Reversible adsorption of nitrogen dioxide within a robust porous metal–organic framework

Han, Xue; Godfrey, Harry G.  W.; Briggs, Lydia; Davies, Andrew J.; Cheng, Yongqiang; Daemen, Luke L.; Sheveleva, Alena M.; Tuna, Floriana; McInnes, Eric J.  L.; Sun, Junliang; Drathen, Christina; George, Michael W.; Ramirez-Cuesta, Anibal J.; Thomas, K. Mark; Yang, Sihai; Schröder, Martin

doi:10.1038/s41563-018-0104-7

Title: Reversible adsorption of nitrogen dioxide within a robust porous metal–organic framework

Journal Article · Mon Jun 11 00:00:00 EDT 2018 · Nature Materials

DOI:https://doi.org/10.1038/s41563-018-0104-7· OSTI ID:1474849

Han, Xue ^[1]; Godfrey, Harry G. W. ^[1]; Briggs, Lydia ^[1]; Davies, Andrew J. ^[2]; Cheng, Yongqiang ^[3]; Daemen, Luke L. ^[3]; Sheveleva, Alena M. ^[4]; Tuna, Floriana ^[1];

^[1]; Sun, Junliang ^[5]; Drathen, Christina ^[6]; George, Michael W. ^[7];

^[3]; Thomas, K. Mark ^[8]; Yang, Sihai ^[1]; Schröder, Martin ^[1]

Univ. of Manchester (United Kingdom). School of Chemistry
Univ. of Nottingham (United Kingdom). School of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical and Engineering Materials Division (CEMD), Neutron Sciences Directorate
Univ. of Manchester (United Kingdom). School of Chemistry; Novosibirsk State Univ. (Russian Federation). International Tomography Center SB RAS
Peking Univ., Beijing (China). College of Chemistry and Molecular Engineering
European Synchrotron Radiation Facility (ESRF), Grenoble (France)
Univ. of Nottingham (United Kingdom). School of Chemistry; Univ. of Nottingham Ningbo China, Ningbo (China). Dept. of Chemical and Environmental Engineering
Univ. of Newcastle upon Tyne, Newcastle upon Tyne (United Kingdom)

Nitrogen dioxide (NO₂) is a major air pollutant causing significant environmental and health problems. We report reversible adsorption of NO₂ in a robust metal–organic framework. Under ambient conditions, MFM-300(Al) exhibits a reversible NO₂ isotherm uptake of 14.1 mmol g^-1, and, more importantly, exceptional selective removal of low-concentration NO₂ (5,000 to <1 ppm) from gas mixtures. Complementary experiments reveal five types of supramolecular interaction that cooperatively bind both NO₂ and N₂O₄ molecules within MFM-300(Al). We find that the in situ equilibrium 2NO₂ ↔ N₂O₄ within the pores is pressure-independent, whereas ex situ this equilibrium is an exemplary pressure-dependent first-order process. The coexistence of helical monomer–dimer chains of NO₂ in MFM-300(Al) could provide a foundation for the fundamental understanding of the chemical properties of guest molecules within porous hosts. Lastly, this work may pave the way for the development of future capture and conversion technologies.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Laboratory Directed Research and Development (LDRD) Program; Engineering and Physical Sciences Research Council (EPSRC); Univ. of Manchester; Univ. of Nottingham; Russian Ministry of Science and Education

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1474849

Journal Information:: Nature Materials, Vol. 17, Issue 8; ISSN 1476-1122

Publisher:: Springer Nature - Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 113 works

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