/554666; 20150180031	patent-application	June 2015
Lithium manganese oxide compound Thackeray, Michael M.; Rossouw, Margaretha H. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5153081 US Patent Document 5,153,081	patent	October 1992
Influence of Lattice Parameter Differences on the Electrochemical Performance of the 5 V Spinel LiMn_{1.5 − y}Ni_{0.5 − z}M_y + zO₄ (M = Li , Mg, Fe, Co, and Zn) Arunkumar, T. A.; Manthiram, A. Electrochemical and Solid-State Letters, Vol. 8, Issue 8, p. A403-A405 https://doi.org/10.1149/1.1945369	journal	January 2005
Improvement of structural and electrochemical properties of AlF₃-coated Li[Ni_1/3Co_1/3Mn_1/3]O₂ cathode materials on high voltage region Park, B.-C.; Kim, H.-B.; Myung, S.-T. Journal of Power Sources, Vol. 178, Issue 2, p. 826-831 https://doi.org/10.1016/j.jpowsour.2007.08.034	journal	April 2008
Intergrown LiNi_0.5Mn_1.5O₄·LiNi_1/3Co_1/3Mn_1/3O₂ composite nanorods as high-energy density cathode materials for lithium-ion batteries Yang, Jingang; Zhang, Xiaolong; Han, Xiaopeng Journal of Materials Chemistry A, Vol. 1, Issue 44, p. 13742-13745 https://doi.org/10.1039/c3ta13766j	journal	January 2013
Active material for battery and method of preparing same Cho, Jae-Phil; Jung, Won-II; Park, Yong-Chul https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6878487 US Patent Document 6,878,487	patent	April 2005
Coated electrode particles for composite electrodes and electrochemical cells Holman, Richard K.; Chiang, Yet-Ming; Gozdz, Antoni S. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7087348 US Patent Document 7,087,348	patent	August 2006
Ordering in Li_x(Ni_0.5Mn_0.5)O₂ and its relation to charge capacity and electrochemical behavior in rechargeable lithium batteries Van der Ven, A.; Ceder, G. Electrochemistry Communications, Vol. 6, Issue 10, p. 1045-1050 https://doi.org/10.1016/j.elecom.2004.07.018	journal	October 2004
Lithium metal oxide electrodes for lithium cells and batteries Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6680143 US Patent Document 6,680,143	patent	January 2004
Electrode Structures and Surfaces for Li Batteries Thackery, Michael M.; Kang, Sun-Ho; Balasubramanian, Mahalingam https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20120263998 US Patent Application 13/440431; 20120263998	patent-application	October 2012
Superior Capacity Retention Spinel Oxyfluoride Cathodes for Lithium-Ion Batteries Choi, W.; Manthiram, A. Electrochemical and Solid-State Letters, Vol. 9, Issue 5, p. A245-A248 https://doi.org/10.1149/1.2186022	journal	March 2006
Coated lithium mixed oxide particles and a process for producing them Oesten, Ruediger; Li, Bangyin; Nakamura, Nobuaki https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20010046628 US Patent Application 09/816663; 20010046628	patent-application	November 2001
Stabilization of xLi₂MnO₃ ⋅ ( 1 − x ) LiMO₂ Electrode Surfaces ( M = Mn , Ni , Co ) with Mildly Acidic, Fluorinated Solutions Kang, S.-H.; Thackeray, M. M. Journal of The Electrochemical Society, Vol. 155, Issue 4, p. A269-A275 https://doi.org/10.1149/1.2834904	journal	January 2008
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteries Thackeray, Michael M.; Johnson, Christopher S.; Vaughey, John T. Journal of Materials Chemistry, Vol. 15, Issue 23, p. 2257-2267 https://doi.org/10.1039/b417616m	journal	March 2005
Li₂MnO₃-based composite cathodes for lithium batteries: A novel synthesis approach and new structures Croy, J. R.; Kang, S.-H.; Balasubramanian, M. Electrochemistry Communications, Vol. 13, Issue 10, p. 1063-1066 https://doi.org/10.1016/j.elecom.2011.06.037	journal	October 2011
In situ X-ray diffraction studies of mixed LiMn₂O₄–LiNi_1/3Co_1/3Mn_1/3O₂ composite cathode in Li-ion cells during charge–discharge cycling Nam, Kyung-Wan; Yoon, Won-Sub; Shin, Hyunjung Journal of Power Sources, Vol. 192, Issue 2, p. 652-659 https://doi.org/10.1016/j.jpowsour.2009.02.088	journal	July 2009
Manganese oxide composite electrodes for lithium batteries Thackeray, Michael M.; Johnson, Christopher S.; Li, Naichao https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7303840 US Patent Document 7,303,840	patent	December 2007
Mixed phase lithium metal oxide compositions with desirable battery performance Sharma, Sanjeev; Venkatachalam, Subramanian; Anguchamy, Yogesh Kumar https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/9070489 US Patent Document 9,070,489	patent	June 2015
Positive Electrode Materials for Lithium Ion Batteries Having a Specific Discharge Capacity and Processes for the Synthesis of These Materials Venkatachalam, Subramanian; Lopez, Herman; Kumar, Sujeet https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20100086853 US Patent Application 12/246814; 20100086853	patent-application	April 2010
