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Title: Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature

Abstract

We have performed high pressure-temperature Brillouin scattering measurements on single crystal hydrogen sulfide using externally heated diamond anvil cell techniques. The pressure dependences of the acoustic velocities, isothermal elastic constants, and moduli of single crystal hydrogen sulfide have been determined along four isotherms. Both elastic constants and moduli increase monotonously with pressure along each isotherm, while they show a decreased tendency with temperature elevated under the same pressure points. The experimental equation of state of single crystal hydrogen sulfide is obtained by fitting with a third-order Birch-Murnaghan and Tait equation. It is proposed that the effect of hydrogen bonds contributes to the unique tendency of elastic anisotropy in single crystal hydrogen sulfide. Through our work, we have extended the melting curve and phase diagram of hydrogen sulfide up to 12 GPa and 580 K.

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1];  [1]
  1. Jilin Univ., Changchun (China). State Key Lab. of Superhard Materials
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1476093
Alternate Identifier(s):
OSTI ID: 1473737
Grant/Contract Number:  
AC02-06CH11357; FG02-94ER14466
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 124; Journal Issue: 12; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
ENGLISH
Subject:
36 MATERIALS SCIENCE; Equations of state; Diamond anvil cells; Crystal structure; Elasticity; Acoustical properties; Light scattering; Brillouin spectroscopy; Phase transitions

Citation Formats

Zhou, Di, Huang, Xiaoli, Li, Xin, Yu, Hongyu, Li, Fangfei, Huang, Yanping, Lu, Mengya, Liang, Yongfu, Liu, Mingkun, Wu, Gang, Zhou, Qiang, Liu, Bingbing, and Cui, Tian. Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature. United States: N. p., 2018. Web. doi:10.1063/1.5040399.
Zhou, Di, Huang, Xiaoli, Li, Xin, Yu, Hongyu, Li, Fangfei, Huang, Yanping, Lu, Mengya, Liang, Yongfu, Liu, Mingkun, Wu, Gang, Zhou, Qiang, Liu, Bingbing, & Cui, Tian. Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature. United States. doi:10.1063/1.5040399.
Zhou, Di, Huang, Xiaoli, Li, Xin, Yu, Hongyu, Li, Fangfei, Huang, Yanping, Lu, Mengya, Liang, Yongfu, Liu, Mingkun, Wu, Gang, Zhou, Qiang, Liu, Bingbing, and Cui, Tian. Fri . "Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature". United States. doi:10.1063/1.5040399. https://www.osti.gov/servlets/purl/1476093.
@article{osti_1476093,
title = {Elastic properties of single crystal hydrogen sulfide: A Brillouin scattering study under high pressure-temperature},
author = {Zhou, Di and Huang, Xiaoli and Li, Xin and Yu, Hongyu and Li, Fangfei and Huang, Yanping and Lu, Mengya and Liang, Yongfu and Liu, Mingkun and Wu, Gang and Zhou, Qiang and Liu, Bingbing and Cui, Tian},
abstractNote = {We have performed high pressure-temperature Brillouin scattering measurements on single crystal hydrogen sulfide using externally heated diamond anvil cell techniques. The pressure dependences of the acoustic velocities, isothermal elastic constants, and moduli of single crystal hydrogen sulfide have been determined along four isotherms. Both elastic constants and moduli increase monotonously with pressure along each isotherm, while they show a decreased tendency with temperature elevated under the same pressure points. The experimental equation of state of single crystal hydrogen sulfide is obtained by fitting with a third-order Birch-Murnaghan and Tait equation. It is proposed that the effect of hydrogen bonds contributes to the unique tendency of elastic anisotropy in single crystal hydrogen sulfide. Through our work, we have extended the melting curve and phase diagram of hydrogen sulfide up to 12 GPa and 580 K.},
doi = {10.1063/1.5040399},
journal = {Journal of Applied Physics},
issn = {0021-8979},
number = 12,
volume = 124,
place = {United States},
year = {2018},
month = {9}
}

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