Highly efficient Cu-decorated iron oxide nanocatalyst for low pressure CO2 conversion

Journal Article · Fri Jun 01 04:00:00 EDT 2018 · Applied Catalysis. B, Environmental

DOI:https://doi.org/10.1016/j.apcatb.2017.11.047· OSTI ID:1475556

Halder, Avik; Kilianová, Martina; Yang, Bing; Tyo, Eric C.; Seifert, Soenke; Prucek, Robert; Panáček, Aleš; Suchomel, Petr; Tomanec, Ondřej; Gosztola, David J.; Milde, David; Wang, Hsien-Hau; Kvítek, Libor; Zbořil, Radek; Vajda, Stefan

We report a nanoparticulate iron oxide based catalyst for CO2 conversion with high efficiency at low pressures and on the effect of the presence of copper on the catalyst’s restructuring and its catalytic performance. In situ X-ray scattering reveals the restructuring of the catalyst at the nanometer scale. In situ X-ray absorption near edge structure (XANES) shows the evolution of the composition and oxidation state of the iron and copper components under reaction conditions along with the promotional effect of copper on the chemical transformation of the iron component. X-ray diffraction (XRD), XANES and Raman spectroscopy proved that the starting nanocatalyst is composed of iron oxides differing in chemical nature (α-Fe2O3, Fe3O4, FeO(OH)) and dimensionality, while the catalyst after CO2 conversion was identified as a mixture of α-Fe, Fe3C, and traces of Fe5C2. The significant increase of the rate CO2 is turned over in the presence of copper nanoparticles indicates that Cu nanoparticles activate hydrogen, which after spilling over to the neighbouring iron sites, facilitate a more efficient conversion of carbon dioxide.

• Research Organization: Argonne National Laboratory (ANL)
• Sponsoring Organization: USDOE Office of Science - Office of Basic Energy Sciences - Materials Sciences and Engineering Division; USDOE Office of Science - Office of Basic Energy Sciences - Scientific User Facilities Division
• DOE Contract Number: AC02-06CH11357
• OSTI ID: 1475556
• Journal Information: Applied Catalysis. B, Environmental, Journal Name: Applied Catalysis. B, Environmental Journal Issue: C Vol. 225; ISSN 0926-3373
• Publisher: Elsevier
• Country of Publication: United States
• Language: English

Related Subjects

Benzene
CO2 conversion
Carbon dioxide
Carbon monoxide
Copper
Heterogeneous catalysis
Hydrogen
Iron oxide
Methane
Methanol
Nanoparticles