The Effects of Acid Treatment on the Electrochemical Properties of 0.5 Li₂MnO₃ ∙ 0.5 LiNi_0.44Co_0.25Mn_0.31O₂ Electrodes in Lithium Cells Kang, S.-H.; Johnson, C. S.; Vaughey, J. T. Journal of The Electrochemical Society, Vol. 153, Issue 6, p. A1186-A1192 https://doi.org/10.1149/1.2194764	journal	January 2006
Positive electrode active material, positive electrode and non-aqueous electrolyte secondary battery using thereof Noguchi, Takehiro; Numata, Tatsuji https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030086863 US Patent Application 10/270946; 20030086863	patent-application	May 2003
Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries Kim, Donghan; Sandi, Giselle; Croy, Jason R. Journal of The Electrochemical Society, Vol. 160, Issue 1, p. A31-A38 https://doi.org/10.1149/2.049301jes	journal	November 2012
Manganese oxide composite electrodes for lithium batteries Johnson, Christopher S.; Kang, Sun-Ho; Thackeray, Michael M. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7635536 US Patent Document 7,635,536	patent	December 2009
ChemInform Abstract: Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell. Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo ChemInform, Vol. 32, Issue 12 https://doi.org/10.1002/chin.200112011	journal	March 2001
Surface and Bulk Modified High Capacity Layered Oxide Cathodes with Low Irreversible Capacity Loss Manthiram, Arumugam https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20090224212 US Patent Application 11/861248; 20090224212	patent-application	September 2009
Electrode Structures and Surfaces for Li Batteries Thackeray, Michael M.; Kang, Sun-Ho; Balasubramanian, Mahalingam https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20140127398 US Patent Application 14/154948; 20140127398	patent-application	May 2014
Structure and electrochemistry of lithium cobalt oxide synthesised at 400°C Gummow, R. J.; Thackeray, M. M.; David, W. I. F. Materials Research Bulletin, Vol. 27, Issue 3, p. 327-337 https://doi.org/10.1016/0025-5408(92)90062-5	journal	March 1992
Lithium–manganese oxide electrodes with layered–spinel composite structures xLi₂MnO₃·(1−x)Li_1+yMn_2−yO₄ (0<x<1, 0⩽y⩽0.33) for lithium batteries Johnson, C. S.; Li, N.; Vaughey, J. T. Electrochemistry Communications, Vol. 7, Issue 5, p. 528-536 https://doi.org/10.1016/j.elecom.2005.02.027	journal	May 2005
Understanding the effect of synthesis temperature on the structural and electrochemical characteristics of layered-spinel composite cathodes for lithium-ion batteries Lee, Eun-Sung; Huq, Ashfia; Manthiram, Arumugam Journal of Power Sources, Vol. 240, p. 193-203 https://doi.org/10.1016/j.jpowsour.2013.04.010	journal	October 2013
Structural Considerations of Layered and Spinel Lithiated Oxides for Lithium Ion Batteries Thackeray, M. M. Journal of The Electrochemical Society, Vol. 142, Issue 8 https://doi.org/10.1149/1.2050053	journal	January 1995
Positive-electrode active material for non-aqueous electrolyte secondary cell and process for preparing the same Oesten, Ruediger; Suzuki, Ryuta; Nitta, Katsuhisa https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7384664 US Patent Document 7,384,664	patent	June 2008
A reinvestigation of the structures of lithium-cobalt-oxides with neutron-diffraction data Gummow, R. J.; Liles, D. C.; Thackeray, M. M. Materials Research Bulletin, Vol. 28, Issue 11, p. 1177-1184 https://doi.org/10.1016/0025-5408(93)90098-X	journal	November 1993
Surface protected lithium-metal-oxide electrodes Thackeray, Michael M.; Kang, Sun-Ho https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8808912 US Patent Document 8,808,912	patent	August 2014
Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries Park, S.; Kang, S.; Johnson, C. Electrochemistry Communications, Vol. 9, Issue 2, p. 262-268 https://doi.org/10.1016/j.elecom.2006.09.014	journal	February 2007

Similar Records

First-Principles Study of Lithium Cobalt Spinel Oxides: Correlating Structure and Electrochemistry

Journal Article · Wed Apr 04 00:00:00 EDT 2018 · ACS Applied Materials and Interfaces · OSTI ID:1476897

Kim, Soo; Hegde, Vinay I.; Yao, Zhenpeng; +8 more

Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Patent · Tue Sep 29 00:00:00 EDT 2020 · OSTI ID:1476897

Thackeray, Michael M.; Croy, Jason R.; Long, Brandon R.; +2 more

Protective coating on positive lithium-metal-oxide electrodes for lithium batteries

Patent · Tue May 23 00:00:00 EDT 2006 · OSTI ID:1476897

Johnson, Christopher S.; Thackeray, Michael M.; Kahaian, Arthur J.

Title: Cobalt-stabilized lithium metal oxide electrodes for lithium batteries

Citation Formats

References (88)

Similar Records

Related Subjects